Medium density polyethylene compositions

Patent metadata

Field	Value
Publication number	US-10858464-B2
Application number	US-201715805982-A
Country	US
Kind code	B2
Filing date	Nov 7, 2017
Priority date	Mar 11, 2013
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

An ethylene alpha-olefin copolymer having (a) a density of from about 0.910 g/cc to about 0.940 g/cc; (b) a weight average molecular weight of from about 150,000 g/mol to about 300,000 g/mol; and (c) a melt index at a load of 2.16 kg of from about 0.01 dg/10 min. to about 0.5 dg/min.; wherein a 1 mil blown film formed from the polymer composition is characterized by (i) a Dart Impact strength greater than about 175 g/mil; (ii) an Elmendorf machine direction tear strength greater than about 20 g/mil; and (iii) an Elmendorf transverse direction tear strength greater than about 475 g/mil.

First claim

What is claimed is:

1. An ethylene alpha-olefin copolymer having:
(a) a density of from about 0.910 g/cc to about 0.940 g/cc;
(b) a melt index (MI) ranging from about 0.01 dg/min. to about 0.5 dg/min.; a high load melt index (HLMI) ranging from about 4 dg/min. to about 25 dg/min.; and a ratio of the high load melt index (HLMI) to the melt index (MI) of from about 100 to about 2500, wherein the high load melt index (HLMI) is determined in accordance with ASTM D1238 at a load of 21.6 kg at 190° C., and the melt index (MI) is determined in accordance with ASTM D1238 at a load of 2.16 kg at 190° C.;
(c) a CY-a value of from about 0.35 to about 0.65;
(d) a moisture vapor transmission rate of less than about 1.3 g-mil/100 in 2 -day when tested in accordance with ASTM F1249 at 100° F. and 90% relative humidity using a test specimen having a 1 mil thickness; and
(e) a molecular weight distribution of from about 6 to about 30.

2. The copolymer of claim 1 having a 1% secant modulus in the machine direction of from about 90,000 psi to about 116,000 psi when tested in accordance with ASTM D882.

3. The copolymer of claim 1 having a 2% secant modulus in the machine direction of from 77,297 to 81,479 psi when tested in accordance with ASTM D882.

4. The copolymer of claim 1 having a 1% secant modulus in the transverse direction of from about 110,000 psi to about 174,000 psi when tested in accordance with ASTM D882.

5. The copolymer of claim 1 having a 2% secant modulus in the transverse direction of from 111,707 to 113,967 psi when tested in accordance with ASTM D882.

6. The copolymer of claim 1 having a yield strain in the machine direction of less than about 8% when tested in accordance with ASTM D882.

7. The copolymer of claim 1 having a yield strain in the transverse direction of from about 2% to about 5% when tested in accordance with ASTM D882.

8. The copolymer of claim 1 having a break strength in the transverse direction of from about 4300 psi to about 10,000 psi when tested in accordance with ASTM D882.

9. The copolymer of claim 1 having a break strength in the machine direction of from about 6500 psi to about 13,500 psi when tested in accordance with ASTM D882.

10. An ethylene alpha-olefin copolymer having:
(a) a density of from about 0.910 g/cc to about 0.940 g/cc;
(b) a melt index (MI) ranging from about 0.01 dg/min. to about 0.5 dg/min.; a high load melt index (HLMI) ranging from about 4 dg/min. to about 25 dg/min.; and a ratio of the high load melt index (HLMI) to the melt index (MI) of from about 100 to about 2500, wherein the high load melt index (HLMI) is determined in accordance with ASTM D1238 at a load of 21.6 kg at 190° C., and the melt index (MI) is determined in accordance with ASTM D1238 at a load of 2.16 kg at 190° C.;
(c) a CY-a value of from about 0.35 to about 0.65;
(d) a moisture vapor transmission rate of less than about 1.3 g-mil/100 in 2 -day when tested in accordance with ASTM F1249 at 100° F. and 90% relative humidity using a test specimen having a 1 mil thickness; and
(e) a weight average molecular weight of from about 150,000 g/mol to about 300,000 g/mol.

11. The copolymer of claim 10 having a 1% secant modulus in the machine direction of from about 90,000 psi to about 116,000 psi when tested in accordance with ASTM D882.

12. The copolymer of claim 10 having a 2% secant modulus in the machine direction of from 77,297 to 81,479 psi when tested in accordance with ASTM D882.

13. The copolymer of claim 10 having a 1% secant modulus in the transverse direction of from about 110,000 psi to about 174,000 psi when tested in accordance with ASTM D882.

14. The copolymer of claim 10 having a 2% secant modulus in the transverse direction of from 111,707 to 113,967 psi when tested in accordance with ASTM D882.

15. The copolymer of claim 10 having a yield strain in the machine direction of less than about 8% when tested in accordance with ASTM D882.

16. The copolymer of claim 10 having a yield strain in the transverse direction of from about 2% to about 5% when tested in accordance with ASTM D882.

17. The copolymer of claim 10 having a break strength in the transverse direction of from about 4300 psi to about 10,000 psi when tested in accordance with ASTM D882.

18. The copolymer of claim 10 having a break strength in the machine direction of from about 6500 psi to about 13,500 psi when tested in accordance with ASTM D882.

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Sukhadia Ashish M
• St Jean Guylaine
• Yang Qing
• Mcdaniel Max P

Classifications

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• C08L2203/16

  used for films · CPC title

• C08F10/08

  Butenes · CPC title

• C08F10/14

  Monomers containing five or more carbon atoms · CPC title

• C08F210/16 Primary

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title