Slurry phase organic-inorganic fused hybrid catalyst for residue hydroprocessing and process for preparation thereof

Patent metadata

Field	Value
Publication number	US-10857532-B2
Application number	US-201615085661-A
Country	US
Kind code	B2
Filing date	Mar 30, 2016
Priority date	Mar 30, 2015
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

Oil soluble organic-inorganic fused slurry phase hydroprocessing catalysts for heavy oils and residues are prepared at supercritical conditions. The hydrodemetallization, hydrodesulfurization, asphaltene conversion and hydrocracking activities of a residue having high percentage of metals, sulfur and asphaltene have been tested in an autoclave batch reactor. The different organic compounds are used to modify the solid fused material (catalyst). The effect of the concentration of modifier on the hydroprocessing and hydrocracking reactions has also been investigated.

First claim

We claim:

1. An organic-inorganic fused hybrid catalyst for use in a slurry phase reactor, consisting of an Inorganic part of one metal from group VIB and one metal from group VIIIB in a weight ratio of 4:1 and an organic part;
wherein the metals are not in the form of metal oxides;
wherein the organic part is provided on an inorganic part surface of the metals from group VIB and VIIIB; and
wherein said hybrid catalyst is soluble in hydrocarbons.

2. The catalyst of claim 1 , wherein the metal from VIB is molybdenum and the metal from VIIIB is nickel in a ratio of 4:1 and the said catalyst is solid at room temperature and is thermally stable.

3. The catalyst of claim 1 wherein the said catalyst is useful for hydroprocessing reaction selected from a group comprising of hydrodemetallization, hydrodesulfurization, asphaltene conversion and hydrocracking.

4. A process for the preparation of the slurry phase organic-inorganic fused hybrid catalyst of claim 1 comprising the steps of:
a) mixing aqueous solutions of ammonium hepta molybdate and hexahydrade nickel nitrate to obtain a mixture;
b) preheating the mixture of aqueous solutions of as obtained in step (a) with an organic modifier at a temperature in the range of 100-200° C. and at a pressure in the range of 75-150 kg/cm 2 for a period in the range of 10-30 minutes;
c) reacting the mixture as obtained in step (b) in an autoclave batch reactor at a temperature in the range of 300-400° C., at a pressure in the range of 150-300 kg/cm 2 for a period in range of 30-75 minutes to obtain a reaction mixture;
d) quenching the reaction mixture as obtained in step (c) at temperature in the range of 15-30° C. to obtain a bi-phase reaction mixture with an aqueous and organic phase; and
e) separating the bi-phase reaction mixture as obtained in step (d) by solvent extraction, followed by washing and drying to obtain an organo metallic catalyst.

5. The process of claim 4 , wherein the organic modifier of step (b) are added in 1M-5M ratio with respect to Mo.

6. The process of claim 4 , wherein the organic modifier of step (b) is oleic acid, palmitic acid, lauric acid, cyclo hexane carboxylic acid, hexadecanol or 2-methyl 1-hexanal.

7. A method for hydro processing of heavy oils and residues (feedstock) using the catalyst of claim 1 , comprising heating 100-500 gram of feedstock with 3-5 gram of catalyst in a reactor at a temperature in the range of 300-500° C., pressure in the range of 50-200 kg/cm 2 for a period in the range of 2-6 hours, stirring in the presence of hydrogen in a slurry phase reactor, and separating a desired product.

8. The method of claim 7 , further comprising use of a solvent further defined as decaline, diesel, or light cyclic oil.

9. The method of claim 7 , wherein the residue employed as feedstock comprises a high metal content of >250 wppm; a high sulfur content of >5 wt %; a high asphaltene content of >15 wt %; and contains a maximum 550° C. plus material as not less than 90 wt %.

Assignees

• Council Scient Ind Res

Inventors

• Prajapati Ravindra
• Kohli Kirtika
• Maity Samir Kumar
• Garg Madhukar Onkarnath

Classifications

• B01J37/04 Primary

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J31/0202

  Alcohols or phenols · CPC title

• C10G45/08

  in combination with chromium, molybdenum, or tungsten metals, or compounds thereof · CPC title

• B01J23/85

  Chromium, molybdenum or tungsten · CPC title

• C10G47/26

  suspended in the oil, e.g. slurries · CPC title