Cathode slurry for lithium ion battery

Patent metadata

Field	Value
Publication number	US-10868308-B2
Application number	US-201716313875-A
Country	US
Kind code	B2
Filing date	Sep 29, 2017
Priority date	Oct 11, 2016
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

Provided herein is a lithium-ion battery cathode slurry, comprising: a cathode active material, a conductive agent, a binder material, and a solvent, wherein the cathode active material has a particle size D50 in the range from about 10 μm to about 50 μm, and wherein the slurry coated onto a current collector having a wet film thickness of about 100 μm has a drying time of about 5 minutes or less under an environment having a temperature of about 60° C. to about 90° C. and a relative humidity of about 25% to about 40%. The cathode slurry disclosed herein has homogeneous ingredient dispersion and quick drying capability for making a lithium-ion battery with high quality and consistent performance. In addition, these properties of the cathode slurry increase productivity and reduce the cost of manufacturing lithium-ion batteries.

First claim

What is claimed is:

1. A lithium-ion battery cathode slurry, comprising: a cathode active material, a conductive agent, a binder material, and a solvent, wherein the cathode active material has a particle size D50 in the range from about 10 μm to about 50 μm;
wherein the binder material is selected from the group consisting of styrene-butadiene rubber, acrylated styrene-butadiene rubber, acrylonitrile copolymer, acrylonitrile-butadiene rubber, nitrile butadiene rubber, acrylonitrile-styrene-butadiene copolymer, acryl rubber, butyl rubber, fluorine rubber, polytetrafluoroethylene, polyethylene, polypropylene, ethylene/propylene copolymers, polybutadiene, polyethylene oxide, chlorosulfonated polyethylene, polyvinylpyrrolidone, polyvinylpyridine, polyvinyl alcohol, polyvinyl acetate, polyepichlorohydrin, polyphosphazene, polyacrylonitrile, polystyrene, latex, acrylic resins, phenolic resins, epoxy resins, carboxymethyl cellulose, hydroxypropyl cellulose, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethylcellulose, cyanoethylsucrose, polyester, polyamide, polyether, polyimide, polycarboxylate, polycarboxylic acid, polyacrylic acid, polyacrylate, polymethacrylic acid, polymethacrylate, polyacrylamide, polyurethane, fluorinated polymer, chlorinated polymer, polyvinylidene fluoride, poly(vinylidene fluoride)-hexafluoropropene, and combinations thereof;
wherein the solvent is selected from the group consisting of water, pure water, de-ionized water, distilled water, ethanol, isopropanol, methanol, acetone, n-propanol, t-butanol, and combinations thereof; and
wherein the viscosity of the slurry is in the range from 1,500 mPa·s to 3,000 mPa·s.

2. The slurry of claim 1 , wherein the cathode active material has a D10 value of at least 3 μm.

3. The slurry of claim 1 , wherein the cathode active material has a D90 value of less than or equal to 80 μm.

4. The slurry of claim 1 , wherein the cathode active material is present in an amount from 30% to 65% by weight; wherein the conductive agent is present in an amount from 0.8% to 5% by weight; wherein the binder material is present in an amount from 0.5% to 6% by weight; wherein the solvent is present in an amount from 30% to 60% by weight, and wherein all weight % values are based on the total weight of the slurry.

5. The slurry of claim 1 , wherein the cathode active material is selected from the group consisting of LiCoO 2 , LiNiO 2 , LiNi x Mn y O 2 , Li 1+z Ni x Mn y Co 1−x−y O 2 , LiNi x Co y Al z O 2 , LiV 2 O 5 , LiTiS 2 , LiMoS 2 , LiMnO 2 , LiCrO 2 , LiMn 2 O 4 , LiFeO 2 , LiFePO 4 , LiNi 0.5 Mn 1.5 O 4 , LiNi 0.4 Mn 1.6 O 4 , composites thereof, and combinations thereof, wherein each x is independently from 0.3 to 0.8; each y is independently from 0 to 0.45; and each z is independently from 0 to 0.2.

6. The slurry of claim 1 , wherein the conductive agent is selected from the group consisting of carbon, carbon black, graphite, expanded graphite, graphene, graphene nanoplatelets, carbon fibres, carbon nano-fibers, graphitized carbon flake, carbon tubes, carbon nanotubes, activated carbon, mesoporous carbon, and combinations thereof.

7. The slurry of claim 1 , wherein a vapor pressure of the solvent is at least 15 kPa.

8. The slurry of claim 1 , wherein a pH of the slurry is from about 7 to about 11.

9. The slurry of claim 1 , wherein a viscosity of the slurry is in the range from about 1,000 mPa·s to about 4,500 mPa·s.

10. The slurry of claim 1 , wherein the solvent has a boiling point of less than 140° C.

11. The slurry of claim 1 , wherein a ratio D90/D10 of the cathode active material is from about 3 to about 10.

12. The slurry of claim 1 , wherein a particle size distribution of the cathode active material is bimodal with a first peak at about 12 μm and a second peak at about 30 μm.

13. A positive electrode for a lithium-ion battery, the positive electrode comprising: a cathode current collector; and a cathode electrode layer, wherein the cathode electrode layer is the cathode slurry of claim 1 coated on the cathode current collector.

14. A lithium-ion battery comprising: a cathode; an anode; and a separator interposed between the cathode and the anode, wherein at least one of the cathode is the positive electrode of claim 13 .

15. The slurry of claim 1 , wherein the solvent has a boiling point of less than 120° C.

16. The slurry of claim 1 , wherein the solvent has a boiling point of less than 100° C.

17. The slurry of claim 1 , wherein a ratio D90/D10 of the cathode active material is from about 5 to about 8.

Assignees

• Grst Int Ltd

Inventors

• Ho Kam Piu
• Wang Ranshi
• Shen Peihua

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/622

  being polymers · CPC title

• H01M4/1397

  of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title