Recycling carbon fiber based materials

Patent metadata

Field	Value
Publication number	US-10875213-B2
Application number	US-201616063506-A
Country	US
Kind code	B2
Filing date	Dec 14, 2016
Priority date	Dec 18, 2015
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

A process is provided to reclaim carbon fiber from a cured vinyl ester, crosslinked unsaturated polyester, or epoxy thermoset matrix. The composite pieces are added to a polyol solvent composition under to conditions to free more than 95% by weight of the carbon fiber from the composite. The freed carbon fibers are washed and dried to reclaim carbon fiber reusable to reinforce a polymer to form a new FRC article. Solvents are chosen that are low cost and low toxicity. Processing is further facilitated by techniques such as solvent pre-swell of the particles, microwave heating, and sonication to promote thermoset matrix digestion to free reinforcing carbon fibers.

First claim

The invention claimed is:

1. A process to reclaim carbon fiber from a cured thermoset matrix comprising:
adding the cured thermoset matrix to a polyol solvent composition under conditions to free more than 95% by weight of the carbon fiber from the cured thermoset matrix, wherein the polyol solvent composition is selected from a group consisting of monosaccharides, disaccharides, sugar alcohols, ethylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, diethylene, glycol, diethylene glycol monoethyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, triethylene glycol, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, tetraethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, 1,5-pentanediol, glycerol, or dipropylene glycol;
washing the carbon fiber with water; and
drying the carbon fiber to reclaim the carbon fiber wherein more than 97% by weight of the carbon fiber is freed from said thermoset matrix and wherein more than 99% by weight of the freed carbon fiber is reclaimed;
wherein said conditions comprise a constant temperature of between 125 and 250 degrees Celsius.

2. The process of claim 1 wherein more than 99% by weight of the carbon fiber is freed from said thermoset matrix.

3. The process of claim 1 wherein said polyol solvent composition comprises more than 95% total weight percent of diethylene glycol monomethyl ether.

4. The process of claim 1 wherein said conditions further comprise an inert gas blanket.

5. The process of claim 1 further comprising swelling said thermoset matrix prior to said adding step.

6. The process of claim 1 further comprising exposing said thermoset matrix to microwave radiation.

7. The process of claim 6 wherein said exposing is prior to said adding step.

8. The process of claim 6 wherein said exposing is after said adding step and prior to said washing step.

9. The process of claim 1 further comprising sonicating said thermoset matrix in said polyol solvent composition.

10. The process of claim 1 further comprising grinding the cured thermoset matrix containing at least 4.5 kilograms of carbon fiber inclusions to form particles prior to the addition of the thermoset matrix to the polyol solvent composition.

11. A process to reclaim carbon fiber from a cured thermoset matrix comprising:
adding the cured thermoset matrix to a polyol solvent composition under to conditions to free more than 95% by weight of the carbon fiber from the cured thermoset matrix;
washing the carbon fiber with water; and
drying the carbon fiber to reclaim the carbon fiber;
wherein said polyol solvent composition is molten glucose.

12. The process of claim 11 wherein said polyol solvent composition further comprises a sugar alcohol.

13. The process of claim 11 wherein said polyol solvent composition further comprises a monosaccharide or disaccharide dissolved in a glycol.

14. The process of claim 13 wherein said glycol in an aqueous solution.

Assignees

• Continental Structural Plastics Inc

Inventors

• Guha Probir Kumar
• Siwajek Michael
• Krug David J

Classifications

• B09B3/70

  Chemical treatment, e.g. pH adjustment or oxidation (involving an extraction step B09B3/80) · CPC title

• Y02W30/62

  Plastics recycling; Rubber recycling · CPC title

• C08J11/24

  containing hydroxyl groups · CPC title

• B29K2105/06

  containing reinforcements, fillers or inserts · CPC title

• B29K2307/04

  Carbon · CPC title