Bulk metallic glass interference layers

Patent metadata

Field	Value
Publication number	US-10870904-B2
Application number	US-201715648249-A
Country	US
Kind code	B2
Filing date	Jul 12, 2017
Priority date	Jul 14, 2016
Publication date	Dec 22, 2020
Grant date	Dec 22, 2020

Abstract

BMG parts having an uniform and consistently thick metal oxide layer. The metal oxide layer, also known as an interference layer, exhibits a consistent color and durability over the entire surface of the part. Methods and devices involved in forming the BMG parts with uniformly thick interference layers are also provided.

First claim

What is claimed is:

1. A part comprising:
a body composed of an amorphous alloy; and
a metal oxide layer formed on at least a portion of a surface of the body, the metal oxide layer having a uniform thickness in a range of 5 nm to 3 μm and configured to produce an optical interference effect and the portion of the surface of the body having an average roughness value (Ra) greater than 0.05 microns and less than or equal to 3 microns.

2. The part of claim 1 , wherein the average roughness value (Ra) of the portion of the surface of the body is greater than 0.05 microns and less than or equal to 0.25 microns.

3. The part of claim 2 , wherein the average roughness value (Ra) of the portion of the surface of the body is greater than or equal to 0.25 microns and less than or equal to 3 microns.

4. The part of claim 1 , wherein the thickness of the metal oxide layer is uniform to within 10%.

5. The part of claim 4 , wherein the metal oxide layer is formed over an entirety of the surface of the body.

6. The part of claim 1 , wherein the thickness of the metal oxide layer is uniform to within 5%.

7. The part of claim 1 , wherein the thickness of the metal oxide layer is uniform to within 1%.

8. The part of claim 1 , wherein the amorphous alloy is a bulk metallic glass.

9. The part of claim 8 , wherein the bulk metallic glass comprises at least 40 wt % zirconium.

10. A portable electronic device comprising a housing and a cover glass, an external surface of the housing being defined by a metal oxide layer grown on at least a portion of an external surface of a bulk metallic glass housing component, the metal oxide layer having a uniform thickness in a range of 5 nm to 3 μm and configured to produce an optical interference effect and the portion of the external surface of the bulk metallic glass housing component having an average roughness value (Ra) greater than 0.05 microns and less than or equal to 3 microns.

11. The portable electronic device of claim 10 , wherein the bulk metallic glass housing component comprises a bulk metallic glass alloy having at least 40% by weight zirconium.

12. The portable electronic device of claim 10 , wherein the average roughness value (Ra) of the portion of the external surface of the bulk metallic glass housing component is greater than or equal to 0.25 microns and less than or equal to 3 microns.

13. The portable electronic device of claim 10 , wherein the portion of the external surface of the bulk metallic glass housing component is uniformly rough.

14. The portable electronic device of claim 10 , wherein the thickness of the metal oxide layer is uniform to within 15%.

15. The portable electronic device of claim 10 , wherein:
the portion of the external surface of the bulk metallic glass housing component is a first portion of the external surface of the bulk metallic glass housing component;
a text or a graphic feature is engraved into a second portion of the external surface of the bulk metallic glass housing component; and
the text or the graphic feature has a different hue than the external surface of the housing.

16. A method of making the product of claim 1 , the method comprising:
creating a uniformly roughened surface on at least a portion of a bulk metallic glass based article, the uniformly roughened surface having an average roughness value (Ra) greater than 0.05 microns and less than or equal to 3 microns; and
oxidizing the uniformly roughened surface of the bulk metallic glass based article at a desired set-point temperature to form a metal oxide layer having a uniform thickness in a range of 5 nm to 3 μm and configured to produce an optical interference effect.

17. The method of claim 16 , wherein the uniformly roughened surface extends across an entirety of an external surface of the bulk metallic glass based article.

18. The method of claim 17 , wherein the bulk metallic glass based article includes zirconium.

19. The method of claim 16 , wherein the uniformly roughened surface is prepared by media blasting, tumbling, and/or etching.

20. The method of claim 16 , wherein the uniformly roughened surface is created during injection molding.

Assignees

• Crucible Intellectual Prop Llc

Inventors

• Stevick Joseph W
• Lopez Adrian

Classifications

• C22C45/10 Primary

  with molybdenum, tungsten, niobium, tantalum, titanium, or zirconium {or Hf} as the major constituent · CPC title

• C22C1/11 Primary

  Making amorphous alloys · CPC title

• C22C45/001

  with Cu as the major constituent · CPC title

• C22C16/00

  Alloys based on zirconium · CPC title

• C22C45/08

  with aluminium as the major constituent · CPC title