Compact contacting systems and methods for scavenging sulfur-containing compounds

Patent metadata

Field	Value
Publication number	US-10876052-B2
Application number	US-201815950867-A
Country	US
Kind code	B2
Filing date	Apr 11, 2018
Priority date	Jun 20, 2017
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

A hydrogen sulfide (H 2 S) scavenging system for removing H 2 S, mercaptans, and/or other sulfur-containing compounds from a natural gas stream. A co-current contacting system is located in-line within a pipe and receives the natural gas stream and a liquid scavenger stream. The co-current contacting system includes a co-current contactor including a droplet generator and a mass transfer section. The droplet generator generates droplets from the liquid scavenger stream and disperses the droplets into the natural gas stream. The mass transfer section provides a mixed, two-phase flow having a vapor phase and a liquid phase. The liquid phase includes the liquid scavenger stream with H 2 S, mercaptans, and/or other sulfur-containing compounds absorbed from the natural gas stream, and the vapor phase includes the natural gas stream. A separation system separates the vapor phase from the liquid phase.

First claim

What is claimed is:

1. A hydrogen sulfide (H 2 S) scavenging system for removing H 2 S, mercaptans, and/or other sulfur-containing compounds from a natural gas stream, comprising:
a liquid scavenger stream, wherein the liquid scavenger stream comprises caustic;
a co-current contacting system located in-line within a pipe, the co-current contacting system receiving the natural gas stream and the liquid scavenger stream, the co-current contacting system including:
a co-current contactor including a droplet generator and a mass transfer section, the droplet generator configured to generate droplets from the liquid scavenger stream and to disperse the droplets into the natural gas stream, and the mass transfer section configured to provide a mixed, two-phase flow having a vapor phase and a liquid phase, wherein the liquid phase includes the liquid scavenger stream with H 2 S, mercaptans, and/or other sulfur-containing compounds absorbed from the natural gas stream, and wherein the vapor phase includes the natural gas stream; and
a separation system configured to separate the vapor phase from the liquid phase;

wherein the liquid phase exiting the separation system comprises the liquid scavenger stream received by the co-current contacting system;
the H 2 S scavenging system further comprising:
a spent scavenger line for removing part of the liquid scavenger stream prior to being received by the co-current contacting system;
a fresh scavenger line for injecting fresh scavenger liquid into the liquid scavenger stream prior to being received by the co-current contacting system; and
a scavenger regenerator connected to the spent scavenger line, the scavenger regenerator configured to remove H 2 S, mercaptans, mercaptides, disulfides, and/or other sulfur-containing compounds from the removed part of the liquid scavenger stream to produce a regenerated scavenger, the scavenger regenerator further configured to return the regenerated scavenger to the liquid scavenger stream through the fresh scavenger line.

2. The H 2 S scavenging system of claim 1 , further comprising:
a storage tank that stores the liquid scavenger stream.

3. The H 2 S scavenging system of claim 2 , wherein the storage tank is a first storage tank, and further comprising a second storage tank that stores the liquid phase after the liquid phase exits the co-current contacting system.

4. The H 2 S scavenging system of claim 2 , wherein the storage tank is a first storage tank having an outlet connected to the droplet generator and an inlet connected to a liquid outlet of the separation system, and further comprising a second storage tank having an outlet connected to the droplet generator and an inlet connected to the liquid outlet of the separation system.

5. The H 2 S scavenging system of claim 4 , wherein the outlet of the first storage tank is connected to the droplet generator through a first isolation valve, the outlet of the second storage tank is connected to the droplet generator through a second isolation valve, the inlet of the first storage tank is connected to the liquid outlet of the separation system through a third isolation valve, and the inlet of the second storage tank is connected to the liquid outlet of the separation system through a fourth isolation valve.

6. The H 2 S scavenging system of claim 1 , wherein the droplet generator comprises:
an annular support ring securing the droplet generator in-line within the pipe;
a plurality of spokes extending from the annular support ring, the annular support ring having a plurality of liquid channels configured to allow the liquid scavenger stream to flow through the plurality of spokes and out of injection orifices disposed on the plurality of spokes; and
a gas entry cone supported by the plurality of spokes and configured to allow
a first portion of the natural gas stream to flow through a hollow section of the gas entry cone and through gas exit slots included in the plurality of spokes, and
a second portion of the natural gas stream to flow around the gas entry cone and between the plurality of spokes, wherein the second portion of the natural gas stream is separate from the first portion of the gas stream;

wherein a downstream portion of the gas entry cone comprises one of a blunt ended cone and a tapered ended cone.

7. The H 2 S scavenging system of claim 1 , wherein the separation system of the co-current contacting system comprises a cyclonic separator.

8. The H 2 S scavenging system of claim 1 , wherein the co-current contacting system is one of a plurality of co-current contacting systems connected in series, said plurality of co-current contacting systems including a last co-current contacting system;
wherein each of the plurality of co-current contacting system comprises
a co-current contactor including a droplet generator and a mass transfer section, the droplet generator configured to generate droplets of the liquid scavenger and to disperse the droplets into a gas stream received from a previous co-current contacting system, and the mass transfer section configured to provide a mixed, two-phase flow having a vapor phase and a liquid phase; and
a separation system configured to separate the vapor phase from the liquid phase, wherein the vapor phase comprises a processed gas stream and the liquid phase comprises the liquid from which droplets are generated in a co-current contactor of a previous co-current contacting system.

9. A method of removing H 2 S, mercaptans, and/or other sulfur-containing compounds from a natural gas stream, comprising:
receiving the natural gas stream and a liquid scavenger stream in a co-current contacting system located in-line within a pipe, the co-current contacting system including a droplet generator and a mass transfer section, wherein the liquid scavenger stream comprises caustic;
using the droplet generator, generating droplets from the liquid scavenger stream and dispersing the droplets into the natural gas stream;
using the mass transfer section, providing a mixed, two-phase flow having a vapor phase and a liquid phase, wherein the liquid phase includes the liquid scavenger stream with H 2 S, mercaptans, and/or other sulfur-containing compounds absorbed from the natural gas stream, and wherein the vapor phase includes the natural gas stream; and
separating the vapor phase from the liquid phase;
wherein the liquid phase exiting the separation system comprises the liquid scavenger stream received by the co-current contacting system;
the method further comprising
removing part of the liquid scavenger stream prior to being received by the co-current contacting system;
injecting fresh scavenger liquid into the liquid scavenger stream prior to being received by the co-current contacting system;
in a scavenger regenerator, removing H 2 S, mercaptans, mercaptides, disulfides, and/or other sulfur-containing compounds from the removed part of the liquid scavenger stream, thereby producing a regenerated scavenger; and
returning the regenerated scavenger to the liquid scavenger stream.

10. The method of claim 9 , further comprising:
storing the liquid scavenger stream in a first storage tank; and
storing the liquid phase in a second storage tank after the liquid phase exits the co-current contacting system.

11. The method of claim 9 , further comprising:
storing the liquid scavenger stream in a first storage tank;
connecting an outlet of the first storage tank to the droplet generator;
connecting an inlet of the first storage tank to a liquid outlet of the separation system;
connecting an outlet of a second storage tank to the droplet generator; and
connecting an inlet of the second storage tan

Assignees

• Ramkumar Shwetha
• Shatto Donald P
• Northrop P Scott
• Philbrook Sean T
• Exxonmobil Upstream Res Co

Inventors

• Ramkumar Shwetha
• Shatto Donald P
• Northrop P Scott
• Philbrook Sean T

Classifications

• B01D53/1487

  Removing organic compounds · CPC title

• B01D2257/306

  Organic sulfur compounds, e.g. mercaptans · CPC title

• B01D53/18

  Absorbing units; Liquid distributors therefor (B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32) · CPC title

• C10G2300/207

  Acid gases, e.g. H2S, COS, SO2, HCN · CPC title

• C10G25/003 Primary

  Specific sorbent material, not covered by C10G25/02 or C10G25/03 · CPC title