Process for production of ammonia and derivatives, in particular urea

Patent metadata

Field	Value
Publication number	US-10858313-B2
Application number	US-201916251521-A
Country	US
Kind code	B2
Filing date	Jan 18, 2019
Priority date	Jun 18, 2014
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

A process for producing ammonia and a derivative of ammonia from a natural gas feed comprising conversion of natural gas into a make-up synthesis gas; synthesis of ammonia; use of said ammonia to produce said derivative of ammonia, wherein a portion of the natural gas feed is used to fuel a gas turbine; power produced by said gas turbine is transferred to at least one power user of the process, such as a compressor; heat is recovered from exhaust gas of said gas turbine, and at least part of said heat is recovered as low-grade heat available at a temperature not greater than 200° C., to provide process heating to at least one thermal user of the process, such as CO 2 removal unit or absorption chiller; a corresponding plant and method of modernization are also disclosed.

First claim

What is claimed is:

1. A method of modernizing a plant for producing ammonia and a derivative of ammonia, namely one or more of urea, phosphates or nitric acid, wherein:
said plant comprises a front-end section for generation of ammonia make-up synthesis gas; a synthesis loop for synthesis of ammonia from said make-up synthesis gas;
a section for the conversion of at least part of the synthesized ammonia into said derivative;
the plant also comprising power users and thermal users;
wherein:
the provision of at least one gas turbine, and the provision of suitable power transfer means to transfer the power produced by said turbine to at least one of said power users,
the provision of heat recovery means for recovering a low-grade heat from exhaust gas of said gas turbine, by indirect heat exchange with a medium, said medium being heated by the exhaust gas to a temperature not greater than 200° C.,
the provision of the so recovered low-grade heat to at least one of said thermal users of the plant, or to at least one newly-installed thermal user being one of the following: a reboiler of a CO 2 -rich solution in a CO 2 removal unit, a reboiler of an absorption refrigeration chiller, a reboiler of an ammonia-rich aqueous ammonia solution distillation system, a preheater of a natural gas or fuel gas, a preheater of process air, and a preheater of combustion air.

2. The method according to claim 1 , wherein the provision of said power transfer means includes: the provision of an electrical motor and the provision of an electrical generator coupled to said gas turbine.

Assignees

• Casale Sa

Inventors

• Ostuni Raffaele
• Skinner Geoffrey Frederick

Classifications

• C01C1/0452 Primary

  Heat exchangers · CPC title

• B01J19/00

  Chemical, physical or physico-chemical processes in general; Their relevant apparatus · CPC title

• C01C1/04 Primary

  Preparation of ammonia by synthesis (preparation or purification of gas mixtures for ammonia synthesis C01B3/025) · CPC title

• Y02P20/10

  Process efficiency · CPC title

• F02C3/22

  the fuel or oxidant being gaseous at standard temperature and pressure (F02C3/28 takes precedence) · CPC title