Epoxidation process

Patent metadata

Field	Value
Publication number	US-10865189-B2
Application number	US-201916511542-A
Country	US
Kind code	B2
Filing date	Jul 15, 2019
Priority date	Aug 9, 2016
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

A method for the oxidation of ethylene to form ethylene oxide which comprises: providing an aqueous stream containing ethylene glycol and impurities; introducing the aqueous stream in a first ion exchange treatment bed to reduce the content of these impurities; determining whether an outlet of the first ion exchange treatment bed has a conductivity greater than about 5 μS/cm; upon determining that the outlet of the first ion exchange treatment bed has a conductivity greater than about 5 μS/cm, introducing the outlet of the first ion exchange treatment bed into a second ion exchange treatment bed; and upon determining that the outlet of the first ion exchange treatment bed has a conductivity greater than about 60 μS/cm, redirecting the introduction of the aqueous stream to the second ion exchange treatment bed and regenerating the first ion exchange bed.

First claim

We claim:

1. A method for removing impurities, the method comprising:
providing an aqueous stream obtained from a stripping column of an ethylene oxide reactor, the aqueous stream containing ethylene glycol and impurities;
introducing the aqueous stream into a first ion exchange treatment bed to reduce the content of the impurities;
introducing an outlet of the first ion exchange treatment bed into a second ion exchange treatment bed to further reduce the content of the impurities, while keeping the first ion exchange treatment bed on-line and working simultaneously with the second ion exchange treatment bed; and
redirecting, upon determining whether an outlet of the first ion exchange treatment bed has a conductivity greater than about 5 μS/cm, the aqueous stream to the second ion exchange treatment bed and regenerating the first ion exchange bed.

2. The method according to claim 1 , wherein the impurities are selected from long chain esters, formaldehyde, acetaldehyde, glycolaldehyde and their associated acids and ions, and mixtures thereof.

3. The method according to claim 1 , wherein the aqueous stream comprises 0.2 to 20 wt % ethylene glycol.

4. The method according to claim 1 , further comprising the aqueous stream to a glycol purification section.

5. The method according to claim 1 , wherein the first ion exchange treatment bed is operated at a temperature from about 30° C. to about 50° C.

6. The method according to claim 1 , wherein the first and second ion exchange treatment beds contain resins selected from the group consisting of cationic exchange resins, anionic exchange resins, and mixtures thereof.

7. The method according to claim 1 , wherein the regenerating comprises contacting the first ion exchange bed with a regenerant selected from potassium hydroxide, sodium hydroxide, hydrochloric acid, and sulfuric acid.

8. The method according to claim 1 , further comprising initiating an epoxidation reaction by reacting a feed gas composition containing ethylene and oxygen in the presence of an epoxidation catalyst comprising a promoting amount of rhenium, wherein the initiating is performed prior to the providing of the aqueous stream.

9. A method for removing impurities, the method comprising:
providing an aqueous stream obtained from a stripping column of an ethylene oxide reactor, the aqueous stream containing ethylene glycol and impurities;
introducing the aqueous stream into a first ion exchange treatment bed and a second ion exchange treatment bed arranged in series to reduce the content of these impurities, wherein the first ion exchange treatment bed is kept on-line and works simultaneously with the second ion exchange treatment bed; and
redirecting, upon determining whether an outlet of the first ion exchange treatment bed has a conductivity greater than about 5 μS/cm, the aqueous stream to the second ion exchange treatment bed and regenerating the first ion exchange bed.

10. The method according to claim 9 , wherein the impurities are selected from long chain esters, formaldehyde, acetaldehyde, glycolaldehyde and their associated acids and ions, and mixtures thereof.

11. The method according to claim 9 , wherein the aqueous stream comprises 0.2 to 20 wt % ethylene glycol.

12. The method according to claim 9 , further comprises passing the aqueous stream to a glycol purification section.

13. The method according to claim 9 , wherein the first ion exchange treatment bed is operated at a temperature from about 30° C. to about 50° C.

14. The method according to claim 9 , further comprising initiating an epoxidation reaction by reacting a feed gas composition containing ethylene and oxygen in the presence of an epoxidation catalyst comprising a promoting amount of rhenium, wherein the initiating is performed prior to the providing of the aqueous stream.

15. The method according to claim 9 , wherein the first and second ion exchange treatment beds contain resins selected from the group consisting of cationic exchange resins, anionic exchange resins, and mixtures thereof.

Assignees

• Scient Design Co

Inventors

• Mcgovern Shaun
• Husain Mansoor
• Sullivan John

Classifications

• C07D301/03

  by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds · CPC title

• C07C29/76

  by physical treatment · CPC title

• C07D301/32

  Separation; Purification · CPC title

• B01J8/06

  in tube reactors; the solid particles being arranged in tubes · CPC title

• C07D301/36

  Use of additives, e.g. for stabilisation · CPC title