Use of a hydrocarbyl-substituted dicarboxylic acid for improving or boosting the separation of water from fuel oils and gasoline fuels

Patent metadata

Field	Value
Publication number	US-10858608-B2
Application number	US-201816154952-A
Country	US
Kind code	B2
Filing date	Oct 9, 2018
Priority date	Jul 12, 2013
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

Use of a hydrocarbyl-substituted dicarboxylic acid for improving or boosting the separation of water from fuel oils and gasoline fuels which comprise additives with detergent action. A Fuel additive concentrate comprising the said hydrocarbyl-substituted dicarboxylic acid, certain additives with detergent action and optionally other customary additives and solvents or diluents.

First claim

The invention claimed is:

1. A method of improving separation of water from a fuel oil or a gasoline fuel, the method comprising:
contacting (A) a polyisobutenylsuccinic acid having a polyisobutenyl substituent comprising 32 to 100 carbon atoms with a fuel oil or a gasoline fuel comprising
(B) at least one nitrogen compound quaternized in the presence of an acid or in an acid-free manner, obtained by addition of a compound comprising at least one oxygen- or nitrogen-containing group reactive with an anhydride and additionally at least one quatemizable amino group onto a polycarboxylic anhydride compound and by subsequent quaternization, as an additive with a detergent action, and
(C) as an additive component, an alkoxylation copolymer comprising at least one oxide selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide, and styrene oxide, as a dehazer.

2. The method of claim 1 , wherein the alkoxylation copolymer (C) comprises ethylene oxide.

3. The method of claim 1 , wherein the alkoxylation copolymer (C) comprises propylene oxide.

4. The method of claim 1 , wherein the alkoxylation copolymer (C) comprises butylene oxide.

5. The method of claim 1 , wherein the alkoxylation copolymer (C) comprises styrene oxide.

6. The method of claim 1 , wherein the alkoxylation copolymer (C) further comprises an epoxy based resin.

7. The method of claim 1 , wherein the fuel oil further comprises as an additive component (D) at least one cetane number improver.

8. The method of claim 1 , wherein the fuel oil consists of:
(a) 0.1 to 100% by weight of at least one biofuel oil based on one or more fatty acid esters, and
(b) 0 to 99.9% by weight of one or more middle distillates of at least one origin selected from the group consisting of fossil origin, synthetic origin, vegetable origin, and animal origin, which are essentially hydrocarbon mixtures and are free of fatty acid esters.

9. The method of claim 1 , wherein the fuel oil consist of one or more middle distillates of at least one origin selected from the group consisting of fossil origin, synthetic origin, vegetable, and animal origin, which are essentially hydrocarbon mixtures and are free of fatty acid esters.

10. The method of claim 1 , wherein the fuel oil or gasoline fuel has at least one of the following properties:
(α) a sulfur content of less than 50 mg/kg;
(β) a maximum content of 8% by weight of polycyclic aromatic hydrocarbons; and
(γ) a 95% distillation point (vol/vol) at not more than 360° C.

11. A fuel additive concentrate for a fuel oil, comprising:
(A) 0.01 to 40% by weight of a polyisobutenylsuccinic acid having a polyisobutenyl substituent comprising 20 to 200 carbon atoms;
(B) 5 to 40% by weight of at least one additive with detergent action, wherein the at least one additive is selected from the group consisting of
(i) a compound comprising a moiety derived from succinic anhydride and having a hydroxyl group, amino group, amido, imido group, or a combination thereof;
(ii) a nitrogen compound quaternized in the presence of an acid or in an acid-free manner, obtained by addition of a compound comprising at least one oxygen- or nitrogen-containing group reactive with an anhydride and additionally at least one quaternizable amino group onto a polycarboxylic anhydride compound and by subsequent quaternization; and
(iii) a polytetrahydrobenzoxazine or a bistetrahydrobenzoxazine;

(C) 0.01 to 5% by weight of an alkoxylation copolymer comprising at least one oxide selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide, and styrene oxide, as a dehazer;
(D) 0 to 75% by weight of at least one cetane number improver; and
(E) 0 to 50% by weight of at least one solvent or diluent.

12. The method of claim 1 , wherein the alkoxylation copolymer further comprises at least one epoxy based resin.

Assignees

• Basf Se

Inventors

• Boehnke Harald
• Voelkel Ludwig
• Walter Marc

Classifications

• C10L2300/20

  Mixture of two components · CPC title

• C10L2200/0438

  Middle or heavy distillates, heating oil, gasoil, marine fuels, residua · CPC title

• C10L10/00

  Use of additives to fuels or fires for particular purposes (additives for liquid carbonaceous fuels characterised by their chemical nature C10L1/10; using binders for briquetting solid fuels C10L5/10; using additives to improve the combustion of solid fuels C10L9/10) · CPC title

• C10L2230/086

  Demulsifiers · CPC title

• C10L1/238

  obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds {(C10L1/221 takes precedence)} · CPC title