Method for producing super absorber particles

Patent metadata

Field	Value
Publication number	US-10857256-B2
Application number	US-201615564215-A
Country	US
Kind code	B2
Filing date	Mar 29, 2016
Priority date	Apr 7, 2015
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

A process for agglomerating superabsorbent particles, wherein polymer particles having a particle size of 250 μm or less are dispersed in a hydrophobic organic solvent, the dispersed polymer particles are mixed with an aqueous monomer solution, the amount of unneutralized monomer applied with the monomer solution being from 0.5% to 80% by weight, based on the dispersed polymer particles, and the monomer solution is polymerized.

First claim

The invention claimed is:

1. A process for agglomerating superabsorbent particles by polymerizing a first aqueous monomer solution comprising
a) at least one ethylenically unsaturated carboxylic acid and optionally at least partly neutralized,
b) optionally one or more crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a), and
e) optionally one or more water-soluble polymer,
and drying and/or comminuting the resulting polymer particles, which comprises removing polymer particles having a particle size of 250 μm or less, dispersing the polymer particles removed in a hydrophobic organic solvent, mixing the dispersed polymer particles with a second aqueous monomer solution comprising
a) 2% to 40% by weight, based on the dispersed polymer particles, of at least one ethylenically unsaturated carboxylic acid and optionally at least partly neutralized,
b) optionally one or more crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a) and
e) optionally one or more water-soluble polymer,
where the first monomer solution and the second monomer solution may be the same or different, and polymerizing the second monomer solution.

2. The process according to claim 1 , wherein polymer particles having a particle size of 150 μm or less are removed.

3. The process according to claim 1 , wherein the amount of unneutralized monomer a) applied with the second monomer solution is from 5% to 30% by weight, based on the dispersed polymer particles.

4. The process according to claim 1 , wherein the second monomer solution comprises from 0.01 to 0.50 mmol of crosslinker b), based on unneutralized monomer a).

5. The process according to claim 1 , wherein the second monomer solution comprises from 0.05 to 0.15 mmol of crosslinker b), based on unneutralized monomer a).

6. The process according to claim 1 , wherein the first monomer solution is polymerized by dropletizing polymerization.

7. The process according to claim 6 , wherein the polymer particles are removed from the offgas of the dropletizing polymerization by means of a filter or cyclone.

8. The process according to claim 1 , wherein the first monomer solution is polymerized by suspension polymerization and the resulting polymer particles are dried.

9. The process according to claim 1 , wherein the first monomer solution is polymerized by solution polymerization and the resulting polymer particles are dried and comminuted.

10. The process according to claim 9 , wherein the polymer particles are removed by means of a sieve having a mesh size of 250 μm or less.

11. The process according to claim 9 , wherein the polymer particles are removed by means of a sieve having a mesh size of 150 μm or less.

12. The process according to claim 8 , wherein the polymer particles are removed by means of a sieve having a mesh size of 250 μm or less.

13. The process according to claim 8 , wherein the polymer particles are removed by means of a sieve having a mesh size of 150 μm or less.

14. A process for agglomerating superabsorbent particles comprising providing superabsorbent polymer particles having a particle size of 250 μm or less, dispersing the polymer particles in a hydrophobic organic solvent, mixing the dispersed polymer particles with an aqueous monomer solution comprising
a) 2% to 40% by weight, based on the dispersed polymer particles, of at least one ethylenically unsaturated carboxylic acid and optionally at least partly neutralized,
b) optionally one or more crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a) and
e) optionally one or more water-soluble polymer, and polymerizing the aqueous monomer solution.

15. The process according to claim 14 , wherein polymer particles having a particle size of 150 μm or less are removed.

16. The process according to claim 14 , wherein the amount of unneutralized monomer a) applied with the monomer solution is from 5% to 30% by weight, based on the dispersed polymer particles.

Assignees

• Basf Se

Inventors

• Mark Tina
• Daniel Thomas
• Lutz Erich

Classifications

• A61L15/60 Primary

  Liquid-swellable gel-forming materials, e.g. super-absorbents · CPC title

• C08F6/18

  Increasing the size of the dispersed particles · CPC title

• C08F265/04

  on to polymers of esters · CPC title

• A61L15/22 Primary

  containing macromolecular materials · CPC title

• C08F222/385

  Monomers containing two or more (meth)acrylamide groups, e.g. N,N'-methylenebisacrylamide · CPC title