Radiofrequency and other electronic devices formed from enhanced resonant frequency hexaferrite materials

Patent metadata

Field	Value
Publication number	US-10862184-B2
Application number	US-201715727975-A
Country	US
Kind code	B2
Filing date	Oct 9, 2017
Priority date	Dec 7, 2010
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

Radiofrequency and other electronic devices can be formed from textured hexaferrite materials, such as Z-phase barium cobalt ferrite Ba 3 Co 2 Fe 24 O 41 (Co 2 Z) having enhanced resonant frequency. The textured hexaferrite material can be formed by sintering fine grain hexaferrite powder at a lower temperature than conventional firing temperatures to inhibit reduction of iron. The textured hexaferrite material can be used in radiofrequency devices such as circulators or telecommunications systems.

First claim

What is claimed is:

1. An enhanced resonant frequency ferrite material comprising a Z-phase barium cobalt hexagonal ferrite material having a formula Ba 3 Co 2 Fe 24 O 41 formed from a fine grain hexagonal ferrite powder having a surface area of greater than 8 m 2 /g, an average particle size of between 300-600 nm, and a grain size between about five micrometers and one millimeter in diameter, the Z-phase barium cobalt hexagonal ferrite material having a resonant frequency peak at a higher frequency as compared to standard hexagonal ferrite powder having a surface area less than 3 m 2 /g, the Z-phase barium cobalt hexagonal ferrite material being sintered at a temperature between 1100 and 1150° C. thereby reducing magnetorestriction of the Z-phase barium cobalt hexagonal ferrite.

2. The enhanced resonant frequency ferrite material of claim 1 wherein zeta-milling is used to form the fine grain hexagonal ferrite powder.

3. The enhanced resonant frequency ferrite material of claim 1 wherein the fine grain hexagonal ferrite powder has a surface area of greater than about 15 m 2 /g.

4. The enhanced resonant frequency ferrite material of claim 1 wherein the fine grain hexagonal ferrite powder has a surface area of between 8 and about 15 m 2 /g.

5. The enhanced resonant frequency ferrite material of claim 1 wherein the barium cobalt hexagonal ferrite material is magnetically textured.

6. An enhanced resonant frequency ferrite material comprising a barium cobalt hexagonal ferrite material having a formula Ba 3 Co 2 Fe 24 O 41 formed from fine grain hexagonal ferrite powder having a surface area of at least 8 m 2 /g, a grain size between about five micrometers and one millimeter in diameter, and an average particle size of between 300-600 nm, the barium cobalt hexagonal ferrite material having a resonant peak at a higher frequency as compared to standard hexagonal ferrite powder having a surface area from 1-3 m 2 /g and an average particle size of 1-5 microns, the barium cobalt hexagonal ferrite material being sintered at a temperature between 1100 and 1150° C. thereby reducing magnetorestriction of the Z-phase barium cobalt hexagonal ferrite.

7. The enhanced resonant frequency ferrite material of claim 6 wherein the barium cobalt hexagonal ferrite material is selected from the group consisting of M-phase, W-phase, U-phase, X-phase, Y-phase, Z-phase, and combinations thereof, barium cobalt hexagonal ferrite material.

8. The enhanced resonant frequency ferrite material of claim 6 wherein the fine grain hexagonal ferrite powder has a surface area of greater than about 15 m 2 /g.

9. The enhanced resonant frequency ferrite material of claim 6 wherein the fine grain hexagonal ferrite powder has a surface area of between 8 and about 15 m 2 /g.

10. The enhanced resonant frequency ferrite material of claim 6 wherein zeta-milling is used to form the fine grain hexagonal ferrite powder.

11. The enhanced resonant frequency ferrite material of claim 6 wherein the barium cobalt hexagonal ferrite material is magnetically textured.

12. The enhanced resonant frequency ferrite material of claim 6 wherein the barium cobalt hexagonal ferrite material is Z-phase barium cobalt hexagonal ferrite material.

13. A magnetic isolator comprising a Z-phase barium cobalt hexagonal ferrite material having a formula Ba 3 Co 2 Fe 24 O 41 formed from a fine grain hexagonal ferrite powder having a surface area of greater than 8 m 2 /g, an average particle size of between 300-600 nm, and a grain size between about five micrometers and one millimeter in diameter, the Z-phase barium cobalt hexagonal ferrite material having a resonant peak at a higher frequency as compared to standard hexagonal ferrite powder having a surface area less than 3 m 2 /g, the Z-phase barium cobalt hexagonal ferrite material being sintered at a temperature between 1100 and 1150° C. thereby reducing magnetorestriction of the Z-phase barium cobalt hexagonal ferrite.

14. The magnetic isolator of claim 13 wherein the magnetic isolator is incorporated into a radio-frequency telecommunication system.

15. The magnetic isolator of claim 13 wherein the magnetic isolator is incorporated into a power amplifier.

16. The magnetic isolator of claim 13 wherein the magnetic isolator is incorporated into telecommunication base station system.

17. The magnetic isolator of claim 13 wherein the fine grain hexagonal ferrite powder has a surface area of between 8 and about 15 m 2 /g.

18. The magnetic isolator of claim 13 wherein zeta-milling is used to form the fine grain hexagonal ferrite powder.

19. The magnetic isolator of claim 13 wherein the fine grain hexagonal ferrite powder has a surface area of greater than about 15 m 2 /g.

20. The magnetic isolator of claim 13 wherein the barium cobalt hexagonal ferrite material is magnetically textured.

Assignees

• Skyworks Solutions Inc

Inventors

• Hill Michael David

Classifications

• C04B35/64 Primary

  Burning or sintering processes (C04B33/32 takes precedence {; powder metallurgy B22F}) · CPC title

• C04B35/624

  Sol-gel processing · CPC title

• C04B2235/5445

  submicron sized, i.e. from 0,1 to 1 micron · CPC title

• H04B1/38

  Transceivers, i.e. devices in which transmitter and receiver form a structural unit and in which at least one part is used for functions of transmitting and receiving · CPC title

• H01F1/348

  Hexaferrites with decreased hardness or anisotropy, i.e. with increased permeability in the microwave (GHz) range, e.g. having a hexagonal crystallographic structure · CPC title