Safely ingestible batteries and methods

Patent metadata

Field	Value
Publication number	US-10868284-B2
Application number	US-201916504970-A
Country	US
Kind code	B2
Filing date	Jul 8, 2019
Priority date	Mar 13, 2013
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

A battery for use in electronic devices and which is safely ingested into a body and a related method of making the battery. The battery includes an anode, a cathode and a quantum tunneling composite coating. The quantum tunneling composite coating covers at least a portion of at least one of the anode or the cathode and provides pressure sensitive conductive properties to the battery including a compressive stress threshold for conduction. The compressive stress threshold may be greater than a pre-determined applied stress in a digestive tract of the body in order to prevent harm if the battery is ingested. The battery may include a waterproof seal that extends between the quantum tunneling composite coating and a gasket separating the anode and cathode to inhibit the battery from short circuiting in a conductive fluid below the compressive stress threshold.

First claim

The invention claimed is:

1. A battery, comprising:
an anode;
a cathode; and
a pressure-sensitive coating that comprises a quantum tunneling composite covering at least one of the anode and the cathode and providing pressure sensitive conductive properties including a compressive stress threshold such that, when a stress above the compressive stress threshold is applied to the quantum tunneling composite coating, the quantum tunneling composite coating is placed in a conductive state in which electrons are able to tunnel through the quantum tunneling composite coating,
wherein the compressive stress threshold is greater than a pre-determined applied stress associated with a digestive tract of a body.

2. The battery of claim 1 , wherein the battery is a button battery.

3. The battery of claim 1 , wherein, when no stress or a stress below the compressive stress threshold is applied to the quantum tunneling composite coating, the quantum tunneling composite coating is in an insulating state in which electrons are unable to quantum tunnel through the quantum tunneling composite coating.

4. The battery of claim 1 , wherein the quantum tunneling composite coating comprises a polymer matrix with conductive microparticles suspended therein that collectively provide the pressure sensitive conductive properties for the quantum tunneling composite coating.

5. The battery of claim 1 , further comprising a gasket that insulates and separates the anode and the cathode.

6. The battery of claim 1 , wherein the compressive stress threshold has a value between 15.5 N/cm 2 and 19.4 N/cm 2 .

7. The battery of claim 1 , wherein the pressure-sensitive coating is a pressure-gated coating.

8. A battery, comprising:
an anode;
a cathode; and
a pressure-sensitive coating that comprises a quantum tunneling composite covering at least one of the anode and the cathode and providing pressure sensitive conductive properties including a compressive stress threshold such that, when a stress above the compressive stress threshold is applied to the quantum tunneling composite coating, the quantum tunneling composite coating is placed in a conductive state in which electrons are able to tunnel through the quantum tunneling composite coating,
wherein the compressive stress threshold is between 15.5 N/cm 2 and 19.4 N/cm 2 .

9. The battery of claim 8 , wherein the battery is a button battery.

10. The battery of claim 8 , wherein, when no stress or a stress below the compressive stress threshold is applied to the quantum tunneling composite coating, the quantum tunneling composite coating is in an insulating state in which electrons are unable to quantum tunnel through the quantum tunneling composite coating.

11. The battery of claim 8 , wherein the quantum tunneling composite coating comprises a polymer matrix with conductive microparticles suspended therein that collectively provide the pressure sensitive conductive properties for the quantum tunneling composite coating.

12. The battery of claim 8 , further comprising a gasket that insulates and separates the anode and the cathode.

13. The battery of claim 8 , wherein the pressure-sensitive coating is a pressure-gated coating.

14. A battery, comprising:
an anode;
a cathode;
a pressure-sensitive coating that comprises a quantum-tunneling composite coating covering at least one of the anode and the cathode and providing pressure sensitive conductive properties including a compressive stress threshold, the compressive stress threshold being greater than a pre-determined applied stress associated with a digestive tract of a body; and
a gasket separating a part of the anode and the cathode,
wherein the pressure-sensitive coating provides at least a portion of a water-impermeable coating extending to the gasket and fully covering the at least one of the anode and the cathode to leave no exposed surfaces thereby inhibiting the battery from short circuiting in a conductive fluid.

15. The battery of claim 14 , wherein, when a stress above the compressive stress threshold is applied to the quantum tunneling composite coating, the quantum tunneling composite coating is in a conductive state in which electrons are able to quantum tunnel through the quantum tunneling composite coating and, wherein, when no stress or a stress below the compressive stress threshold is applied to the quantum tunneling composite coating, the quantum tunneling composite coating is in an insulating state in which electrons are unable to quantum tunnel through the quantum tunneling composite coating.

16. The battery of claim 15 , wherein the quantum tunneling composite coating comprises a polymer matrix with conductive microparticles suspended therein that collectively provide the pressure sensitive conductive properties for the quantum tunneling composite coating.

17. The battery of claim 16 , wherein the polymer matrix comprises a silicone rubber and the conductive microparticles comprise silver.

18. The battery of claim 14 , wherein the compressive stress threshold has a value between 15.5 N/cm 2 and 19.4 N/cm 2 .

19. The battery of claim 14 , wherein the pressure-sensitive coating is a pressure-gated coating.

20. The battery of claim 14 , wherein the battery is a button battery.

Assignees

• Brigham & Womens Hospital Inc
• Massachusetts Inst Technology
• The Brigham And Womens Hospital

Inventors

• Laulicht Bryan
• Freilich Janet
• Karp Jeffrey M
• Langer Robert

Classifications

• H01M50/593

  Spacers; Insulating plates · CPC title

• H01M50/586

  inside the batteries, e.g. incorrect connections of electrodes · CPC title

• H01M50/469

  tubular or cylindrical · CPC title

• H01M50/186

  characterised by the disposition of the sealing members · CPC title

• H01M50/193

  Organic material · CPC title