Organic light emitting device

Patent metadata

Field	Value
Publication number	US-10854821-B2
Application number	US-201414787800-A
Country	US
Kind code	B2
Filing date	Apr 25, 2014
Priority date	Apr 30, 2013
Publication date	Dec 1, 2020
Grant date	Dec 1, 2020

Abstract

Provided is an organic light emitting device having high emission efficiency and a long continuous driving lifetime. The organic light emitting device includes: an anode; a cathode; and an emitting layer placed between the anode and the cathode, in which: the emitting layer contains an emitting material that emits fluorescence; and in an emission wavelength region of the emitting material, an absorption peak of an absorption spectrum in a minimum excited triplet state of a material having a smallest minimum excited triplet energy out of constituent materials in the emitting layer is absent.

First claim

The invention claimed is:

1. An organic light emitting device comprising:
a first electrode;
second electrode; and
an emitting layer placed between the first electrode and the second electrode,
wherein the emitting layer contains an emitting material that emits fluorescence and a material having a smallest minimum excited triplet energy among constituent materials of the emitting layer;
wherein a maximum value of absorption spectrum of the material in a minimum excited triplet state exists in a region other than in an emission wavelength region of the emitting material, and
wherein the material comprises a compound represented by the following general formula (1) or (2):

in the general formula (1), R 1 to R 15 each represent a hydrogen atom or a substituted or unsubstituted alkyl group, and n represents an integer of 0 or more and 2 or less,

in the general formula (2), R 13 to R 17 each represent a hydrogen atom or a substituted or unsubstituted alkyl group, R 18 and R 19 each represent a substituted or unsubstituted alkyl group, and n represents an integer of 0 or more and 2 or less.

2. The organic light emitting device according to claim 1 , wherein the emitting material comprises a material that emits blue light.

3. The organic light emitting device according to claim 1 , wherein in the emission wavelength region of the emitting material, a molar absorbance coefficient in the minimum excited triplet state of the material having the smallest minimum excited triplet energy in the emitting layer is 6,500 [L/(mol·cm)] or less.

4. The organic light emitting device according to claim 1 , wherein the material having the smallest minimum excited triplet energy comprises a host having a largest weight ratio among constituent materials of the emitting layer.

5. The organic light emitting device according to claim 1 , further comprising:
a hole transporting layer in contact with the emitting layer; and
an electron transporting layer in contact with the emitting layer,
wherein minimum excited triplet energies of the hole transporting layer and the electron transporting layer are larger than the minimum excited triplet energy of the material having the smallest minimum excited triplet energy in the emitting layer.

6. The organic light emitting device according to claim 1 , further comprising:
a hole transporting layer in contact with the emitting layer; and
an electron transporting layer in contact with the emitting layer,
wherein the emitting layer contains the material represented by formula (1) or (2) serving as a host and a luminous dopant;
the material has a hole mobility μ H of 5×10 −5 cm 2 /Vs or less; and
a relationship represented by the following expression (I) is satisfied:
EL D −EL H ≥0.15 eV  (I)

in the expression (I), EL D is a parameter derived from the following expression (Ia) and EL H is a parameter derived from the following expression (Ib):
EL D =|Ip D |−EG D   (Ia)

EL H =|Ip H |−EG H   (Ib)

in the expression (Ia), Ip D represents an ionization potential of the luminous dopant and EG D represents an energy gap of the luminous dopant; and
in the expression (Ib), Ip H represents an ionization potential of the material and EG H represents an energy gap of the material.

7. The organic light emitting device according to claim 1 , wherein a relationship represented by the following expression (II) is satisfied:
0.1≤{μ HEML /μ EEmL }≤1,000  (II)

in the expression (II), μ EEML represents an electron mobility of the emitting layer containing the material and μ HEML represents the hole mobility of the emitting layer containing the material.

8. The organic light emitting device according to claim 1 , wherein the emitting layer contains multiple kinds of emitting materials;
at least one kind of the multiple kinds of emitting materials comprises an emitting material that emits light having a color different from that of any other emitting material; and
the organic light emitting device outputs white light to an outside.

9. A display apparatus comprising multiple pixels, wherein the display apparatus is configured to control light emission of each of the multiple pixels; and
at least one of the multiple pixels includes the organic light emitting device according to claim 1 and an active device connected to the organic light emitting device.

10. The display apparatus according to claim 9 , wherein the active device comprises a transistor; and
the transistor includes an oxide semiconductor in a channel portion thereof.

11. A lighting apparatus comprising:
the organic light emitting device according to claim 1 ; and
an AC/DC converter circuit for supplying a driving voltage to the organic light emitting device.

12. An image forming apparatus comprising:
a photosensitive member;
a charging device for charging the photosensitive member;
an exposing device for exposing the photosensitive member to form an electrostatic latent image; and
a developing device for developing the electrostatic latent image formed on the photosensitive member,
wherein the exposing device includes the organic light emitting device according to claim 1 .

13. An exposing unit for exposing a photosensitive member comprising an emitting point, wherein the emitting point includes the organic light emitting device according to claim 1 and an active device connected to the organic light emitting device.

14. The exposing unit according to claim 13 , wherein the exposing unit includes a plurality of the emitting points; and
the emitting points are arrayed along a long axis direction of the photosensitive member.

15. An organic light emitting device comprising:
a first electrode;
second electrode; and
an organic compound layer placed between the first electrode and the second electrode, wherein the organic compound layer contains a compound represented by the following general formula (1) or (2):

in the general formula (1), R 1 to R 15 each represent a hydrogen atom or a substituted or unsubstituted alkyl group, and n represents an integer of 0 or more and 2 or less;

in the general formula (2), R 13 to R 17 each represent a hydrogen atom or a substituted or unsubstituted alkyl group, R 18 and R 19 each represent a substituted or unsubstituted alkyl group, and n represents an integer of 0 or more and 2 or less.

16. The organic light emitting device according to claim 15 , wherein the organic compound layer includes a light emitting layer, and
wherein the light emitting layer contains the compound represented by the general formula (1) or (2).

17. A display apparatus comprising multiple pixels, wherein the display apparatus is configured to control light emission of each of the multiple pixels; and
at least one of the multiple pixels includes the organic light emitting device according to claim 15 and an active device connected to the organic light emitting device.

18. The display apparatus according to claim 15 , wherein the active device comprises a transistor; and
the transistor includes an oxide semiconductor in a channel portion thereof.

Assignees

• Canon Kk

Inventors

• Ikari Kenichi
• Ohrui Hiroki
• Matsuda Yojiro
• Iida Haruna
• Itabashi Masumi
• Tagami Kei
• Takahashi Tetsuo
• Shiobara Satoru
• Yamaguchi Tomona

Classifications

• H10K59/12

  Active-matrix OLED [AMOLED] displays · CPC title

• H10K85/626

  containing more than one polycyclic condensed aromatic rings, e.g. bis-anthracene · CPC title

• C09K11/06 Primary

  containing organic luminescent materials · CPC title

• H10K2101/40

  Interrelation of parameters between multiple constituent active layers or sublayers, e.g. HOMO values in adjacent layers · CPC title

• H10K2101/10

  Triplet emission · CPC title