Coated pigments for coloring PVC

Patent metadata

Field	Value
Publication number	US-10870743-B2
Application number	US-201314648464-A
Country	US
Kind code	B2
Filing date	Dec 13, 2013
Priority date	Dec 13, 2012
Publication date	Dec 22, 2020
Grant date	Dec 22, 2020

Abstract

Coated pigments for plastics, as well as processes for production of the pigments, the use thereof for colouring polyvinyl chloride (PVC), processes for colouring PVC, PVC coloured with such coated pigments, and also plastics products including such coated pigments, may include inorganic pigments coated with of at least one of hydroxides of magnesium, hydroxides of calcium, oxides of magnesium, and oxides of calcium.

First claim

What is claimed is:

1. A coated pigment comprising:
inorganic pigment selected from the group consisting of iron oxides, iron oxide hydroxides, zinc ferrites, magnesium ferrites, manganese ferrites, and mixtures thereof; and
at least one of hydroxides and oxides of at least one of magnesium and calcium bonded directly to the surface of the core of the inorganic pigment to form coated pigment;
wherein, based on the total weight of the coated pigment, the coated pigment comprises:
3.5% to 30% by weight of magnesium and 0.001% to 0.1% by weight of calcium, or
5.5% to 30% by weight of calcium.

2. The coated pigment according to claim 1 , wherein the coated pigment comprises:
a core consisting of the inorganic pigment; and
a coating surrounding at least a portion of the core and consisting of the hydroxides and/or oxides of magnesium and/or calcium.

3. The coated pigment according to claim 1 , wherein the inorganic pigment is haematite, and the coated pigment has an isoelectric point of <7.

4. The coated pigment according claim 1 , wherein the inorganic pigment is selected from the group consisting of iron oxides, iron oxide hydroxides, zinc ferrites, magnesium ferrites, manganese ferrites, and mixtures thereof, excluding haematite, and the coated pigment has an isoelectric point of 2 to 12.

5. The coated pigment according to claim 1 , wherein the coated pigment comprises 3.5% to 25% by weight of magnesium or 5.5% to 25% by weight of calcium, based on the total weight of the coated pigment.

6. The coated pigment according to claim 1 , wherein the coated pigment comprises 3.5% to 25% by weight of magnesium based on the total weight of the coated pigment.

7. The coated pigment according to claim 1 , wherein:
the at least one of hydroxides and oxides of at least one of magnesium and calcium comprises hydroxides of at least one of magnesium and calcium, and the at least one of magnesium and calcium comprise 5% to 25% by weight of the coated pigment;
the inorganic pigment forms a core of the coated pigment, the hydroxides and oxides define a surrounding layer around the core, and a surface of the core of the inorganic pigment is bonded directly to the surrounding layer; and
wherein,
when the inorganic pigment is haematite, the coated pigment has an isoelectric point of <6.8; or
when the inorganic pigment is iron oxides other than haemetite, iron oxide hydroxides, zinc ferrites, magnesium ferrites, manganese ferrites, or mixtures thereof, the coated pigment has an isoelectric point of 2 to 12.

8. The coated pigment according to claim 1 , wherein the coated pigment comprises 5.5% to 25% by weight, of calcium, based on the total weight of the coated pigment.

9. A plastics product comprising at least one polymer and at least one coated pigment according to claim 1 , wherein at least 50% by weight of the polymer is formed from monomer vinyl chloride.

10. The plastics product according to claim 9 , wherein at least 80% by weight of the polymer is formed from the monomer vinyl chloride.

11. The plastics product according to claim 9 , wherein the polymer is polyvinyl chloride.

12. The plastics product according to claim 11 , wherein the polyvinyl chloride is pulverulent polyvinyl chloride.

13. The plastics product according to claim 11 , wherein the polyvinyl chloride is rigid polyvinyl chloride.

14. The plastics product according to claim 9 , comprising 10% to 90% by weight of the at least one coated pigment.

15. The plastics product according to claim 9 , comprising 20% to 70% by weight of the at least one coated pigment.

16. The plastics product according to claim 9 , comprising 0.1% to 10% by weight of the at least one coated pigment.

17. The plastics product according to claim 9 , comprising 0.5% to 5% by weight of the at least one coated pigment.

18. The plastics product according to claim 9 , comprising 0% to 15% by weight of plasticizer, based on the amount of vinyl chloride present in the plastics product.

19. The plastics product according to claim 9 , comprising 0% to 12% by weight of plasticizer, based on the amount of vinyl chloride present in the plastics product.

20. A process for producing the coated pigment according to claim 1 , the process comprising precipitating the coating onto the inorganic pigment by adding:
at least one of magnesium salts and calcium salts; and
a precipitant selected from the group of alkali metal hydroxides, alkaline earth metal hydroxides, and mixtures thereof,
to an aqueous suspension of the at least one inorganic pigment.

21. The process for producing the coated pigment according to claim 20 , wherein the process comprises one of:
a) precipitating the coating onto the inorganic pigment by adding the at least one of magnesium salts and calcium salts to the aqueous suspension of the at least one inorganic pigment, followed by adding the precipitant, or
b) precipitating the coating onto the inorganic pigment by adding the precipitant to the aqueous suspension of the at least one inorganic pigment, followed by adding the at least one of magnesium salts and calcium salts to the suspension.

22. The process for producing coated pigment according to claim 20 , wherein the at least one of magnesium salts and calcium salts, and the precipitant are added in dissolved form.

23. The process for producing coated pigment according to claim 20 , additionally comprising one, two, three or four of the steps of:
i) isolating the coated pigment,
ii) washing the coated pigment,
iii) drying the coated pigment, and
iv) comminuting the coated pigment.

24. The process for producing coated pigment according to claim 20 , wherein the process does not include a calcination step.

25. A process for producing the plastics products according to claim 11 , the process comprising at least one of kneading or extruding the polyvinyl chloride with the at least one coated pigment.

26. A process for producing the plastics product according to claim 12 , the process comprising mixing the at least one coated pigment and the pulverulent polyvinyl chloride at a temperature just below the melting point of the polyvinyl chloride.

27. A product comprising at least one plastics product according to claim 9 .

28. The product according to claim 27 , wherein the product is one of window profiles, pipes, floor coverings, insulation material or roofing membranes.

Assignees

• Lanxess Deutschland Gmbh

Inventors

• Chlopek Krzysztof
• Meisen Ulrich
• Koenig Ralf Gerhard

Classifications

• C09C1/22

  Compounds of iron {(C09C1/0009, C09C1/0015, C09C1/0078 take precedence)} · CPC title

• C09C1/24

  Oxides of iron · CPC title

• C01P2006/12

  Surface area · CPC title

• C01P2004/84

  one phase coated with the other · CPC title

• C08K5/07

  Aldehydes; Ketones · CPC title