Method for manufacturing porous membrane

Patent metadata

Field	Value
Publication number	US-10865286-B2
Application number	US-201615756771-A
Country	US
Kind code	B2
Filing date	Aug 31, 2016
Priority date	Sep 4, 2015
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

To provide a method for manufacturing a polyimide and/or a polyamide imide porous membrane with which it is possible to prepare a varnish in which microparticles are satisfactorily dispersed, even when minute microparticles are used, and to manufacture a porous membrane using the varnish. The method for manufacturing a polyimide and/or a polyamide imide porous membrane comprises a step for preparing a porous membrane manufacturing composition containing microparticles and at least one resin component selected from the group consisting of polyamic acids, polyimides, polyamide imide precursors, polyamide imides, and polyethersulfones, the preparation step including a dispersion step for causing a slurry containing the microparticles to disperse by shear and compression or shock.

First claim

The invention claimed is:

1. A method for manufacturing a porous film, the method comprising:
preparing a composition for producing a porous film containing fine particles, and at least one resin component selected from the group consisting of polyamide acid, polyimide, a polyamide-imide precursor, polyamide-imide and polyethersulfone,
wherein said preparing comprises dispersing a slurry containing the fine particles by a shearing force and a compression or an impact force,
wherein the slurry contains the at least one resin component selected from the group consisting of polyamide acid, polyimide, a polyamide-imide precursor, polyamide-imide and polyethersulfone, and
wherein the porous film has a front surface and a rear surface, and pores communicating the front and rear surfaces with each other.

2. The method according to claim 1 , wherein an average particle diameter of the fine particles is not more than 200 nm.

3. The method according to claim 1 , wherein a content of the fine particles in the slurry is not less than 30% by mass and not more than 90% by mass with respect to a mass of the slurry.

4. The method according to claim 1 , wherein the fine particles are inorganic fine particles.

5. The method according to claim 1 , further comprising:
forming an unburned composite film using the composition for producing a porous film,
burning the unburned composite film to obtain a resin-fine particle composite film, and
removing fine particles from the resin-fine particle composite film.

6. The method according to claim 1 , wherein a film thickness of the porous film is 10 to 500 μm.

7. The method according to claim 1 , wherein the step of dispersing the slurry by a shearing force and a compression or an impact force is carried out by dispersing the slurry using a three-roll mill.

8. The method according to claim 1 , wherein the porous film has fluid permeability because of the pores communicating the front and rear surfaces with each other.

9. The method according to claim 8 , wherein the fluid permeability is air permeability and/or liquid permeability.

10. The method according to claim 5 , wherein the pores communicating the front and rear surfaces with each other are formed by the removing of the fine particles.

11. A method for manufacturing a composition for producing a porous film, the method comprising:
preparing slurry (1) including fine particles and a solvent (1);
preparing a varnish (1) including at least one resin component selected from the group consisting of polyamide acid, polyimide, a polyamide-imide precursor, polyamide-imide and polyethersulfone, and a solvent (2), wherein the solvent (2) may be a same solvent as the solvent (1) or a different solvent from the solvent (1);
preparing slurry (2) by kneading the slurry (1) and the varnish (1),
kneading the prepared slurry (2), and
dispersing the kneaded slurry (2) by a shearing force and a compression or an impact force,
wherein a content of the fine particles is not less than 30% by mass and not more than 90% by mass with respect to the slurry (2).

12. The method according to claim 11 , wherein the step of dispersing the kneaded slurry (2) by a shearing force and a compression or an impact force is carried out by dispersing the kneaded slurry (2) using a three-roll mill.

Assignees

• Tokyo Ohka Kogyo Co Ltd

Inventors

• Sugawara Tsukasa

Classifications

• C08L81/06

  Polysulfones; Polyethersulfones · CPC title

• C08L79/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08J2477/00

  Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers · CPC title

• C08J2381/06

  Polysulfones; Polyethersulfones · CPC title

• C08J2377/00

  Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers · CPC title