Insolubilizing agent for specific toxic substances, method for insolubilizing specific toxic substances using same, and soil improving method

Patent metadata

Field	Value
Publication number	US-10850256-B2
Application number	US-201816119723-A
Country	US
Kind code	B2
Filing date	Aug 31, 2018
Priority date	Mar 30, 2012
Publication date	Dec 1, 2020
Grant date	Dec 1, 2020

Abstract

Provided is an insolubilizing material for a specific toxic substance useful for insolubilizing a heavy metal or the like conducted by applying the insolubilizing material for a specific toxic substance to soil or on the surface of the soil. The insolubilizing material, for a specific toxic substance, is used in a manner so that soil does not reach a strongly alkaline region of a pH of 11 or more. The insolubilizing material for a specific toxic substance comprises an amorphous aluminum compound or a derivative thereof as a main component. The insolubilizing material functions as a solidifying material. The insolubilizing material also comprises gypsum obtained by adding and mixing, to the gypsum, the amorphous aluminum compound or the derivative thereof in a range from 0.5 to 60 mass parts relative to 100 mass parts of the gypsum. A method for improving soil using the insolubilizing material is also disclosed.

First claim

The invention claimed is:

1. A method for insolubilizing a specific toxic substance, the method comprising:
conducting a treatment of soil so that the soil does not reach a strongly alkaline region in a range of pH 11 or more by adding to and mixing with, or spraying to the soil, an insolubilizing material so as to insolubilize the specific toxic substance,
wherein the insolubilizing material comprises:
an amorphous aluminum compound, or a derivative thereof, or a combination thereof, as a main component; and
calcined gypsum, or gypsum dihydrate, or a combination thereof, as a calcium component, and

the insolubilizing material insolubilizes the specific toxic substance without forming ettringite.

2. The method for insolubilizing a specific toxic substance according to claim 1 ,
wherein the insolubilizing material is added to and mixed with, or sprayed to the soil in an amount in a range from 0.5 to 50 g per 1 kg on a dry mass basis of the soil.

3. The method for insolubilizing a specific toxic substance according to claim 1 ,
wherein the insolubilizing material is added to and mixed with, or sprayed to the soil in an amount in a range from 10 to 40 g per 1 kg on a dry mass basis of the soil.

4. The method for insolubilizing a specific toxic substance according to claim 1 ,
wherein the specific toxic substance to be insolubilized is attributable to the soil, and
if the specific toxic substance also is present in the insolubilizing material, both the specific toxic substance in the soil and the specific toxic substance in the insolubilizing material are insolubilized.

5. The method for insolubilizing a specific toxic substance according to claim 1 ,
wherein the amorphous aluminum compound, or the derivative thereof, or the combination thereof is amorphous aluminum hydroxide or a derivative thereof, or a combination thereof.

6. The method for insolubilizing a specific toxic substance according to claim 1 ,
wherein the insolubilizing material insolubilizes the specific toxic substance by adsorbing the specific toxic substance, and forming a mineral other than ettringite with the specific toxic substance, wherein the mineral other than ettringite comprises the insolubilizing material and the specific toxic substance.

7. The method for insolubilizing a specific toxic substance according to claim 1 ,
wherein the amorphous aluminum compound is derived from aluminum sludge, and
the amorphous aluminum compound in the insolubilizing material is present (a) in the aluminum sludge as it is or (b) in a dehydrated and dried state of the aluminum sludge without changing properties of the aluminum sludge.

8. The method for insolubilizing a specific toxic substance according to claim 1 ,
wherein the specific toxic substance is at least one material selected from the group consisting of cadmium and compounds thereof, hexavalent chromium compounds, cyanides, mercury and compounds thereof, which may be alkyl mercury compounds, selenium and compounds thereof, lead and compounds thereof, arsenic and compounds thereof, fluorine and compounds thereof, and boron and compounds thereof.

9. The method for insolubilizing a specific toxic substance according to claim 1 ,
wherein the calcium component further comprises at least one material selected from the group consisting of calcium carbonate, calcium peroxide, calcium fluoride, calcium iodide, calcium phosphate, calcium chloride, calcium nitrate, calcium acetate, calcium citrate, calcium gluconate, calcium malate, and calcium lactate.

10. A method for improving soil, comprising:
conducting a treatment of the soil comprising a specific toxic substance so that the soil does not reach a strongly alkaline region in a range of pH 11 or more by adding to and mixing with the soil, an insolubilizing material so as to insolubilize the specific toxic substance,
wherein the insolubilizing material comprises:
an amorphous aluminum compound or a derivative thereof or a combination thereof as a main component; and
calcined gypsum, or gypsum dihydrate, or a combination thereof, as a calcium component,

the insolubilizing material for a specific toxic substance is obtained by adding and mixing; to the calcium component, the amorphous aluminum compound or the derivative thereof or the combination thereof in a range from 0.5 to 60 mass parts relative to 100 mass parts of the calcium component,
the insolubilizing material insolubilizes the specific toxic substance without forming ettringite, and
the insolubilizing material solidifies the soil.

11. The method for improving soil according to claim 10 ,
wherein the insolubilizing material is added to and mixed with the soil, in an amount in a range from 30 to 200 kg relative to 1 m 3 of the soil containing the specific toxic substance.

12. The method for improving soil according to claim 10 ,
wherein the insolubilizing material comprises the amorphous aluminum compound, or the derivative thereof, or the combination thereof in a range from 15 to 50 mass parts relative to 100 mass parts of the calcium component.

13. The method for improving soil according to claim 10 , wherein the calcium component comprises calcined gypsum.

14. The method for improving soil according to claim 12 , wherein the calcium component comprises calcined gypsum.

Assignees

• Yoshino Gypsum Co

Inventors

• Yamaguchi Masato
• Miura Shinichi
• Ichino Yusuke
• Ishii Saburo
• KITSUDA Kazuomi

Classifications

• C04B28/06

  Aluminous cements (monolithic refractories or refractory mortars C04B35/66) · CPC title

• B01J20/045

  containing sulfur, e.g. sulfates, thiosulfates, gypsum · CPC title

• C04B2111/00767

  for waste stabilisation purposes · CPC title

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title

• A62D2101/24

  containing heavy metals · CPC title