Silver particle producing method, silver particles, and silver paste

Patent metadata

Field	Value
Publication number	US-10875097-B2
Application number	US-201615746902-A
Country	US
Kind code	B2
Filing date	Jul 22, 2016
Priority date	Jul 24, 2015
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

First, a liquid mixture is obtained by mixing at least a silver compound, a reductant, and a dispersant (S1). Then, the liquid mixture is heated to cause reaction between the silver compound and the reductant and generate first silver particles each having a sheet-like or plate-like shape and second silver particles each having a spherical shape or a shape closer to a sphere than the first silver particles and a particle diameter smaller than a maximum value of a length of a side of each of the first silver particles (S2).

First claim

The invention claimed is:

1. A silver particle producing method comprising:
obtaining a liquid mixture by mixing a silver compound, a reductant, a dispersant, and water; and
heating the liquid mixture to cause reaction between the silver compound and the reductant and generate first silver particles and second silver particles, the first silver particles each having a sheet-like or plate-like shape, and the second silver particles each having a spherical shape or a shape closer to a sphere than the first silver particles and a particle diameter smaller than a maximum value of a length of a side of each of the first silver particles, wherein
the reductant is N,N-dimethylformamide,
the reaction between the silver compound and the reductant is caused at a reaction temperature not lower than 100° C. and lower than 150° C.,
an amount of the silver compound is at least 0.1 parts by weight and no greater than 20 parts by weight relative to 100 parts by weight of the liquid mixture,
an amount of the reductant is at least 10 parts by weight and smaller than 100 parts by weight relative to 100 parts by weight of the liquid mixture,
an amount of the dispersant is at least 0.1 parts by weight and no greater than 20 parts by weight relative to 100 parts by weight of the liquid mixture, and
an amount of the water is at least 40 parts by weight and smaller than 100 parts by weight relative to 100 parts by weight of the liquid mixture.

2. The silver particle producing method according to claim 1 , wherein
the reaction between the silver compound and the reductant is caused under atmospheric pressure.

3. The silver particle producing method according to claim 1 , further comprising
after generating the first silver particles and the second silver particles through the reaction between the silver compound and the reductant, isolating the first silver particles and the second silver particles by centrifugal separation, wherein
among the first silver particles and the second silver particles isolated by the centrifugal separation, the number of the second silver particles is larger than the number of the first silver particles.

4. The silver particle producing method according to claim 1 , wherein
an average value of the lengths of the sides of the first silver particles is at least 100 nm and no greater than 800 nm, and
an average value of the particle diameters of the second silver particles is at least 10 nm and no greater than 100 nm.

5. The silver particle producing method according to claim 1 , wherein
the length of the side of each of the first silver particles is at least 10 nm and no greater than 800 nm.

6. The silver particle producing method according to claim 5 , wherein
the first silver particles include silver particles having a triangular contour and silver particles having a hexagonal contour.

7. The silver particle producing method according to claim 6 , wherein
a rate of the silver particles having the triangular contour is larger than a rate of the silver particles having the hexagonal contour.

8. The silver particle producing method according to claim 6 , wherein
a maximum value of a length of a side of each of the silver particles having the triangular contour is at least 50 nm.

9. The silver particle producing method according to claim 6 , wherein
a maximum value of a length of a side of each of the silver particles having the hexagonal contour is at least 30 nm.

10. The silver particle producing method according to claim 1 , wherein
the particle diameter of each of the second silver particles is at least 20 nm and no greater than 150 nm.

11. The silver particle producing method according to claim 1 , wherein
a thickness of each of the first silver particles is at least 10 nm and no greater than 100 nm.

12. The silver particle producing method according to claim 11 , wherein
the thickness of each of the first silver particles is no greater than 30 nm.

13. A silver paste producing method comprising:
washing the first silver particles and the second silver particles produced by the method according to claim 1 ; and
dispersing in an organic solvent the first silver particles after the washing and the second silver particles after the washing.

Assignees

• Univ Osaka

Inventors

• Suganuma Katsuaki
• Jiu Jinting

Classifications

• B22F1/054

  Nanosized particles · CPC title

• B22F1/056

  Submicron particles having a size above 100 nm up to 300 nm · CPC title

• B22F1/0553

  Complex form nanoparticles, e.g. prism, pyramid, octahedron · CPC title

• B22F1/0551

  Flake form nanoparticles · CPC title

• B22F1/0545

  Dispersions or suspensions of nanosized particles · CPC title