Method for starting a fuel cell and fuel cell system

Patent metadata

Field	Value
Publication number	US-10868317-B2
Application number	US-201515505834-A
Country	US
Kind code	B2
Filing date	Jul 24, 2015
Priority date	Aug 25, 2014
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

A method for starting a fuel cell and to a fuel cell system which is configured to carry out the method. The fuel cell includes electrically conductive bipolar plates, arranged between which there is in each case a cathode, including a fluid-conducting cathode space, a membrane and an anode, including a fluid-conducting anode space. There is provision that the method includes the following steps in the specified order:
purging the anode space with a fluid in order to expel fuel, —impressing electricity on a unit composed of the cathode ( 2 k )/membrane ( 1 )/anode ( 2 a ) by applying a current and/or a voltage, wherein the fluid is applied to the anode space or continues to be so, —switching off the electricity, and —introducing a fuel into the anode space.

First claim

The invention claimed is:

1. A method for operating a fuel cell, the fuel cell including electrically conductive bipolar plates, between which are situated a cathode, including a fluid-conducting cathode chamber, a membrane and an anode, including a fluid-conducting anode chamber, the method comprising the following steps in the specified order:
shutting down the fuel cell by ceasing the flow of fluid into the fuel cell and purging the anode chamber with air such that an anode flow field of the anode chamber is filled with oxygen;
purging the anode chamber with an inert gas in order to expel the oxygen present in the anode flow field of the anode chamber while the flow of fluid into the anode chamber is ceased;
impressing electricity on the fuel cell by applying a current or a voltage, the anode chamber being or continuing to be acted upon by the fluid;
switching off the electricity, and
introducing a fuel into the anode chamber.

2. The method as recited in claim 1 wherein the fluid for purging the anode chamber is nitrogen.

3. The method as recited in claim 1 wherein an intensity of the impressed electricity is controlled by an intensity of the applied voltage or of the applied current.

4. The method as recited in claim 1 wherein a voltage in the range of 0.5 V to 1.5 V is applied or induced.

5. The method as recited in claim 1 wherein a direction of the applied current flow is opposite a direction of the current flow during operation of the fuel cell.

6. The method as recited in claim 1 wherein a current flow of the current is induced for a duration in the range of 0.1 s to 50 s.

7. The method as recited in claim 1 wherein the fuel is introduced with a time delay after the electricity is switched off.

8. The method as recited in claim 1 wherein the oxygen is present in air in the anode chamber.

9. The method as recited in claim 1 wherein the purging forms an inert gas/oxygen front to force the oxygen out of the anode chamber with the inert gas.

10. The method as recited in claim 9 after the purging an entirety of the anode chamber is filled with the inert gas.

11. The method as recited in claim 10 wherein supply of the inert gas continues during the impressing step to reduce platinum oxides at the anode.

12. The method as recited in claim 10 wherein the introducing of the fuel creates a hydrogen/inert gas front.

13. The method as recited in claim 1 wherein during the switching off step, the anode chamber continues to be acted upon by the fluid.

14. The method as recited in claim 1 wherein the purging step is performed for a duration prior to the impressing of electricity.

15. The method as recited in claim 14 wherein the duration is 0.5 min to 1.5 min.

16. The method as recited in claim 14 wherein the purging step is performed for a duration after the impressing of electricity has stopped.

17. The method as recited in claim 16 wherein the duration after the impressing of electricity has stopped is 2 s to 15 s.

18. A fuel cell system comprising:
a fuel cell including two electrically conductive bipolar plates, a cathode, including a fluid-conducting cathode chamber, a membrane and an anode, including a fluid-conducting anode chamber;
a voltage source; and
a control unit, the control unit configured to carry out the method steps as recited in claim 1 .

19. A method for starting a fuel cell, the fuel cell including electrically conductive bipolar plates, between which are situated a cathode, including a fluid-conducting cathode chamber, a membrane and an anode, including a fluid-conducting anode chamber, the method comprising the following steps in the specified order:
purging the anode chamber with a fluid in order to expel oxygen present in the anode chamber;
impressing electricity on the fuel cell by applying a current having a current flow of the current for a duration in the range of 0.1 s to 50 s, the anode chamber being or continuing to be acted upon by the fluid;
switching off the electricity, and
introducing a fuel into the anode chamber.

20. A method for starting a fuel cell, the fuel cell including electrically conductive bipolar plates, between which are situated a cathode, including a fluid-conducting cathode chamber, a membrane and an anode, including a fluid-conducting anode chamber, the method comprising the following steps in the specified order:
purging the anode chamber with an inert gas in order to expel oxygen present in the anode chamber and an amount of hydrogen in order to cause a controlled chemical reduction of the gaseous oxygen located in the anode chamber;
impressing electricity on the fuel cell by applying a current, the anode chamber being or continuing to be acted upon by the inert gas while the current is applied, the impressing electricity being stopped while the purging the anode chamber with the inert gas continues;
switching off the electricity, and
introducing a fuel into the anode chamber.

Assignees

• Volkswagen Ag
• Audi Ag

Inventors

• Kirsch Sebastian
• Zihrul Patrick
• Hartung Ingmar

Classifications

• H01M8/0488

  of fuel cell stacks · CPC title

• H01M8/0491

  of fuel cell stacks · CPC title

• H01M4/926

  on carbon or graphite · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M8/04231 Primary

  Purging of the reactants · CPC title