Multi-layer film with improved modulus properties

Patent metadata

Field	Value
Publication number	US-10864708-B2
Application number	US-201816224867-A
Country	US
Kind code	B2
Filing date	Dec 19, 2018
Priority date	May 14, 2012
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

The invention relates to a multi-layer, preferably co-extruded, plastic film with improved modulus properties, which is suitable, in particular, for producing three-dimensionally shaped articles.

First claim

What is claimed is:

1. A three-layer plastic film, comprising:
a core layer A comprising at least one polycarbonate or copolycarbonate and/or a polyester or copolyester having a glass transition temperature T g from 80° C. to 200° C.,
two outer layers B comprising at least one thermoplastic polyurethane exhibiting a hardness from 45 Shore D to 85 Shore D;
wherein the core layer A is located between the two outer layers B.

2. The three-layer plastic film according to claim 1 , wherein the core layer A comprises at least one polyester or copolyester having an inherent viscosity from 0.50 dL/g to 1.20 dL/g and a glass transition temperature T g from 80° C. to 200° C.

3. The three-layer plastic film according to claim 1 , wherein
the core layer A comprises at least one copolyester that exhibits residues from
(a) a dicarboxylic acid component comprising
i) 70 mole % to 100 mole % terephthalic acid residues,
ii) 0 mole % to 30 mole % aromatic dicarboxylic acid residues with up to 20 carbon atoms, and
iii) 0 mole % to 10 mole % aliphatic dicarboxylic acid residues with up to 16 carbon atoms, and

(b) a diol component comprising
i) 5 mole % to 50 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and
ii) 50 mole % to 95 mole % 1,4-cyclohexanedimethanol residues,

wherein the sum of the mole % of residues i)-iii) of the dicarboxylic acid component amounts to 100 mole % and the sum of the mole % of residues i) and ii) of the diol component amounts to 100 mole %
and wherein the inherent viscosity of the copolyester is from 0.50 dL/g to 1.20 dL/g and the copolyester has a glass transition temperature T g from 80° C. to 150° C.,
the two outer layers B comprise at least one thermoplastic polyurethane, the thermoplastic polyurethane exhibiting a hardness from 45 Shore D to 85 Shore D and being obtained from
a) one or more linear polyether diols with mean molecular weights from 500 g/mol to 10,000 g/mol, and, on average, in each instance at least 1.8 and at most 3.0, Tserevitinov-active hydrogen atoms
b) one or more organic diisocyanates,
c) one or more diol chain-extenders with molecular weights from 60 g/mol to 500 g/mol and with, on average, 1.8 to 3.0 Tserevitinov-active hydrogen atoms

in the presence of
d) optionally, one or more catalysts

with addition of
e) optionally, auxiliary substances and additives,

wherein the molar ratio of the NCO groups in b) to the groups in a) and c) that are reactive towards isocyanate amounts to 0.85:1 to 1.2:1.

4. The three-layer plastic film according to claim 1 , wherein the thermoplastic polyurethane exhibits a hardness from 50 Shore D to 80 Shore D.

5. The three-layer plastic film according to claim 3 , wherein the polyether diols a) used for producing the thermoplastic polyurethane are selected from one or more polyether diols of the group based on 1,4-butanediol units and/or 1,3-propylene glycol units.

6. The three-layer plastic film according to claim 3 , wherein the organic diisocyanate b) used for producing the thermoplastic polyurethane is selected from one or more isocyanates of the group containing 4,4′-diphenylmethane diisocyanate, isophorone diisocyanate, dicyclohexylmethane-4,4′-diisocyanate or 1,6-hexamethylene diisocyanate.

7. The three-layer plastic film according to claim 3 , wherein the diol chain-extender c) used for producing of the thermoplastic polyurethane is selected from one or more chain-extenders of the group containing 1,4-butanediol, 1,3-propanediol, 1,2-propanediol, 1,2-ethylene glycol, 1,6-hexanediol, 1,4-di(β-hydroxyethyl)hydroquinone or 1,4-di(β-hydroxyethyl)bisphenol A.

8. The three-layer plastic film according to claim 3 , wherein the thermoplastic polyurethane was produced in the prepolymer process.

9. The three-layer plastic film according to claim 3 , wherein the diol component of the copolyester comprises 10 mole % to 35 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 65 mole % to 90 mole % 1,4-cyclohexanedimethanol residues, the sum of the mole % of these two components of the diol component amounting to 100 mole %.

10. The three-layer plastic film according to claim 3 , wherein the residues from the dicarboxylic acid component of the polyester include 95 mole % to 100 mole % terephthalic acid residues.

11. The three-layer plastic film according to claim 1 , wherein the film has been co-extruded.

12. The three-layer plastic film according to claim 1 , wherein the film has a total thickness from 300 μm to 2000 μm.

13. The three-layer plastic film according to claim 1 , wherein the core layer A has a layer thickness from 250 μm to 1600 μm.

14. The three-layer plastic film according to claim 1 , wherein the outer layers B each have a layer thickness from 25 μm to 500 μm.

15. The three-layer plastic film according to claim 2 , wherein the poly or copolyester exhibits an inherent viscosity from 0.50 dL/g to 0.80 dL/g.

16. The three-layer plastic film according to claim 1 , wherein the poly- or copolyester exhibits a glass transition temperature T g from 85° C. to 130° C.

17. A three-dimensionally shaped article obtained by three-dimensionally forming the three-layer plastic film according to claim 1 .

Assignees

• Covestro Deutschland Ag

Inventors

• Pudleiner Heinz
• Meyer Klaus
• Winkler Juergen
• Braeuer Wolfgang
• Nickel Joerg
• Pehlert Craig
• Li Chunhua
• Chen Yan

Classifications

• C08L69/00

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08L67/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• B32B2457/12

  Photovoltaic modules · CPC title

• B32B2307/536

  Hardness · CPC title

• B32B27/08 Primary

  of synthetic resin · CPC title