Method for manufacturing aerogel

Patent metadata

Field	Value
Publication number	US-10875776-B2
Application number	US-201916447102-A
Country	US
Kind code	B2
Filing date	Jun 20, 2019
Priority date	Nov 11, 2014
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

In a method for manufacturing an aerogel, an acid is added to a first aqueous high-molar-ratio silicate solution that includes silica particles having a mean particle diameter of from 1 nm to 10 nm and that is alkaline, to produce a gel. The gel is subjected to a dehydration condensation to obtain a hydrogel. The hydrogel is converted into a hydrophobized gel. Then, the hydrophobized gel is dried. According to the method, an aerogel having a pore volume of from 3.00 cc/g to 10 cc/g, a mean pore diameter of from 10 nm to 68 nm, and a specific surface area of from 200 m 2 /g to 475 m 2 /g can be prepared.

First claim

What is claimed is:

1. A method for manufacturing an aerogel, comprising:
adding an acid to a first aqueous silicate solution that includes silica particles having a mean particle diameter of from 1 nm to 10 nm and that is alkaline, to produce a gel;
subjecting the gel to a dehydration condensation to obtain a hydrogel;
converting the hydrogel into a hydrophobized gel; and
drying the hydrophobized gel,
wherein the first aqueous silicate solution includes SiO 2 and Na 2 O, and a molar ratio of SiO 2 to Na 2 O is from 15 to 30.

2. The method for manufacturing an aerogel according to claim 1 , wherein a silicate concentration of the first aqueous silicate solution is 10 wt% or more.

3. The method for manufacturing an aerogel according to claim 1 , wherein the first aqueous silicate solution includes 10 wt% to 20 wt% of SiO 2 , and 1 wt% or less of Na 2 O.

4. The method for manufacturing an aerogel according to claim 1 , further comprising:
adding an acid to a second aqueous silicate solution that is water glass, to produce a by-product salt; and
by bringing the second aqueous silicate solution, in which the by-product salt is produced, into contact with a pressure-driven semipermeable membrane, concentrating the second aqueous silicate solution, and separating and removing the byproduct salt therefrom, to provide the first aqueous silicate solution.

5. The method for manufacturing an aerogel according to claim 1 , wherein the subjecting the gel to obtain the hydrogel further includes curing the hydrogel at a temperature equal to or greater than 80° C. and equal to or less than 100° C.

6. The method for manufacturing an aerogel according to claim 1 , wherein the subjecting the gel to obtain the hydrogel further includes curing the hydrogel at a temperature equal to or greater than 80° C. and equal to or less than 100° C. for longer than 4.5 hours and for 94 hours or less.

7. The method for manufacturing an aerogel according to claim 1 , wherein the aerogel has a pore volume of 3.00 cc/g to 10 cc/g, a mean pore diameter of 10 nm to 68 nm, and a specific surface area of 200 m 2 /g to 475 m 2 /g.

8. The method for manufacturing an aerogel according to claim 1 , wherein the aerogel has a pore volume of 3.00 cc/g to 10 cc/g, a mean pore diameter of 19.2 nm to 68 nm, and a specific surface area of 200 m 2 /g to 422 m 2 /g.

9. The method for manufacturing an aerogel according to claim 1 , wherein the aerogel has a pore volume of 3.00 cc/g to 3.69 cc/g, a mean pore diameter of 19.2 nm to 42.7 nm, and a specific surface area of 315 m 2 /g to 422 m 2 /g.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Sakatani Shigeaki
• Oikawa Kazuma

Classifications

• C01B33/16 Primary

  Preparation of silica xerogels · CPC title

• C01P2006/12

  Surface area · CPC title

• C01P2006/14

  Pore volume · CPC title

• C01P2006/16

  Pore diameter · CPC title

• C01B33/1585 Primary

  Dehydration into aerogels · CPC title