Liquid inkjettable materials for three-dimensional printing
US-9156999-B2 · Oct 13, 2015 · US
US10850446B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10850446-B2 |
| Application number | US-201616073181-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 20, 2016 |
| Priority date | Apr 20, 2016 |
| Publication date | Dec 1, 2020 |
| Grant date | Dec 1, 2020 |
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In a three-dimensional printing method example, an epoxy mold compound build material is applied. A fusing agent is selectively applied on at least a portion of the epoxy mold compound build material. The epoxy mold compound build material is exposed to energy, thereby fusing the portion of the epoxy mold compound build material in contact with the fusing agent to form a layer.
Opening claim text (preview).
What is claimed is: 1. A three-dimensional (3D) printing method, comprising: applying a one part thermal cure epoxy mold compound build material; selectively applying a fusing agent on at least a portion of the epoxy mold compound build material; and exposing the epoxy mold compound build material to energy, thereby fusing the portion of the epoxy mold compound build material in contact with the fusing agent to form a layer. 2. The method as defined in claim 1 wherein the epoxy mold compound build material is a white powder. 3. The method as defined in claim 2 , further comprising preparing the epoxy mold compound build material by grinding and sorting, by particle size, an epoxy mold compound build material precursor. 4. The method as defined in claim 3 wherein the grinding is accomplished in liquid nitrogen. 5. The method as defined in claim 2 wherein the epoxy mold compound build material includes a catalyst selected from the group consisting of a phosphorous catalyst, an amine catalyst, and an imidazole catalyst. 6. The method as defined in claim 1 wherein the epoxy mold compound build material is a thermal set material. 7. The method as defined in claim 1 wherein the applying of the epoxy mold compound build material is accomplished by spraying the epoxy mold compound build material. 8. The method as defined in claim 7 wherein the epoxy mold compound build material includes a melting epoxy resin and a non-melting filler, and wherein a ratio of melting epoxy resin to non-melting filler ranges from about 1 to about 10. 9. The method as defined in claim 8 wherein: the melting epoxy resin is a cycloaliphatic epoxide; and the non-melting filler is selected from the group consisting of silica, alumina, alumina nitride, quartz, and combinations thereof. 10. The method as defined in claim 1 wherein: prior to selectively applying the fusing agent, the method further comprises heating the epoxy mold compound build material to a heating temperature ranging from about 80° C. to about 100° C.; and the exposing of the epoxy mold compound build material to the energy raises a temperature of the portion of the epoxy mold compound build material in contact with the fusing agent to a final temperature ranging from about 100° C. to about 130° C. 11. The method as defined in claim 1 , further comprising selectively applying a detailing agent to an other portion of the epoxy mold compound build material, wherein the other portion of the epoxy mold compound build material does not fuse during the exposing of the epoxy mold compound build material to energy. 12. The method as defined in claim 11 wherein: the exposing of the epoxy mold compound build material to the energy raises a temperature of the portion of the epoxy mold compound build material in contact with the fusing agent to a final temperature; and a temperature of the other portion of the epoxy mold compound during the exposure to the energy is at least 20° C. less than the final temperature. 13. The method as defined in claim 1 wherein the fusing agent includes a radiation absorber selected from the group consisting of carbon black, carbon fibers, graphite, iron oxides, and spherical gold nanoparticles. 14. The method as defined in claim 1 , wherein the epoxy mold compound build material includes a silane coupling agent adhesion promoter. 15. The method as defined in claim 1 , wherein the epoxy mold compound build material includes a mold release agent selected from the group consisting of a hydrocarbon wax, silicone, sodium dodecyl sulfate (SDS) soap, and a fatty acid. 16. The method as defined in claim 1 wherein the epoxy mold compound build material is applied without a hardener or curing agent. 17. A three-dimensional (3D) printing system, comprising: a supply containing a one part thermal cure epoxy mold compound build material; a build material distributor; a supply of a fusing agent; an inkjet applicator for selectively dispensing the fusing agent; a controller; and a non-transitory computer readable medium having stored thereon computer executable instructions to cause the controller to: utilize the build material distributor to dispense the epoxy mold compound build material; and utilize the inkjet applicator to selectively dispense the fusing agent to pattern a three-dimensional part layer. 18. The 3D printing system as defined in claim 17 , further comprising: a supply of a detailing agent; and an other inkjet applicator for selectively dispensing the detailing agent; wherein the computer executable instructions further cause the controller to utilize the other inkjet applicator to selectively dispense the detailing agent. 19. The 3D printing system as defined in claim 17 wherein the epoxy mold compound build material is a white powder including a melting epoxy resin and a non-melting filler, and wherein a ratio of the melting epoxy resin to the non-melting filler ranges from about 1 to about 10.
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using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber · CPC title
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