Electrolyte additive for lithium battery, organic electrolyte solution including the same, and lithium battery including the same

Patent metadata

Field	Value
Publication number	US-10847841-B2
Application number	US-201816185042-A
Country	US
Kind code	B2
Filing date	Nov 9, 2018
Priority date	Nov 15, 2017
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

An electrolyte additive for a lithium battery comprising a sulfone compound represented by Formula 1:

wherein, in Formula 1,
R 1 is a halogen-substituted or unsubstituted C1-C5 alkyl group, a halogen-substituted or unsubstituted C4-C10 cycloalkyl group, a halogen-substituted or unsubstituted C5-C10 aryl group, or a halogen-substituted or unsubstituted C2-C10 heteroaryl group, and R 2 is a halogen-substituted or unsubstituted C2-C10 alkenyl group.

First claim

What is claimed is:

1. An organic electrolyte solution, comprising:
a lithium salt;
an organic solvent; and
an electrolyte additive for a lithium battery comprising a sulfone compound represented by Formula 1:

wherein, in Formula 1,
R 1 is a halogen-substituted or unsubstituted C1-C5 alkyl group, a halogen-substituted or unsubstituted C4-C10 cycloalkyl group, a halogen-substituted or unsubstituted C5-C10 aryl group, or a halogen-substituted or unsubstituted C2-C10 heteroaryl group, and
R 2 is a halogen-substituted or unsubstituted C2-C10 alkenyl group,
wherein the organic solvent comprises a cyclic carbonate compound represented by Formula 17:

wherein, in Formula 17,
X 1 and X 2 are each independently a hydrogen atom or a halogen atom, and at least one of X 1 and X 2 is fluorine, and
wherein an amount of the cyclic carbonate compound represented by Formula 17 is 10 volume percent or less based on a total volume of the organic solvent.

2. The organic electrolyte solution of claim 1 , wherein the sulfone compound represented by Formula 1 is a sulfone compound represented by Formula 2:

wherein, in Formula 2,
R 3 is a halogen-substituted or unsubstituted C1-C5 alkyl group or a halogen-substituted or unsubstituted C5-C10 aryl group, and
R 4 is a covalent bond, a C1-C5 alkylene group or a C2-C10 alkenylene group.

3. The organic electrolyte solution of claim 1 , wherein the sulfone compound represented by Formula 1 is a compound represented by one of Formulae 3 to 9:

4. The organic electrolyte solution of claim 1 , wherein an amount of the sulfone compound represented by Formula 1 is in a range of about 0.1 weight percent to about 3 weight percent based on the total weight of the organic electrolyte solution.

5. The organic electrolyte solution of claim 1 , wherein the organic solvent comprises a cyclic carbonate compound represented by Formula 17a:

wherein, in Formula 17a,
X 1 is a hydrogen atom and X 2 is fluorine.

6. The organic electrolyte solution of claim 5 , wherein an amount of the cyclic carbonate compound represented by Formula 17a is about 10 volume percent or less based on a total volume of the organic solvent.

7. The organic electrolyte solution of claim 1 , wherein the organic electrolyte solution further comprises a cyclic carbonate compound represented by Formula 18:

wherein, in Formula 18,
X 3 and X 4 are each independently a hydrogen atom, a halogen atom, or a C1-C3 alkyl group.

8. The organic electrolyte solution of claim 7 , wherein an amount of the cyclic carbonate compound represented by Formula 18 is about 3 weight percent or less based on the total weight of the organic electrolyte solution.

9. The organic electrolyte solution of claim 1 , wherein the organic solvent further comprises at least one of ethylmethyl carbonate, methylpropyl carbonate, ethylpropyl carbonate, dimethyl carbonate, diethyl carbonate, dipropyl carbonate, propylene carbonate, ethylene carbonate, butylene carbonate, ethyl propionate, ethyl butyrate, acetonitrile, succinonitrile, adiponitrile, dimethyl sulfoxide, dimethyl formamide, dimethyl acetamide, gamma-valerolactone, gamma-butyrolactone, and tetrahydrofuran.

10. The organic electrolyte solution of claim 1 , wherein
the sulfone compound represented by Formula 1 is a compound represented by one of Formulae 3 to 9 and is contained in an amount of about 0.1 weight percent to about 3 weight,
the organic electrolyte solution further comprises a compound represented by Formula 18a contained in an amount of about 0.1 weight percent to about 2 weight percent, each based on the total weight of the organic electrolyte solution, and
the cyclic carbonate compound represented by Formula 17 is a compound represented by Formula 17a and is contained in an amount of about 1 volume percent to about 10 volume percent, based on a total volume of the organic solvent:

11. The organic electrolyte solution of claim 1 , wherein the lithium salt comprises at least one selected from LiPF 6 , LiBF 4 , LiCF 3 SO 3 , Li(CF 3 SO 2 ) 2 N, LiC 2 F 5 SO 3 , Li(FSO 2 ) 2 N, LiC 4 F 9 SO 3 , LiN(SO 2 CF 2 CF 3 ) 2 , and compounds represented by Formulae 19 to 22:

12. The organic electrolyte solution of claim 1 , wherein a concentration of the lithium salt in the organic electrolyte solution is in a range of about 0.01 molar to about 5 molar, based on a total volume of the organic electrolyte solution.

13. A lithium battery comprising:
a cathode comprising a cathode active material;
an anode comprising an anode active material; and
the organic electrolyte solution of claim 1 disposed between the cathode and the anode.

14. The lithium battery of claim 13 , wherein the cathode active material comprises a lithium transition metal oxide including nickel and at least one transition metal other than nickel, wherein an amount of the nickel is about 60 mole percent or more, based on the total number of moles of the nickel and the at least one transition metal.

15. The lithium battery of claim 14 , wherein the lithium transition metal oxide is represented by Formula 23:
Li a Ni x Co y M z O 2-b A b   Formula 23

wherein, in Formula 23,
1.0≤a≤1.2, 0≤b≤0.2, 0.6≤x≤1, 0<y≤0.3, 0<z≤0.3, and x+y+z=1,
M is at least one of manganese, vanadium, magnesium, gallium, silicon, tungsten, molybdenum, iron, chromium, copper, zinc, titanium, aluminum, and boron, and
A is at least one of F, S, Cl, and Br.

16. The lithium battery of claim 14 , wherein the lithium transition metal oxide is a compound represented by one of Formulae 24 and 25:
LiNi x Co y Mn z O 2   Formula 24

LiNi x Co y Al z O 2   Formula 25

wherein, in Formulae 24 and 25, x, y, and z are each independently 0.6≤x≤0.95, 0<y≤0.2, and 0<z≤0.1.

17. The lithium battery of claim 13 , wherein the anode active material comprises at least one of a silicon compound, a carbonaceous material, and a composite of a silicon compound and a carbonaceous material.

18. The lithium battery of claim 17 , wherein the silicon compound is a silicon oxide of the formula SiO x wherein 0<x<2, and wherein the anode active material comprises a composite of the silicon oxide and the carbonaceous material.

19. The lithium battery of claim 17 , wherein in the composite, the silicon compound is in a form of a silicon nanoparticle, and wherein the carbonaceous material is disposed on the silicon nanoparticle in the form of a coating.

20. The lithium battery of claim 17 , wherein an average secondary particle diameter of the composite of the silicon compound and the carbonaceous material is in a range of about 5 mi

Assignees

• Samsung Electronics Co Ltd
• Samsung Sdi Co Ltd

Inventors

• Park Insun
• Koh Myongchun
• Kim Dongyoung
• Park Eunha
• Kang Yoonsok
• Seo Jinah

Classifications

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• H01M2300/0025

  Organic electrolyte · CPC title

• H01M10/0568

  characterised by the solutes · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M10/0567 Primary

  characterised by the additives · CPC title