Biosensor electrode and biosensor using the same

Patent metadata

Field	Value
Publication number	US-10852267-B2
Application number	US-201715792795-A
Country	US
Kind code	B2
Filing date	Oct 25, 2017
Priority date	May 8, 2017
Publication date	Dec 1, 2020
Grant date	Dec 1, 2020

Abstract

A biosensor electrode comprises comprising a porous structure comprising a plurality of metal ligaments and a plurality of pores; and at least one carbon nanotube structure embedded in the porous structure and comprising a plurality of carbon nanotubes joined end to end by van der Waals attractive force, wherein the plurality of carbon nanotubes are arranged along a same direction.

First claim

What is claimed is:

1. A biosensor electrode comprising:
a porous structure comprising a plurality of metal ligaments and a plurality of pores defined by adjacent metal ligaments, wherein a material of the plurality of metal ligaments is metal; and
at least one carbon nanotube structure embedded in the porous structure and comprising a plurality of carbon nanotubes joined end to end by van der Waals attractive force, wherein the plurality of carbon nanotubes are arranged along a same direction; and one of the plurality of carbon nanotubes comprises a first portion and a second portion, the first portion is embedded inside of one of the plurality of metal ligaments, an entire outer surface of the first portion is in direct contact with the one of the plurality of metal ligaments, and the second portion is located in one of the plurality of pores.

2. The biosensor electrode of claim 1 , further comprising a material with catalytic property, wherein the porous structure and at least one carbon nanotube structure form a three-dimensional porous composite structure, and the material with catalytic property is located on a surface of the three-dimensional porous composite structure.

3. The biosensor electrode of claim 2 , wherein the material with catalytic property is nano-oxide.

4. The biosensor electrode of claim 1 , wherein a size of each of the plurality of pores is less than or equal to 100 μm.

5. The biosensor electrode of claim 1 , wherein material of the plurality of metal ligaments is an inert metal.

6. The biosensor electrode of claim 1 , wherein the at least one carbon nanotube structure is located in the plurality of pores.

7. The biosensor electrode of claim 1 , wherein the at least one carbon nanotube structure comprises a plurality of carbon nanotube structures spaced from each other.

8. The biosensor electrode of claim 7 , wherein an angle between carbon nanotubes in adjacent spaced carbon nanotube structures is in a range from 0° to 90°.

9. The biosensor electrode of claim 8 , wherein the adjacent spaced carbon nanotube structure are parallel with each other.

10. The biosensor electrode of claim 1 , wherein the carbon nanotube structure comprises at least one carbon nanotube film, the at least one carbon nanotube film is a drawn carbon nanotube film comprising a plurality of successively oriented carbon nanotube segments joined end-to-end by van der Waals force therebetween.

11. The biosensor electrode of claim 10 , wherein the at least one carbon nanotube film comprises a plurality of carbon nanotube films coplanar or stacked.

12. The biosensor electrode of claim 11 , wherein an angle between carbon nanotubes in adjacent stacked carbon nanotube films is in a range from 0° to 90°.

13. The biosensor electrode of claim 1 , wherein the at least one carbon nanotube structure and the porous structure have a common interface.

14. A biosensor comprising:
a molecular recognition element configured to identify a biochemical reaction signal and the molecular recognition element comprising:
a porous structure comprising a plurality of metal ligaments and a plurality of pores, wherein a material of the plurality of metal ligaments is selected from the group consisting of copper, mercury, silver, platinum, and aurum;
at least one carbon nanotube structure embedded in the porous structure and comprising a plurality of carbon nanotubes joined end to end by van der Waals attractive force, wherein the plurality of carbon nanotubes are arranged along a same direction; and one of the plurality of carbon nanotubes comprises a first portion and a second portion, the first portion is embedded inside of one of the plurality of metal ligaments, an entire outer surface of the first portion is in direct contact with the one of the plurality of metal ligaments, and the second portion is located in one of the plurality of pores; and

a signal conversion element configured to convert the biochemical reaction signal into an electrical signal.

15. The biosensor electrode of claim 1 , wherein the material of the plurality of metal ligaments is selected from the group consisting of copper, mercury, silver, platinum, and aurum.

16. The biosensor electrode of claim 1 , wherein the material of the plurality of metal ligaments is mercury or silver.

17. The biosensor electrode of claim 1 , wherein a portion of each of the plurality of carbon nanotubes is embedded inside of the plurality of metal ligaments, an entire outer surface of the portion is in direct contact with the plurality of metal ligaments, and another portion of each of the plurality of carbon nanotubes is located in the plurality of pores.

18. The biosensor electrode of claim 14 , wherein a portion of each of the plurality of carbon nanotubes is embedded inside of the plurality of metal ligaments, an entire outer surface of the portion is in direct contact with the plurality of metal ligaments, and another portion of each of the plurality of carbon nanotubes is located in the plurality of pores.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Fu hong-ying
• Li Wen-Zhen

Classifications

• G01N27/308 Primary

  at least partially made of carbon · CPC title

• G01N27/327 Primary

  Biochemical electrodes {, e.g. electrical or mechanical details for in vitro measurements} · CPC title

• C01B32/168

  After-treatment · CPC title

• G01N27/3278 Primary

  involving nanosized elements, e.g. nanogaps or nanoparticles (nanopores G01N33/48721; magnetic beads G01N27/745) · CPC title

• B82B3/0047

  Bonding two or more elements · CPC title