Reinforcing material for rubber comprising aluminosilicate particles and rubber composition for tires comprising the same

Patent metadata

Field	Value
Publication number	US-10875980-B2
Application number	US-201716070645-A
Country	US
Kind code	B2
Filing date	Sep 4, 2017
Priority date	Sep 9, 2016
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

The present disclosure relates to a reinforcing material for rubber including aluminosilicate particles and a rubber composition for tires including the same. The reinforcing material for rubber according to the present disclosure exhibits excellent dispersibility in the rubber composition and reinforcing effect, and thus can be suitably used for eco-friendly tires requiring high efficiency and high fuel efficiency characteristics.

First claim

The invention claimed is:

1. A reinforcing material for rubber comprising amorphous aluminosilicate particles having a composition of the following Chemical Formula 1,
wherein the aluminosilicate particles satisfy the following conditions:
in a data plot obtained by X-ray diffraction (XRD), a full width at half maximum (FWHM) in a 2θ range of 20° to 37° is 3° to 8.5°, and a maximum peak intensity (I max ) is in a 2θ range of 26° to 31°,
an average primary particle diameter is 10 to 100 nm,
a Brunauer-Emmett-Teller surface area (S BET ) is 80 to 250 m 2 /g, and an external specific surface area (S EXT ) is 60 to 200 m 2 /g according to an analysis of nitrogen adsorption/desorption, and
a volume of micropores (V micro ) having a pore size of less than 2 nm calculated from the S BET by a t-plot method is less than 0.05 cm 3 /g:
M x/n [(AlO 2 ) x ,(SiO 2 ) y ]. m (H 2 O)  [Chemical Formula 1]

wherein, in Chemical Formula 1,
M is an element selected from the group consisting of Li, Na, K, Rb, Cs, Be, and Fr, or an ion thereof;
x>0, y>0, n>0, and m≥0;
1.0≤y/x≤5.0; and
0.5≤x/n≤1.2.

2. The reinforcing material for rubber of claim 1 ,
wherein the aluminosilicate particles satisfy 0.8≤S EXT /S BET ≤1.0.

3. A rubber composition for tires comprising the reinforcing material for rubber of claim 1 .

4. The rubber composition for tires of claim 3 ,
wherein the composition comprises the reinforcing material for rubber and at least one diene elastomer.

5. The rubber composition for tires of claim 4 ,
wherein the diene elastomer is at least one compound selected from the group consisting of a natural rubber, polybutadiene, polyisoprene, a butadiene/styrene copolymer, a butadiene/isoprene copolymer, a butadiene/acrylonitrile copolymer, an isoprene/styrene copolymer, and a butadiene/styrene/isoprene copolymer.

Assignees

• Lg Chemical Ltd

Inventors

• Jun Shin Hee
• Lee Ha Na
• Choi Kwon Il
• Kim Woo Seok
• Jeong Han Nah
• Oh Myounghwan

Classifications

• C08L21/00

  Compositions of unspecified rubbers · CPC title

• C08L9/00

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08L7/00

  Compositions of natural rubber · CPC title

• C08K2201/006

  Additives being defined by their surface area · CPC title

• C08K2201/005

  Additives being defined by their particle size in general · CPC title