Hybrid electrochemical cell

Patent metadata

Field	Value
Publication number	US-10847852-B2
Application number	US-201816223869-A
Country	US
Kind code	B2
Filing date	Dec 18, 2018
Priority date	Jun 16, 2014
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

Disclosed is a hybrid electrochemical cell with a first conductor having at least one portion that is both a first capacitor electrode and a first battery electrode. The hybrid electrochemical cell further includes a second conductor having at least one portion that is a second capacitor electrode and at least one other portion that is a second battery electrode. An electrolyte is in contact with both the first conductor and the second conductor. In some embodiments, the hybrid electrochemical cell further includes a separator between the first conductor and the second conductor to prevent physical contact between the first conductor and the second conductor, while facilitating ion transport between the first conductor and the second conductor.

First claim

What is claimed is:

1. A method of producing a hybrid electrochemical cell comprising:
(a) fabricating a first conductor having a single portion that is both a first capacitor electrode and a first battery electrode;
(b) fabricating a second conductor having at least one portion that is a second capacitor electrode and at least one other portion that is a second battery electrode; and
(c) adding an electrolyte to both the first conductor and the second conductor.

2. The method of claim 1 , wherein fabricating the second conductor comprises:
(a) receiving a substrate having a carbon-based oxide film; and
(b) generating a light beam that reduces portions of the carbon-based oxide film to a plurality of expanded and interconnected carbon layers that are electrically conductive, thereby forming an interconnected corrugated carbon-based network.

3. The method of claim 1 , further comprising inserting a separator between the first conductor and the second conductor.

4. The method of claim 1 , further comprising doping the first conductor with lithium ions.

5. The method of claim 1 , wherein the hybrid electrochemical cell comprises lithium-ion (Li-Ion) material or chemistry.

6. The method of claim 1 , wherein the hybrid electrochemical cell comprises a nickel-cadmium (Ni—Cd) chemistry, a nickel-metal hydride (Ni-MH) chemistry, or both.

7. The method of claim 6 , wherein the first conductor comprises nickel oxyhydroxide (NiOOH), graphite, or both.

8. The method of claim 1 , wherein the first battery electrode comprises hard carbon, silicon alloy, a composite alloy, or any combination thereof.

9. The method of claim 1 , wherein the second capacitor electrode comprises an electric double layer capacitor.

10. The method of claim 1 , wherein the second capacitor electrode is redox active and stores charge via intercalation pseudo-capacitance.

11. The method of claim 1 , wherein the second capacitor electrode comprises a layered metal oxide, activated carbon, an interconnected corrugated carbon-based network, niobium pentoxide, or any combination thereof.

12. The method of claim 11 , wherein the interconnected corrugated carbon-based network comprises a plurality of expanded and interconnected carbon layers.

13. The method of claim 12 , wherein the plurality of expanded and interconnected carbon layers comprises at least one corrugated carbon sheet.

14. The method of claim 13 , wherein each of the at least one corrugated carbon sheet has a thickness of 1 atom.

15. The method of claim 12 , wherein each of the plurality of expanded and interconnected carbon layers has a thickness of about 5 μm to 100 μm.

16. The method of claim 1 , wherein the second battery electrode comprises activated carbon, lithium cobalt oxide, lithium manganese oxide, lithium nickel oxide, lithium nickel manganese cobalt oxide, lithium nickel cobalt aluminum oxide, lithium titanium oxide, lithium iron phosphate, or any combination thereof.

17. The method of claim 1 , wherein a ratio between the at least one portion that is the second capacitor electrode and the at least one other portion that is the second battery electrode is about 1:10 to about 10:1.

18. The method of claim 1 , wherein the hybrid electrochemical cell has an energy density of about 20 watt-hour/kilogram (Wh/kg) to about 200 Wh/kg.

19. The method of claim 1 , wherein the hybrid electrochemical cell has a power density of about 103 watt/kilogram (W/kg) to about 104 W/kg.

20. The method of claim 1 , wherein the first conductor and the second conductor are interdigitated.

Assignees

• Univ California

Inventors

• El-Kady Maher F
• Kaner Richard B

Classifications

• H01G11/46

  Metal oxides · CPC title

• H01G11/32

  Carbon-based · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title