Cast films, and articles made therefrom

Patent metadata

Field	Value
Publication number	US-10870714-B2
Application number	US-201716066868-A
Country	US
Kind code	B2
Filing date	Jan 25, 2017
Priority date	Feb 12, 2016
Publication date	Dec 22, 2020
Grant date	Dec 22, 2020

Abstract

Disclosed herein is a cast film comprising a polyethylene composition comprising the reaction product of ethylene and optionally one or more alpha-olefin comonomers, wherein said polyethylene composition is characterized by the following properties: a melt index, I2, measured according to ASTM D1238 (2.16 kg, 190° C.), of from 1 to 20 g/10 min; a density (measured according to ASTM D792) of from 0.935 to 0.970 g/cm3; a melt flow ratio, I 10 /I 2 , wherein I 10 is measured according to ASTM D1238 (10 kg, 190° C.) of from 5.5 to 7.0; a molecular weight distribution (Mw/Mn) of from 2.2 to 3.5; and a vinyl unsaturation of greater than 0.12 vinyls per one thousand carbon atoms present in the backbone of the composition.

First claim

We claim:

1. A cast film comprising a polyethylene composition comprising a reaction product of ethylene and optionally one or more alpha-olefin comonomers, wherein said polyethylene composition is characterized by the following properties:
a. a melt index, 12, measured according to ASTM D 1238 (2.16 kg, 190° C.), of from 1 to 20 g/10 min;
b. a density (measured according to ASTM D792) of from 0.940 to 0.970 g/cm 3 ;
c. a melt flow ratio, I 10 /I 2 , wherein I 10 is measured according to ASTM D1238 (10 kg, 190° C.) of from 5.5 to 7.0;
d. a molecular weight distribution (M w /M n ) of from 2.2 to 3.5; and
e. a vinyl unsaturation of greater than 0.12 vinyls per one thousand carbon atoms present in a backbone of the polyethylene composition;
and wherein the cast film further comprises a low density polyethylene having a melt index, I 2 range of from 0.1 to 20 g/10 min.

2. The cast film of claim 1 , wherein the cast film comprises from 5 to 30% of the low density polyethylene.

3. The cast film of claim 1 , wherein the polyethylene composition is formed in the presence of a catalyst composition comprising a multi-metallic procatalyst via solution polymerization in at least one reactor.

4. The cast film of claim 3 , wherein the solution polymerization occurs in a single reactor.

5. The cast film of claim 3 , wherein the polyethylene composition has a metal catalyst residual of greater than or equal to 1 parts by combined weight of at least three metal residues per one million parts of polyethylene polymer, wherein the at least three metal residues are selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, and combinations thereof, and wherein each of the at least three metal residues is present at greater than or equal to 0.2 ppm.

6. The cast film of claim 3 , wherein the multi-metallic procatalyst has an Al:Ti ratio of from 6 to 15.

7. The cast film of claim 1 , wherein the cast film is a monolayer film.

8. The cast film of claim 1 , wherein the cast film is a multilayer film.

9. The cast film of claim 1 , wherein the cast film is a cast embossed film.

10. A laminate comprising the cast film of claim 1 .

11. An article made from the cast film according to claim 1 .

Assignees

• Dow Global Technologies Llc

Inventors

• Patel Rajen M
• Degroot Jacquelyn A
• Arteaga Larios Fabricio
• Bensason Selim
• Karjala Teresa P
• Demirors Mehmet
• Lai Chuan Yar

Classifications

• C08K2003/2241

  Titanium dioxide · CPC title

• A61L31/048

  obtained by reactions only involving carbon-to-carbon unsaturated bonds (A61L31/041 takes precedence) · CPC title

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• A61L15/24

  Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof {(A61L15/225 takes precedence)} · CPC title

• C08F4/685

  Vanadium or compounds thereof in combination with titanium or compounds thereof · CPC title