Ethylene-to-liquids systems and methods

Patent metadata

Field	Value
Publication number	US-10865165-B2
Application number	US-201916359792-A
Country	US
Kind code	B2
Filing date	Mar 20, 2019
Priority date	Jun 16, 2015
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.

First claim

What is claimed is:

1. A system, comprising:
an adiabatic ethylene-to-liquids (ETL) reactor configured to operate at a temperature of greater than or equal to about 300° C. and a pressure of 4 bar to 50 bar, and that (i) receives an olefin feed stream at a first temperature, said olefin feed stream comprising (1) ethylene (C 2 H 4 ) at a concentration of at least about 0.5 mole percent (mol %), (2) C 2 H 4 and propylene (C 3 H 6 ) at a combined concentration of at most about 10 mol %, and (3) carbon monoxide (CO) or carbon dioxide (CO 2 ), and (ii) as part of an ETL process, facilitates conversion of C 2 H 4 to higher hydrocarbon products with the aid of an ETL catalyst to yield a product stream comprising said higher hydrocarbon products that is at a second temperature which is higher than said first temperature, wherein said ETL process liberates heat, wherein said higher hydrocarbon products comprise an olefin compound and an aromatic compound; and
a separations module in fluid communication with said adiabatic ETL reactor that recovers from said product stream a liquid stream comprising said higher hydrocarbon products, wherein said higher hydrocarbon products include (i) at least 5 compounds having 5 different carbon numbers, said 5 different carbon numbers selected from 4 through 20, wherein each of said at least 5 compounds is at a concentration of at least 5 weight percent (wt %) of said liquid stream, and (ii) a paraffin compound, an isoparaffin compound, and a naphthene compound,
wherein at least about 80% of said heat liberated in said ETL process provides a difference between said first temperature and said second temperature of between about 50° C. and about 150° C.

2. The system of claim 1 , wherein said 5 different carbon numbers are selected from 4 through 12.

3. The system of claim 1 , wherein said 5 different carbon numbers are selected from 12 through 20.

4. The system of claim 1 , wherein said recovering comprises cooling said product stream.

5. The system of claim 1 , further comprising, upstream of said adiabatic ETL reactor, a treatment unit in fluid communication with said adiabatic ETL reactor, wherein said treatment unit reduces the concentration in said olefin feed stream of (i) compounds having triple bonds or (ii) compounds having more than one double bond, wherein said reducing is accomplished by a separations process or a reaction process.

6. The system of claim 1 , wherein said olefin feed stream comprises less than about 500 parts per million (ppm) of acetylene.

7. The system of claim 1 , further comprising, upstream of said adiabatic ETL reactor, a treatment unit in fluid communication with said ETL reactor, wherein said treatment unit reduces the concentration in said olefin feed stream of compounds having sulfur to less than about 300 parts per million (ppm).

8. The system of claim 1 , wherein said olefin feed stream comprises less than about 10 mol % carbon monoxide (CO).

9. The system of claim 1 , wherein said adiabatic ETL reactor generates said higher hydrocarbon products at a single pass conversion of at least about 40%.

10. The system of claim 1 , wherein said adiabatic ETL reactor is configured to operate at a temperature greater than or equal to about 320° C.

11. The system of claim 1 , wherein said product stream comprises less than 50 weight percent (wt %) water.

12. The system of claim 1 , wherein said ETL reactor operates substantially adiabatically.

13. The system of claim 1 , wherein the concentration of CO 2 in the olefin feed stream is at most about 20 mol %.

14. The system of claim 1 , wherein the combined concentration of CO and CO 2 in the olefin feed stream is at most about 20 mol %.

15. The system of claim 1 , wherein the combined concentration of olefins in the olefin feed stream is at most 8 mol %.

16. The system of claim 1 , wherein the olefin feed stream is a gas.

Assignees

• Lummus Technology Inc

Inventors

• Nyce Greg
• Czerpak Peter
• Faz Carlos
• Mccormick Jarod
• Michalak William
• Patel Bipinkumar
• Radaelli Guido
• Rappold Tim A
• Runnebaum Ron
• Scher Erik C
• Zhang Aihua
• Cizeron Joel

Classifications

• C10G50/00 Primary

  Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title

• B01J2219/00006

  Large-scale industrial plants · CPC title

• B01J2208/00256

  in a heat exchanger for the heat exchange medium separate from the reactor · CPC title

• B01J8/0457

  the beds being placed in separate reactors · CPC title

• Y02P20/582

  Recycling of unreacted starting or intermediate materials · CPC title