Method for storage or transportation of graphene oxide

Patent metadata

Field	Value
Publication number	US-10875773-B2
Application number	US-201916381519-A
Country	US
Kind code	B2
Filing date	Apr 11, 2019
Priority date	Apr 11, 2019
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

The present disclosure relates to a method for storage or transportation of graphene oxide. The method for storage or transportation of graphene oxide comprises the steps of: carrying out wet spinning of a graphene oxide spinning solution to a coagulating bath to obtain graphene oxide pellets; drying the obtained graphene oxide pellets; storing or transporting the dried graphene oxide pellets; and redispersing the stored or transported graphene oxide pellets.

First claim

What is claimed is:

1. A method for storing or transporting graphene oxide, comprising the steps of:
injecting a graphene oxide spinning solution to a coagulating bath to obtain graphene oxide pellets;
drying the obtained graphene oxide pellets;
storing or transporting the dried graphene oxide pellets; and
redispersing the stored or transported graphene oxide pellets,
wherein the coagulating bath comprises water and ethanol at a volume ratio of 0.1-10:1.

2. The method according to claim 1 , wherein the graphene oxide spinning solution comprises 0.1-25 wt % of graphene oxide in a solvent.

3. The method according to claim 2 , wherein the solvent for the graphene oxide spinning solution is selected from the group consisting of water, dimethyl formamide, methanol, ethanol, dimethyl pyrrolidinone, tetrahydrofuran, and a combination thereof.

4. The method according to claim 1 , wherein the graphene oxide spinning solution is injected to the coagulating bath at an injection rate of 0.1-50 mL/min.

5. The method according to claim 1 , wherein the coagulating bath further comprises dimethyl pyrrolidinone, tetrahydrofuran, or a combination thereof.

6. The method according to claim 1 , wherein the coagulating bath comprises a coagulating agent, and the coagulating agent comprises a quaternary ammonium salt represented by the following Chemical Formula 1 or a metal salt represented by the following Chemical Formula 2:
[Chemical Formula 1]

[Chemical Formula 2]
M m Y n

wherein R 1 is a C1-C18 linear or branched saturated alkyl group; R 2 and R 3 are the same or different, and each represents a C1-C18 linear or branched saturated or unsaturated alkyl group or aromatic hydrocarbon; R 4 represents H, methyl or ethyl group; and X represents an anion capable of being bound to a quaternary ammonium cation; and
M is an alkali metal or alkaline earth metal; Y represents an anion capable of being bound to an alkali metal or alkaline earth metal; m is an integer of 1-2; and n is an integer of 1-4.

7. The method according to claim 6 , wherein the coagulating agent is selected from the group consisting of cetyl trimethyl ammonium bromide (CTAB), cetyl trimethyl ammonium chloride (CTAC), dodecyl trimethyl ammonium bromide (DTAB), tetradecyl trimethyl ammonium bromide (TTAB), dioctadecyl dimethyl ammonium bromide (DODAB), dimethyl dioctadecyl ammonium chloride (DODMAC), calcium chloride, and a combination thereof.

8. The method according to claim 1 , wherein the step of redispersing comprises a solvent selected from the group consisting of water, ethanol, dimethyl pyrrolidinone, tetrahydrofuran, and a combination thereof.

9. The method according to claim 1 , wherein the step of redispersing comprises a surfactant selected from the group consisting of polyvinyl pyrrolidone (PVP), Triton X-100, Xanthan gum, sodium cholate, Pluronic F127, sodium dodecylbenzene sulfonate, and a combination thereof.

10. The method according to claim 1 , wherein the redispersion is carried out by ultrasonication.

11. A method for storing or transporting graphene oxide, comprising the steps of:
injecting a graphene oxide spinning solution to a coagulating bath to obtain graphene oxide pellets;
drying the obtained graphene oxide pellets;
storing or transporting the dried graphene oxide pellets; and
redispersing the stored or transported graphene oxide pellets,
wherein:
the graphene oxide spinning solution comprises 1-5 wt % of graphene oxide in a solvent;
the solvent for the graphene oxide spinning solution is water;
the graphene oxide spinning solution is injected to the coagulating bath at an injection rate of 3-7 mL/min;
the coagulating bath comprises water and ethanol at a volume ratio of 0.5-2:1;
the coagulating bath includes cetyl trimethyl ammonium bromide as a coagulating agent;
the solvent for redispersion is water;
a surfactant used for redispersion is sodium cholate; and
the redispersion is carried out by ultrasonication.

Assignees

• Univ Cornell
• Jmc Corp

Inventors

• Joo Yong Lak
• Chang Chao-Wen
• Zamani Somayeh
• Jung Wonsik
• Kang Taechung
• Park Sangjoon

Classifications

• B01F31/80

  Mixing by means of high-frequency vibrations above one kHz, e.g. ultrasonic vibrations · CPC title

• B01F2101/2204

  Mixing chemical components in generals in order to improve chemical treatment or reactions, independently from the specific application · CPC title

• C01B32/198 Primary

  Graphene oxide · CPC title

• C01P2006/40

  Electric properties · CPC title

• C01B2204/22

  Electronic properties · CPC title