Process for isolation of hemicelluloses from biomass pulping process waters or spent liquors

Patent metadata

Field	Value
Publication number	US-10870947-B2
Application number	US-201716326769-A
Country	US
Kind code	B2
Filing date	Jul 27, 2017
Priority date	Sep 2, 2016
Publication date	Dec 22, 2020
Grant date	Dec 22, 2020

Abstract

The invention relates to a process for isolation of hemicelluloses from biomass pulping process waters or spent liquors with removal of suspended solids, concentration of the product and purification of the product by removal of inorganic salts and low molecular weight substances. It is characterized in that the hemicellulose isolation process conditions at several separation/purification stages are adjusted separately by e.g. pH adjustment. The invention further relates to a plant for carrying out the process. With such process and plant it is possible to recover most of the suspended solids, especially xylan and other hemicelluloses.

First claim

The invention claimed is:

1. Process for isolation of hemicelluloses from biomass pulping process waters or spent liquors with removal of suspended solids, comprising the steps of:
(a) providing an incoming stream (A) containing hemicellulose and coarse suspended solids having a size greater than 10 microns, fine suspended solids having a size within a range of 5-10 microns and colloidal substances, the incoming stream (A) having a pH;
(b) adjusting the pH of the incoming stream (A) to yield a pH-adjusted incoming stream (C) having a pH within a range of 8-11;
(c) feeding the pH-adjusted incoming stream (C) to a filtration unit for removal of coarse suspended solids (I) to produce a clear fluid stream (G) having a pH;
(d) adjusting the pH of the clear fluid stream (G) to a pH within the range of 8-11 to dissolve hemicelluloses to form a fraction (G′) having dissolved inorganic salts;
(e) removing fine solid particles having a size within a range of 5-10 microns and colloidal substances from the fraction (G′) to form an alternate fraction (J);
(f) enriching hemicelluloses in the alternate fraction (J) to form a concentrate (L);
(g) adjusting the pH of the concentrate (L) to a pH within a range of 4.0-4.5 to form a stream (N) having inorganic salts; and
(h) removing inorganic salts from the stream (N) to form a final product.

2. The process of claim 1 , wherein the final product after step (h) has a dryness of 15-30%.

3. The process of claim 2 , wherein the pH-adjusted incoming stream (C) has a pH within a range of 9.0-9.5.

4. The process of claim 2 , wherein hemicelluloses that are dissolved in step (d) are hemicelluloses that are precipitated on fine suspended solids.

5. The process of claim 4 , wherein the final product after step (h) has a dryness of 15-30%.

6. The process of claim 5 , wherein the pH-adjusted incoming stream (C) has a pH within a range of 9.0-9.5.

7. The process of claim 4 , wherein the pH-adjusted incoming stream (C) has a pH within a range of 9.0-9.5.

8. The process of claim 2 , wherein the fine solid particles having a size within a range of 5-10 micron are removed via a decanter centrifuge.

9. The process of claim 1 , wherein the pH-adjusted incoming stream (C) has a pH within a range of 9.0-9.5.

10. The process of claim 9 , wherein hem icelluloses that are dissolved in step (d) are hemicelluloses that are precipitated on fine suspended solids.

11. The process of claim 1 , wherein hemicelluloses that are dissolved in step (d) are hemicelluloses that are precipitated on fine suspended solids.

12. The process of claim 1 , wherein the fine solid particles having a size within a range of 5-10 micron are removed via a decanter centrifuge.

Assignees

• Andritz Ag Maschf

Inventors

• Shagaev Oleg
• Wiesegger Lukas

Classifications

• D21C11/00 Primary

  Regeneration of pulp liquors {or effluent waste waters} · CPC title

• D21C11/10

  Concentrating spent liquor by evaporation (evaporators B01D) · CPC title

• Y02E50/10

  Biofuels, e.g. bio-diesel · CPC title

• D21C11/0085

  Introduction of auxiliary substances into the regenerating system in order to improve the performance of certain steps of the latter, the presence of these substances being confined to the regeneration cycle (introduction of compounds in order to make up for the losses of pulping agents D21C11/0035; conventional causticizing of green liquors D21C11/0064; fractionating of spent liquors D21C11/0042) · CPC title

• D21C11/04

  of alkali lye · CPC title