Determination of total base number in lubricants

Patent metadata

Field	Value
Publication number	US-10845356-B2
Application number	US-201816212117-A
Country	US
Kind code	B2
Filing date	Dec 6, 2018
Priority date	Dec 15, 2017
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

Systems and methods are provided for estimating the total base number of used oil in an engine. The systems and methods can involve characterizing the sulfur content and at least one other element content of the oil both before introduction into the engine and after passing through an engine cylinder during combustion. Depending on the aspect, a total base number of the oil prior to use can also be measured, or the total base number before use can be estimated based on the at least one element content.

First claim

The invention claimed is:

1. A method for determining a total base number for a used lubricating oil, comprising:
determining a first sulfur content for a marine lubricating oil prior to introduction into a cylinder in an engine;
measuring a second sulfur content for oil that has passed through the cylinder during fuel combustion;
determining a first element content for an element in the marine lubricating oil prior to introduction into the cylinder;
measuring a second element content for the element in the oil that has passed through the cylinder during fuel combustion; and
calculating a total base number for the oil that has passed through the cylinder during fuel combustion based on the first sulfur content, the second sulfur content, the first element content, and the second element content.

2. The method of claim 1 , wherein calculating the total base number for the oil that has passed through the cylinder during fuel combustion is further based on a total base number for the marine lubricating oil prior to introduction into the cylinder.

3. The method of claim 2 , the method further comprising measuring the total base number for the marine lubricating oil prior to introduction into the cylinder.

4. The method of claim 1 , wherein determining a first sulfur content for a marine lubricating oil prior to introduction into a cylinder comprises measuring a sulfur content of a sample of the marine lubricating oil.

5. The method of claim 1 , wherein the first element content comprises a content of Ca, Mg, or a combination thereof.

6. The method of claim 1 , wherein the first element content comprises a metal content, or wherein the first element content comprises a content for an element different from carbon, hydrogen, and sulfur, or wherein the first element comprises a content for an element different from carbon, hydrogen, sulfur, nitrogen, and oxygen.

7. The method of claim 1 , further comprising:
estimating a total base number for the marine lubricating oil prior to introduction into the cylinder based on the first element content,
wherein calculating the total base number for the oil that has passed through the cylinder during fuel combustion is further based on a total base number for the marine lubricating oil prior to introduction into the cylinder.

8. The method of claim 7 , wherein estimating the total base number for the marine lubricating oil prior to introduction into the cylinder based on the first element content comprises estimating the total base number for the marine lubricating oil prior to introduction into the cylinder based on a first polynomial relationship with the first element content.

9. The method of claim 8 , wherein the first polynomial relationship comprises a functional form corresponding to
TBN fresh =A*X fresh +B,
where TBN fresh is the total base number for the marine lubricating oil prior to introduction into the cylinder, X fresh is the first element content, and A and B are constants.

10. The method of claim 1 , further comprising:
estimating a total base number for the marine lubricating oil prior to introduction into the cylinder based on a third element content of the marine lubricating oil prior to introduction into the cylinder, the third element content corresponding to an element different from the element corresponding to the determined first element content,
wherein calculating the total base number for the oil that has passed through the cylinder during fuel combustion is further based on a total base number for the marine lubricating oil prior to introduction into the cylinder.

11. The method of claim 10 , wherein estimating the total base number for the marine lubricating oil prior to introduction into the cylinder based on the third element content comprises estimating the total base number for the marine lubricating oil prior to introduction into the cylinder based on a first polynomial relationship with the third element content, and wherein the first polynomial relationship comprises a functional form corresponding to
TBN fresh =A*X fresh +B,
where TBN fresh is the total base number for the marine lubricating oil prior to introduction into the cylinder, X fresh is the third element content, and A and B are constants.

12. The method of claim 10 , wherein the third element content comprises a combined element content of a plurality of elements.

13. The method of claim 1 , wherein the total base number for the oil that has passed through the cylinder during fuel combustion is calculated based on a second polynomial relationship between the total base number for the oil that has passed through the cylinder during fuel combustion and the first sulfur content, the second sulfur content, the first element content, and the second element content.

14. The method of claim 13 , wherein the second polynomial relationship comprises a functional form corresponding to
TBN used =( TBN fresh +α*S fresh )*( M used /M fresh )−α* S used

where TBN used is the total base number for the oil that has passed through the cylinder during fuel combustion, TBN fresh is the total base number for the marine lubricating oil prior to introduction into the cylinder, α is a constant, M fresh is the first element content, M used is the second element content, S fresh is the first sulfur content, and S used is the second sulfur content.

15. The method of claim 14 , wherein α is determined based on an amount of a strong base required to neutralize a fixed amount of sulfuric acid.

16. The method of claim 1 , wherein the oil that has passed through the cylinder during fuel combustion comprises a scrape down oil.

17. The method of claim 1 , wherein the first element content and the second element content are determined using the same analysis method, using the same analyzer, or a combination thereof.

18. The method of claim 1 , wherein the first sulfur content and the second sulfur content are determined using the same analysis method, using the same analyzer, or a combination thereof.

19. The method of claim 1 , further comprising determining that the calculated total base number of the oil that has passed through the cylinder is less than a first threshold value, and increasing a rate of introducing the marine lubricating oil into the cylinder.

20. The method of claim 19 , wherein the first threshold value comprises a threshold value that is determined based on the total base number for the marine lubricating oil prior to introduction into the cylinder.

21. The method of claim 1 , further comprising determining that the calculated total base number of the oil that has passed through the cylinder is greater than a second threshold value, and decreasing a rate of introducing the marine lubricating oil into the cylinder.

22. The method of claim 21 , wherein the second threshold value comprises a threshold value that is determined based on the total base number for the marine lubricating oil prior to introduction into the cylinder.

23. The method of claim 1 , further comprising determining that the calculated total base number of the oil that has passed through the cylinder is a) less than a first threshold value or b) greater than a second threshold value, and modifying an amount of base added to the marine lubricating oil prior to introduction into the cylinder.

24. A method for determining a total base number for a used lubricating oil, comprising:

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Christensen Gary
• BRABEZ Nabila
• Givens Jr Willie A
• Crouthamel Kevin L
• Satterfield Andrew D

Classifications

• G01N33/2876

  Total acid number · CPC title

• G01N33/2888

  Lubricating oil characteristics, e.g. deterioration (lubricating properties G01N33/30) · CPC title

• C10N2010/04

  Groups 2 or 12 · CPC title

• C10N2030/52

  Base number [TBN] · CPC title

• C10N2040/252

  Diesel engines · CPC title