Electrolyte and battery

Patent metadata

Field	Value
Publication number	US-10862170-B2
Application number	US-201716343326-A
Country	US
Kind code	B2
Filing date	Jul 18, 2017
Priority date	Jun 15, 2017
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

The present disclosure relates to the field of energy storage materials, and particularly, to an electrolyte and a battery using the electrolyte. The electrolyte contains an additive selected from a group consisting of multi-cyano six-membered N-heterocyclic compounds represented by Formula I-1, Formula I-2 and Formula I-3, and combinations thereof. The addition of the multi-cyano six-membered N-heterocyclic compound as an additive in the electrolyte of the present disclosure can effectively passivate surface activity of the positive electrode material and inhibit oxidation of the electrolyte. The battery using the electrolyte according the present disclosure has good cycle performance at high temperature and high voltage and good storage performance, while gas production of the battery is reduced.

First claim

What is claimed is:

1. A battery, comprising:
a positive electrode plate;
a negative electrode plate;
a separator disposed between the positive electrode plate and the negative electrode plate; and
an electrolyte, comprising an additive, wherein the additive is selected from a group consisting of multi-cyano six-membered N-heterocyclic compounds represented by Formula I-1, Formula I-3, and combinations thereof,

wherein R 1 , R 2 , R 3 and R 4 are each independently selected from a group consisting of hydrogen, halogen, substituted or unsubstituted C 1 -C 12 alkyl, substituted or unsubstituted C 1 -C 12 alkoxy, substituted or unsubstituted C 1 -C 12 amine group, substituted or unsubstituted C 2 -C 12 alkenyl, substituted or unsubstituted C 2 -C 12 alkynyl, substituted or unsubstituted C 6 -C 26 aryl, and substituted or unsubstituted C 4 -C 12 heterocyclic group;
the substituent for the above groups, if present, is independently selected from a group consisting of halogen, cyano, C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 1 -C 6 alkoxy, and combinations thereof;
x, y and z are each an integer independently selected from 0-8; and
m, n and k are each an integer independently selected from 0-2.

2. The battery according to claim 1 , wherein
R 1 , R 2 , R 3 and R 4 are each independently selected from a group consisting of hydrogen, halogen, substituted or unsubstituted C 1 -C 3 linear or branched alkyl, substituted or unsubstituted C 5 -C 7 cycloalkyl, substituted or unsubstituted C 1 -C 3 alkoxy, substituted or unsubstituted C 1 -C 3 amine group, substituted or unsubstituted C 2 -C 3 alkenyl, substituted or unsubstituted C 2 -C 3 alkynyl, substituted or unsubstituted C 6 -C 8 aryl, and substituted or unsubstituted C 4 -C 7 heterocyclic group,
the substituent for the above groups, if present, is halogen.

3. The battery according to claim 1 , wherein m, n and k are each independently 1 or 2.

4. The battery according to claim 1 , wherein
in Formula I-1, R 1 and R 3 are identical; and
in Formula I-3, at least two of R 1 , R 2 and R 3 are identical.

5. The battery according to claim 4 , wherein
in Formula I-1, R 1 and R 3 are hydrogen; and
in Formula I-3, at least two of R 1 , R 2 and R 3 are hydrogen.

6. The battery according to claim 1 , wherein the electrolyte comprises 0.001% to 10% by weight of the multi-cyano six-membered N-heterocyclic compound.

7. The battery according to claim 1 , wherein the multi-cyano six-membered N-heterocyclic compound represented by Formula I-1 is selected from a group consisting of the following compounds and combinations thereof: and

the multi-cyano six-membered N-heterocyclic compound represented by Formula I-3 is selected from a group consisting of the following compounds and combinations thereof:

8. The battery according to claim 1 , further comprising an additive A, wherein the additive A is selected from a group consisting of an unsaturated bond-containing cyclic carbonate compound, a halogenated cyclic carbonate compound, a sulfate compound, a sulfite compound, a sultone compound, a disulphonic acid compound, a nitrile compound, an aromatic compound, an isocyanate compound, a phosphazene compound, a cyclic anhydride compound, a phosphite ester compound, a phosphate ester compound, a boric acid ester compound, a carboxylate compound, and combinations thereof.

9. The battery according to claim 8 , wherein the electrolyte comprises 0.01% to 30% by weight of the additive A.

10. The battery according to claim 1 , wherein the battery is a lithium-ion battery, a sodium-ion battery or a magnesium-ion battery.

11. The battery according to claim 1 , wherein the battery is a lithium-ion battery, and a charge cut-off voltage of the battery is not less than 4.2V.

12. The battery according to claim 1 , wherein the electrolyte comprises 0.1% to 3.5% by weight of the multi-cyano six-membered N-heterocyclic compound.

Assignees

• Contemporary Amperex Technology Co Ltd

Inventors

• Yi Tiancheng
• Hu Chunhua
• Hao Li
• Zhan Yingjie
• Liang Chengdu

Classifications

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M10/0567 Primary

  characterised by the additives · CPC title

• H01M10/4235

  Safety or regulating additives or arrangements in electrodes, separators or electrolyte (H01M10/4242 takes precedence) · CPC title

• H01M2300/0025

  Organic electrolyte · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title