Sliding member and method for producing same
US-2017335964-A1 · Nov 23, 2017 · US
US10851776B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10851776-B2 |
| Application number | US-201916239015-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 3, 2019 |
| Priority date | Apr 20, 2018 |
| Publication date | Dec 1, 2020 |
| Grant date | Dec 1, 2020 |
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A sliding member has a sliding surface sliding under a wet condition in which a lubricant oil exists. The sliding surface is coated with a laminate film comprising an upper layer and a lower layer. The lower layer comprises hydrogen-free amorphous carbon (hydrogen-free DLC) and carbon particles dispersed on or in the hydrogen-free DLC. The hydrogen-free DLC has a hydrogen content of 5 atom % or less when the lower layer as a whole is 100 atom %. The upper layer comprises boron-containing amorphous carbon (B-DLC) and has protrusions on a surface side of the upper layer along the carbon particles of the lower layer. The B-DLC has a boron content of 1-40 atom % when the upper layer as a whole is 100 atom %. The protrusions have a particle diameter of 0.5-5 μm and exist with a density of 20 protrusions/100 μm2 or more.
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The invention claimed is: 1. A sliding member having a sliding surface sliding under a wet condition in which a lubricant oil exists, the sliding surface being coated with a laminate film comprising an upper layer and a lower layer, the lower layer comprising hydrogen-free amorphous carbon (referred to as “hydrogen-free DLC”) and carbon particles dispersed on or in the hydrogen-free DLC and having a hydrogen content of 5 atom % or less when the lower layer as a whole is 100 atom %, the upper layer comprising boron-containing amorphous carbon (referred to as “B-DLC”) and having protrusions on a surface side of the upper layer along the carbon particles of the lower layer, the B-DLC having a boron content of 1-40 atom % when the upper layer as a whole is 100 atom %, the protrusions having a particle diameter of 0.5-5 μm and existing with a density of 20 protrusions/100 μm 2 or more. 2. The sliding member as recited in claim 1 , wherein the B-DLC has a thickness of 0.2-3 μm, and the hydrogen-free DLC has a thickness of 0.5-5 μm. 3. The sliding member as recited in claim 1 , wherein the B-DLC has hardness of 15-35 GPa, and the hydrogen-free DLC has hardness of 40-70 GPa. 4. A sliding machine comprising: a pair of sliding members having sliding surfaces that can relatively move while facing each other; and a lubricant oil interposed between the sliding surfaces facing each other, at least one of the sliding members comprising the sliding member as recited in claim 1 . 5. The sliding machine as recited in claim 4 , wherein the sliding machine is an oil pump that pumps the lubricant oil under pressure. 6. The sliding machine as recited in claim 5 , wherein the pair of sliding members are a vane and a cam ring, the oil pump is a vane pump, and the vane has the sliding surface coated with the laminate film on a tip end side of the vane. 7. The sliding machine as recited in claim 6 , wherein the cam ring comprises an iron-based sintered material. 8. The sliding machine as recited in claim 4 , wherein the lubricant oil contains an oil-soluble molybdenum compound with a mass ratio of Mo to the lubricant oil as a whole of 200-1000 ppm, wherein the oil-soluble molybdenum compound has a chemical structure comprising a trinuclear of Mo.
with vanes reciprocating with respect to the inner member · CPC title
derived from Mo or W · CPC title
Elements · CPC title
Mixtures of base-materials and additives · CPC title
in the form of films or sheets · CPC title
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