Additives for suppressing dendritic growth in batteries

Patent metadata

Field	Value
Publication number	US-10873107-B2
Application number	US-201816050987-A
Country	US
Kind code	B2
Filing date	Jul 31, 2018
Priority date	Aug 1, 2017
Publication date	Dec 22, 2020
Grant date	Dec 22, 2020

Abstract

Battery electrolytes comprising: (a) a solvent suitable for use in a battery electrolyte such as an organic liquid solvent or an ionic liquid; (b) a lithium ion or sodium ion salt suitable for use in a battery electrolyte; and (c) a dispersion of nanoparticles of carbon, metal or metalloid oxides or hydroxides, carbides, nitrides, sulfides, graphene or MXene particles; or a combination thereof. The present invention is also directed to battery cells and batteries comprising these electrolytes and devices comprising these battery cells and batteries.

First claim

What is claimed is:

1. A battery cell having an electrolyte comprising:
(a) sodium or lithium ions; and
(b) nanoparticles selected from the group consisting of nanodiamonds and alliform carbon, or a combination thereof.

2. The battery cell of claim 1 , wherein the battery cell is a lithium-ion battery cell, a lithium-sulfur battery cell, a lithium-air battery cell, or a sodium-ion battery cell.

3. The battery cell of claim 1 , wherein the electrolyte comprises lithium ions.

4. The battery cell of claim 3 , wherein the lithium ions are present as complexes selected from the group consisting of lithium hexafluorophosphate (LiPF 6 ), lithium hexafluoroarsenate monohydrate (LiAsF 6 ), lithium perchlorate (LiClO 4 ), lithium tetrafluoroborate (LiBF 4 ), lithium triflate (LiCF 3 SO 3 ), lithium bis(oxalate)borate (LiBOB), lithium bis(trifluoromethane) sulfonamide (LiTFSI), lithium bis(fluorosulfonyl)imide (LiFSI), lithium iron phosphate (LFP, LiFePO 4 ), and a mixture thereof.

5. The battery cell of claim 1 , wherein the electrolyte comprises sodium ions.

6. The battery cell of claim 5 , wherein the sodium ions are present as complexes selected from the group consisting of sodium hexafluorophosphate (NaPF 6 ), sodium hexafluoroarsenate monohydrate (NaAsF 6 ), sodium perchlorate (NaClO 4 ), sodium tetrafluoroborate (NaBF 4 ), sodium triflate (NaCF 3 SO 3 ), sodium bis(oxalate)borate (NaBOB), sodium bis(trifluoromethane)sulfonamide (NaTFSI), sodium bis(fluorosulfonyl)imide (NaFSI), sodium iron phosphate (NaFP, NaFePO 4 ) and a mixture thereof.

7. The battery cell of claim 1 , wherein the electrolyte comprises an organic solvent selected from the group consisting of ethylene carbonate, diethyl carbonate, dimethyl carbonate, dioxolane, dimethoxyethane, and a combination thereof, containing the ion complexes.

8. The battery cell of claim 1 , wherein the electrolyte comprises an ionic liquid.

9. The battery cell of claim 8 , wherein the ionic liquid comprises an alkyl-substituted imidazolium cation, a pyridinium cation, or a combination thereof.

10. The battery cell of claim 9 , wherein the ionic liquid comprises a hexafluorophosphate (PF 6 − ), a tetrafluoroborate (BF 4 − ), a bistriflimide [(CF 3 SO 2 ) 2 N] − , or a dicyanamide (DCI − ) anion.

11. The battery cell of claim 1 , which when operating, exhibits less growth of lithium or sodium dendrites relative to a corresponding battery absent the presence of the nanoparticles, graphene, or MXene particles.

12. A battery comprising at least two battery cells of claim 1 .

13. An electronic device comprising the battery cell of claim 1 or the battery of claim 12 , wherein the electronic device is selected from the group consisting of an electric vehicle, a cell phone, a computer, a tablet computer, a portable media player, a digital music player, a camera, an e-reader and a video player.

Assignees

• Univ Drexel

Inventors

• Gogotsi Yury
• Zhao Meng-Qiang
• Cheng Xin-Bing

Classifications

• H01M2300/0028

  characterised by the solvent · CPC title

• H01M2300/0045

  Room temperature molten salts comprising at least one organic ion · CPC title

• H01M10/054

  Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium · CPC title

• H01M10/0567

  characterised by the additives · CPC title

• H01M10/0568

  characterised by the solutes · CPC title