Method for purifying an asphaltene-containing fuel

Patent metadata

Field	Value
Publication number	US-10858598-B2
Application number	US-201716089617-A
Country	US
Kind code	B2
Filing date	Mar 2, 2017
Priority date	Apr 22, 2016
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

A method for purifying an asphaltene-containing fuel where the asphaltene-containing fuel is supplied to a deasphalting unit in which asphaltene contained in the fuel is separated using a solvent, thereby forming a substantially deasphalted fuel. The solvent is separated from the deasphalted fuel in a solvent recovery unit after a successful separation of the asphaltene from the fuel, and the waste heat of turbine exhaust gas produced in a gas turbine when converting fuel into electricity is used in order to purify the asphaltene-containing fuel. A corresponding device is used for purifying an asphaltene-containing fuel.

First claim

The invention claimed is:

1. An apparatus for purification of an asphaltene-containing fuel, comprising:
receiving a flow of fuel into a first separation stage,
separating the flow of fuel in the first separation stage into a first substream comprising low-boiling fuel constituents and an asphaltene-containing substream of fuel,
sending the first substream to a deasphaltation unit via a draw-off conduit configured to provide fluid communication for the first substream from a first output of the first separation stage to the deasphaltation unit,
sending the asphaltene-containing substream of fuel to the deasphaltation unit via an output path that is discrete from the draw-off conduit and that is configured to provide fluid communication for the asphaltene-containing substream of fuel from a second output of the first separation stage to the deasphaltation unit,
separating off in the deasphalting unit asphaltenes present in the asphaltene-containing substream of fuel by means of a solvent to form an essentially deasphalted fuel, wherein the solvent comprises the low-boiling fuel constituents from the first substream, and
separating the solvent, on completion of separation of the asphaltenes from the fuel, from the deasphalted fuel in a solvent recovery unit,
wherein waste heat from a turbine offgas is utilized for separation of the first substream from the asphaltene-containing substream of fuel.

2. The process as claimed in claim 1 ,
wherein the waste heat from the turbine offgas is utilized for separation of the solvent from the deasphalted fuel.

3. The process as claimed in claim 1 ,
wherein the solvent separated from the deasphalted fuel in the solvent recovery unit is recycled into the deasphaltation unit.

4. The process as claimed in claim 1 ,
wherein the asphaltene-containing substream of fuel, after the first substream has been separated off, is sent to a second separation stage.

5. The process as claimed in claim 4 ,
wherein the waste heat from the turbine offgas is utilized for heating of the asphaltene-containing substream of fuel before it is sent to the second separation stage.

6. The process as claimed in claim 5 ,
wherein a second substream that is vanadium free is separated from a substream of fuel to be deasphaltated in the second separation stage.

7. The process as claimed in claim 6 ,
wherein the asphaltene-containing substream of fuel, before being sent to the second separation stage, is additionally heated by the second substream that is vanadium free.

8. The process as claimed in claim 7 ,
wherein the second substream that is vanadium free is cooled in the heating of the asphaltene-containing substream of fuel.

9. The process as claimed in claim 8 ,
wherein the cooled second substream that is vanadium free is sent to a gas turbine.

10. The process as claimed in claim 6 ,
wherein the substream of fuel to be deasphaltated is sent to the deasphaltation unit in which asphaltenes present in the substream of fuel to be deasphaltated are removed.

11. An apparatus for purification of an asphaltene-containing fuel, comprising:
a first separation stage configured to receive a flow of fuel and to separate the flow of fuel into a first substream comprising low-boiling fuel constituents and an asphaltene containing substream of fuel,
a deasphaltation unit configured to separate off asphaltenes present in the asphaltene containing substream of fuel to form an essentially deasphalted fuel by means of a solvent,
a draw-off conduit configured to provide fluid communication for the first substream from a first output of the first separation stage to the deasphaltation unit,
an output conduit that is discrete from the draw-off conduit and configured to provide fluid communication for the asphaltene containing substream of fuel from a second output of the first separation stage to the deasphaltation unit, and
a solvent recovery unit, coupled for flow purposes to the deasphaltation unit, for separation of the solvent from the deasphalted fuel on completion of separation of the asphaltenes,
wherein the first separation stage coupled for heat transfer purposes to an offgas conduit from a gas turbine and heat from the offgas conduit is used to evaporate the first substream prior to the first substream being delivered to the deasphaltation unit.

12. The apparatus as claimed in claim 11 ,
wherein the solvent recovery unit is coupled for heat transfer purposes to an offgas conduit from the gas turbine.

13. The apparatus as claimed in claim 11 ,
wherein the solvent recovery unit comprises a recycle conduit coupled for flow purposes to a feed conduit to the deasphaltation unit.

14. The apparatus as claim 11 ,
wherein connected downstream of the first separation stage for flow purposes is a second stage configured to receive the asphaltene containing substream of fuel from the output conduit and to separate the asphaltene containing substream of fuel into a second substream of the fuel that is vanadium free and fed to a first output conduit of the second separation stage and a substream of fuel to be deasphaltated.

15. The apparatus as claimed in claim 14 ,
wherein the second separation stage comprises a feed conduit configured to receive the asphaltene containing substream from the output conduit and coupled for heat transfer purposes to an offgas conduit from the gas turbine.

16. The apparatus as claimed in claim 15 ,
where the first output conduit from the second separation stage is coupled for heat transfer purposes to the feed conduit to the second separation stage.

17. The apparatus as claimed in claim 16 ,
wherein the first output conduit from the second separation stage is coupled for flow purposes to a gas turbine.

18. The apparatus as claimed in claim 13 , wherein the first substream is delivered to the recycle conduit and then to the deasphaltation unit.

Assignees

• Siemens Ag

Inventors

• Kinzl Markus
• Kursawe Ansgar
• Löw Sebastian

Classifications

• F02C1/00

  Gas-turbine plants characterised by the use of hot gases or unheated pressurised gases, as the working fluid (by the use of combustion products F02C3/00, F02C5/00) · CPC title

• C10G21/003 Primary

  Solvent de-asphalting · CPC title

• F02C6/18

  using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants (using waste heat as source of energy for refrigeration plants F25B27/02; using the waste heat of a gasturbine for steam generation or in a steam cycle see F01K23/10) · CPC title

• F05D2260/213

  by the provision of a heat exchanger within the cooling circuit · CPC title

• C10G2300/206

  Asphaltenes · CPC title