Method for separating C5-C8 hydrocarbons and acid gases from a fluid stream

Patent metadata

Field	Value
Publication number	US-10864477-B2
Application number	US-201716073840-A
Country	US
Kind code	B2
Filing date	Feb 2, 2017
Priority date	Feb 8, 2016
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

A process for removing C 5 -C 8 -hydrocarbons and acid gases from a fluid stream is described, where a) the fluid stream is brought into contact with an absorption medium comprising at least one amine in an absorption zone to obtain a deacidified fluid stream and an acid-gases-laden absorption medium, b) the laden absorption medium is heated in a first heat exchanger and decompressed into a decompression zone to a pressure of from 5 to 10 bar to obtain a C 5 -C 8 -hydrocarbons-comprising gas phase and a hydrocarbon-depleted laden absorption medium, c) the hydrocarbon-depleted laden absorption medium is heated in an optional second heat exchanger and passed into a stripper in which at a pressure of 1 to 2.5 bar the acid gases are at least partially liberated by supplying heat to obtain a regenerated absorption medium and an acid-gas-comprising stream, and d) the regenerated absorption medium is recycled into the absorption zone.

First claim

The invention claimed is:

1. A process for removing C 5 -C 8 -hydrocarbons and acid gases from a fluid stream, the process comprising:
a) contacting the fluid stream with an absorption medium comprising at least one amine in an absorption zone to obtain a deacidified fluid stream and an acid-gases-laden absorption medium;
b) heating the laden absorption medium in a first heat exchanger and decompressing the heated laden absorption medium into a decompression zone to a pressure of from 5 to 10 bar to obtain a C 5 -C 8 -hydrocarbons-comprising gas phase and a hydrocarbon-depleted laden absorption medium;
c) passing the hydrocarbon-depleted laden absorption medium into a stripper in which at a pressure of 1 to 2.5 bar the acid gases are at least partially liberated by supplying heat to obtain a regenerated absorption medium and an acid-gas-comprising stream, the hydrocarbon-depleted laden absorption medium being heated in a second heat exchanger before being introduced into the stripper; and
d) recycling the regenerated absorption medium into the absorption zone,
wherein:
before the heating in the second heat exchanger the hydrocarbon-depleted laden absorption medium is decompressed into a desorption zone to a pressure of 1 to 2.5 bar and preheated by direct heat exchange with the acid-gas-comprising stream,
the heating medium used in the second heat exchanger is the regenerated absorption medium and the heating medium used in the first heat exchanger is the regenerated absorption medium after it has passed through the second heat exchanger; and
the amount of heat transferred in the first heat exchanger is such that the C 5 -C 8 -hydrocarbons-comprising gas phase comprises 50% to 97% by volume of acid gases.

2. The process according to claim 1 , wherein the fluid stream is brought into contact with the absorption medium in the absorption zone at a pressure of 50 to 80 bar.

3. The process according to claim 1 , wherein the partial pressure of the acid gases in the supplied fluid stream is less than 1 bar.

4. The process according to claim 1 , wherein the volume fraction of the acid gases in the supplied fluid stream is less than 3.3% by volume.

5. The process according to claim 1 , wherein the temperature of the supplied fluid stream is less than 70° C.

6. The process according to claim 1 , wherein the C 5 -C 8 -hydrocarbons-comprising gas phase comprises 70% to 95% by volume of acid gases.

7. The process according to claim 1 , wherein the laden absorption medium heated in the first heat exchanger is decompressed into the decompression zone to a pressure of from more than 6 to 10 bar.

8. The process according to claim 1 , wherein the C 5 -C 8 -hydrocarbons are at least partially condensed out of the C 5 -C 8 -hydrocarbons-comprising gas phase and the uncondensed constituents are passed into the absorption zone.

9. The process according to claim 1 , wherein the C 5 -C 8 -hydrocarbons comprise at least one aromatic hydrocarbon selected from the group consisting of benzene, toluene, ethylbenzene and xylene.

10. The process according to claim 1 , wherein the supplied fluid stream is selected from fluid streams comprising 0.5% to 10% by volume of acid gases and 10 to 5000 ppmv of C 5 -C 8 -hydrocarbons.

11. The process according to claim 1 , wherein the supplied fluid stream is natural gas.

12. The process according to claim 1 , wherein φ is less than 1 and φ is defined as:

φ
=

m
.

a

·

c
pa

m
.

f

·

c
pf

where:
{dot over (m)} a is the mass flow rate of the absorption medium passed into the absorption zone,
{dot over (m)} f is the mass flow rate of the supplied fluid stream,
c pa is the specific heat capacity of the absorption medium passed into the absorption zone, and
c pf is the specific heat capacity of the supplied fluid stream.

13. The process according to claim 1 , wherein the amine is a sterically hindered amine or a tertiary amine.

14. The process according to claim 1 , wherein the absorption medium further comprises a sterically unhindered primary or secondary amine.

Assignees

• Basf Se

Inventors

• Katz Torsten
• Notz Ralf
• Kern Andreas

Classifications

• B01D53/14 Primary

  by absorption · CPC title

• Y02C20/40

  of CO2 · CPC title

• B01D2257/7027

  Aromatic hydrocarbons · CPC title

• B01D2252/204

  Amines · CPC title

• B01D2252/20431

  Tertiary amines · CPC title