Method for producing a dispersant

Patent metadata

Field	Value
Publication number	US-10865144-B2
Application number	US-201615554984-A
Country	US
Kind code	B2
Filing date	Mar 3, 2016
Priority date	Mar 13, 2015
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

The invention relates to a method for producing a dispersant, comprising the steps of
a) providing at least one water-soluble polymer comprising polyether groups, b) providing an inorganic component comprising at least one phyllosilicate which has an integral sheet charge of 0, 1 or 2, c) producing an aqueous suspension comprising the at least one water-soluble polymer comprising polyether groups and the inorganic component comprising the at least one phyllosilicate, and d) spray-drying the aqueous suspension to give a solid. Additionally disclosed is the use of the dispersant of the invention in an inorganic binder composition.

First claim

The invention claimed is:

1. A method for producing a dispersant, comprising the steps of
a) providing at least one water-soluble polymer comprising polyether groups,
b) providing an inorganic component, comprising at least one phyllosilicate which has an integral sheet charge of 0, 1 or 2,
c) preparing an aqueous suspension comprising the at least one water-soluble polymer comprising polyether groups and the inorganic component comprising the at least one phyllosilicate,
d) spray-drying the aqueous suspension to give a solid.

2. The method according to claim 1 , wherein the polyether groups of the at least one water-soluble polymer are polyether groups of structural unit (I),
*—U—(C(O)) k —X-(AlkO) n —W  (I)

where
* indicates the bonding site to the polymer,
U is a chemical bond or an alkylene group having 1 to 8 carbon atoms,
X is oxygen, sulfur or a group NR 1 ,
k is 0 or 1,
n is an integer whose average value based on the polymer is in the range from 3 to 300,
Alk is C 2 -C 4 alkylene, it being possible for Alk to be identical or different within the group (Alk-O) n ,
W is a hydrogen, a C 1 -C 6 alkyl or an aryl radical or is the group Y—F, where
Y is a linear or branched alkylene group having 2 to 8 carbon atoms and may carry a phenyl ring,
F is a 5- to 10-membered nitrogen heterocycle which is bonded via nitrogen and which as ring members, besides the nitrogen atom and besides carbon atoms, may have 1, 2 or 3 additional heteroatoms, selected from oxygen, nitrogen, and sulfur, it being possible for the nitrogen ring members to have a group R 2 , and for 1 or 2 carbon ring members to be present in the form of a carbonyl group,
R 1 is hydrogen, C 1 -C 4 alkyl or benzyl, and
R 2 is hydrogen, C 1 -C 4 alkyl or benzyl.

3. The method according to claim 1 , wherein the water-soluble polymer comprises at least one group from the series consisting of carboxyester, carboxyl, phosphono, sulfino, sulfo, sulfamido, sulfoxy, sulfoalkyloxy, sulfinoalkyloxy, and phosphonooxy.

4. The method according to claim 1 , wherein the water-soluble polymer comprising polyether groups represents a polycondensation product comprising
(II) a structural unit comprising an aromatic or heteroaromatic and the polyether group, and
(III) a phosphated structural unit comprising an aromatic or heteroaromatic.

5. The method according to claim 4 , wherein the structural units (II) and (III) are represented by the following general formulae
A-U—(C(O)) k —X-(AlkO) n —W  (II)

where
A is identical or different and is represented by a substituted or unsubstituted, aromatic or heteroaromatic compound having 5 to 10 carbon atoms in the aromatic system, the other radicals possessing the definition stated for structural unit (I);

where
D is identical or different and is represented by a substituted or unsubstituted, aromatic or heteroaromatic compound having 5 to 10 carbon atoms in the aromatic system
where
E is identical or different and is represented by N, NH or O
where
m=2 if E=N and m=1 if E=NH or O
where
R 3 and R 4 independently of one another are identical or different and are represented by a branched or unbranched C 1 to C 10 alkyl radical, C 5 to C 8 cycloalkyl radical, aryl radical, heteroaryl radical or H
where b
is identical or different and is represented by an integer from 0 to 300.

6. The method according to claim 4 , wherein the polycondensation product comprises a further structural unit (IV) which is represented by the following formula

where
Y independently of one another is identical or different and is represented by (II), (III) or further constituents of the polycondensation product
R 5 and R 6 are identical or different and are represented by H, CH 3 , COOH, or a substituted or unsubstituted, aromatic or heteroaromatic compound having 5 to 10 carbon atoms.

7. The method according to claim 1 , wherein the water-soluble polymer comprising polyether groups represents at least one copolymer which is obtainable by polymerizing a mixture of monomers comprising
(V) at least one ethylenically unsaturated monomer which comprises at least one radical from the series consisting of carboxylic acid, carboxylic salt, carboxylic ester, carboxylic amide, carboxylic anhydride, and carboxylic imide
and
(VI) at least one ethylenically unsaturated monomer comprising the polyether group.

8. The method according to claim 7 , wherein the ethylenically unsaturated monomer (V) is represented by at least one of the following general formulae from the group of (Va), (Vb), and (Vc)

where
R 7 and R 8 independently of one another are hydrogen or an aliphatic hydrocarbon radical having 1 to 20 carbon atoms
B is H, —COOM a , —CO—O(C q H 2q O) r —R 9 , or —CO—NH—(C q H 2q O) r —R 9
M is hydrogen, a mono-, di- or trivalent metal cation, ammonium ion or an organic amine radical
a is ⅓, ½ or 1
R 9 is hydrogen, an aliphatic hydrocarbon radical having 1 to 20 carbon atoms, a cycloaliphatic hydrocarbon radical having 5 to 8 carbon atoms, or an optionally substituted aryl radical having 6 to 14 carbon atoms
q independently of one another for each (C q H 2q O) unit is identical or different and is 2, 3 or 4, and
r is 0 to 200
Z is O, or NR 16
R 16 independently at each occurrence is identical or different and is represented by a branched or unbranched C 1 - to C 10 -alkyl radical, C 5 - to C 8 cycloalkyl radical, aryl radical, heteroaryl radical or H,

where
R 19 and R 11 independently of one another are hydrogen or an aliphatic hydrocarbon radical having 1 to 20 carbon atoms, a cycloaliphatic hydrocarbon radical having 5 to 8 carbon atoms, or an optionally substituted aryl radical having 6 to 14 carbon atoms
R 12 is identical or different and is represented by (C n H 2n )—SO 3 H where n=0, 1, 2, 3 or 4, (C n H 2n )—OH where n=0, 1, 2, 3 or 4; (C n H 2n )—PO 3 H 2 where n=0, 1, 2, 3 or 4, (C n H 2n )—OPO 3 H 2 where n=0, 1, 2, 3 or 4, (C 6 H 4 )—SO 3 H, (C 6 H 4 )—PO 3 H 2 , (C 6 H 4 )—OPO 3 H 2 , or (C n H 2n )—NR 14 b where n=0, 1, 2, 3 or 4 and b=2 or 3
R 13 is H, —COOM a , —OC—O(C q H 2q O) r —R 9 , or —CO—NH—(C q H 2q O) r —R 9 ,
where M a , R 9 , q, and r possess definitions stated above

R 14 is hydrogen, an aliphatic hydrocarbon radical having 1 to 10 carbon atoms, a cycloaliphatic hydrocarbon radical having 5 to 8 carbon atoms, or an optionally substituted aryl radical having 6 to 14 carbon atoms
Q is identical or different and is represented by NH, NR 15 or O; where R 15 is an aliphatic hydrocarbon radical having 1 to 10 carbon atoms, a cycloaliphatic hydrocarbon radical having 5 to 8 carbon atoms, or an optionally substituted aryl radical having 6 to 14 carbon atoms.

9. The method according to claim 1 , wherein the at least one water-soluble polymer comprising polyether groups has an average molar weight (Mw) of between 5000 and 150,000 g/mol, as determined by gel permeation chromatography.

10. The method according to claim 1 , wherein the solid obtained after spray drying is in the form of powder or granule

Assignees

• Basf Se

Inventors

• Gaedt Torben
• Dengler Joachim
• Winklbauer Martin
• Bichler Manfred
• Mazanec Oliver

Classifications

• C04B28/04 Primary

  Portland cements · CPC title

• C04B2103/0057

  added as redispersable powders · CPC title

• C04B24/281 Primary

  Polyepoxides · CPC title

• C08J3/12

  Powdering or granulating · CPC title

• C04B40/0042 Primary

  Powdery mixtures · CPC title