Glass

Patent metadata

Field	Value
Publication number	US-10865134-B2
Application number	US-201815995379-A
Country	US
Kind code	B2
Filing date	Jun 1, 2018
Priority date	Dec 2, 2015
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

A wavelength-selective transmissive glass has a light transmittance T more than 315 nm and 400 nm or less at a wavelength of more than 315 nm and 400 nm or less represented by the formula shown below of 1% or more in terms of a plate thickness of 6 mm and a light transmittance T 315 nm or less at a wavelength of 315 nm or less represented by the formula shown below of 60% or less in terms of a plate thickness of 6 mm. A k is a weighting factor at a wavelength k (nm) for calculating T (light transmittance) defined in ISO-9050:2003, and T k is a transmittance at the wavelength k (nm) in terms of a plate thickness of 6 mm:

T more than 315 nm and 400 nm or less =(Σ k=more than 315 400 A k ×T k )/(Σ k=more than 315 400 A k )

T 315 nm or less =(Σ k=300 315 A k ×T k )/(Σ k=300 315 A k ).

First claim

The invention claimed is:

1. A wavelength-selective transmissive glass, comprising, as represented by mass % based on oxides,
a total iron content represented by Fe 2 O 3 of from 0.04 to 0.15%, from 0.35 to 0.45% of CeO 2 , from 0 to 0.2% of TiO 2 , and from 0 to 0.2% of SnO 2 , wherein CeO 2 +3×TiO 2 +6×SnO 2 is from 0.41 to 0.5, and a value of Fe-Redox is from 25 to 65%,
wherein a glass matrix composition comprises from 60 to 80%, of SiO 2 , from 0 to 7%, of Al 2 O 3 , from 0 to 10% of MgO, from 4 to 20% of CaO, from 7 to 20% of Na 2 O, from 0 to 10% of K 2 O, and 0.5% or less of B 2 O 3 ,
having a light transmittance T more than 315 nm and 400 nm or less at a wavelength of from more than 315 nm to 400 nm represented by the following formula of 1% or more in terms of a plate thickness of 6 mm and a light transmittance T 315 nm or less at a wavelength of 315 nm or less represented by the following formula of 60% or less in terms of a plate thickness of 6 mm:
T more than 315 nm and 400 nm or less =(Σ k=more than 315 400 A k ×T k )/(Σ k=more than 315 400 A k )

T 315 nm or less =(Σ k=300 315 A k ×T k )/(Σ k=300 315 A k ),

wherein A k is a weighting factor at a wavelength k in nm for calculating T which is light transmittance defined in ISO-9050:2003, and T k is a transmittance at the wavelength k in nm in terms of a plate thickness of 6 mm, and
having a dominant wavelength Dw measured using light source A of 460 to 510 nm in terms of a plate thickness of 6 mm.

2. The wavelength-selective transmissive glass according to claim 1 , comprising, as represented by mass % based on oxides:
from 65 to 75% of SiO 2 , from 0 to 5% of Al 2 O 3 , from 0 to 6% of MgO, from 5 to 12% of CaO, from 10 to 16% of Na 2 O, from 0 to 3% of K 2 O as a glass matrix composition, and
wherein [MgOH+CaO] is from 5 to 15% and [Na 2 O+K 2 O] is from 10 to 16%.

3. The wavelength-selective transmissive glass according to claim 1 , wherein [MgO+CaO] is from 5 to 15%.

4. The wavelength-selective transmissive glass according to claim 1 , wherein [Na 2 O+K 2 O] is from 10 to 16%.

5. The wavelength-selective transmissive glass according to claim 1 , having the T more than 315 nm and 400 nm or less of from 18 to 70% in terms of a plate thickness of 6 mm and T 315 nm or less of 1% or less in terms of a plate thickness of 6 mm.

6. The wavelength-selective transmissive glass according to claim 5 , having the T more than 315 nm and 400 nm or less of from 50 to 68% in terms of a plate thickness of 6 mm and T 315 nm or less of 0.1% or less in terms of a plate thickness of 6 mm.

7. The wavelength-selective transmissive glass according to claim 1 , having a light transmittance T 360 to 400 nm at a wavelength of from 360 to 400 nm represented by the following formula of 1% or more in terms of a plate thickness of 6 mm:
T 360-400 nm =(Σ k=360 400 A k ×T k )/(Σ k=360 400 A k ),

wherein A k is a weighting factor at a wavelength k in nm for calculating light transmittance T defined in ISO-9050:2003, and T k is a transmittance at the wavelength k in nm in terms of a plate thickness of 6 mm.

8. The wavelength-selective transmissive glass according to claim 7 , having the T 360 to 400 nm of from 19 to 92% in terms of a plate thickness of 6 mm.

9. The wavelength-selective transmissive glass according to claim 8 , having the T 360 to 400 nm of from 70 to 90% in terms of a plate thickness of 6 mm.

10. The wavelength-selective transmissive glass according to claim 1 , having a light transmittance T 400 to 760 nm at a wavelength of from 400 to 760 nm represented by the following formula of 1% or more in terms of a plate thickness of 6 mm:
T 400-760 nm =(Σ k=400 760 A′ k ×T k )/(Σ k=400 760 A′ k ),

wherein A′ k is a weighting factor at a wavelength k in nm for calculating visible light transmittance using light source D65, T_D65 defined in ISO-9050:2003, and T k is a transmittance at the wavelength k in nm in terms of a plate thickness of 6 mm.

11. The wavelength-selective transmissive glass according to claim 10 , having the T 400 to 760 nm of from 40 to 92% in terms of a plate thickness of 6 mm.

12. The wavelength-selective transmissive glass according to claim 11 , having the T 400 to 760 nm of from 80 to 92% in terms of a plate thickness of 6 mm.

Assignees

• Agc Inc
• Tsubota Lab Inc

Inventors

• Nagai Kensuke
• Nakashima Tetsuya
• Kuroiwa Yutaka
• Hijiya Hiroyuki
• Tanida Masamichi
• Koike Akio
• Nishizawa Manabu
• Tsubota Kazuo
• Kurihara Toshihide
• Torii Hidemasa

Classifications

• C03C2204/00

  Glasses, glazes or enamels with special properties · CPC title

• C03C3/095

  containing rare earths · CPC title

• C03C3/091

  containing aluminium · CPC title

• C03C4/085 Primary

  for ultraviolet absorbing glass · CPC title

• C03C3/085

  containing an oxide of a divalent metal · CPC title