Determining composition of a sample

Patent metadata

Field	Value
Publication number	US-10845306-B2
Application number	US-201715681940-A
Country	US
Kind code	B2
Filing date	Aug 21, 2017
Priority date	Aug 21, 2017
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

A single-wavelength light source is configured to generate an excitation light source. A sample holder that defines an inner cavity is capable of holding a sample and includes a surface transparent to the excitation light source. One or more mounts are attached to at least one of the light source or the sample holder. The mounts are configured to change an incident angle of the excitation light source on the surface. One or more optical components are positioned in a path of a fluorescence emission emitted from the surface and guide the fluorescence emission to a detector. A detector detects an intensity of the fluorescence emission.

First claim

What is claimed is:

1. A fluorescence-measurement apparatus, comprising:
a single-wavelength light source configured to generate an excitation light;
a sample holder defining an inner cavity configured to hold a sample and including a surface transparent to the excitation light, the light source and the sample holder spatially arranged such that, during a sample test, a portion of the excitation light incident on the surface passes through the surface and is incident on the sample in the sample holder at a depth from the surface, wherein the sample is configured to emit fluorescence in response to the portion of the excitation light incident on the sample at the depth from the surface;
one or more mounts attached to at least one of the light source or the sample holder and configured to actively change an incident angle of the excitation light incident on the surface during the sample test and responsively vary the depth from the surface at which the portion of the excitation light is incident on the sample, wherein the one or more mounts comprises a rotatable mount attached to a base of the sample holder and configured to rotate the surface of the sample holder in relation to the excitation light source;
one or more optical components spatially arranged to receive a portion of the fluorescence emitted by the sample and passing through the surface and configured to guide the received to a detector; and
the detector configured to detect an intensity of the fluorescence emission.

2. The fluorescence-measurement apparatus of claim 1 , wherein an axis of rotation of the sample holder is positioned vertically through the center of the sample holder.

3. The fluorescence-measurement apparatus of claim 1 , wherein an axis of rotation of the sample holder is positioned vertically through the center of the surface of the sample holder.

4. The fluorescence-measurement apparatus of claim 1 , wherein the surface is tilted relative to a vertical axis in range from 0°-80°.

5. The fluorescence-measurement apparatus of claim 1 , wherein the light source comprises a laser in an ultraviolet spectrum at a defined wavelength.

6. The fluorescence-measurement apparatus of claim 1 , wherein the detector comprises a monochromator coupled to a photomultiplier.

7. The fluorescence-measurement apparatus of claim 1 , further comprising a filter positioned between the surface and the detector and configured to pass a specified range of wavelengths and filter out wavelengths different from the specified range.

8. The fluorescence-measurement apparatus of claim 1 , wherein the one or more optical components comprise:
a lens positioned between the surface and the detector and configured to focus the fluorescence emission on an inlet of a fiber optic cable; and
a fiber optic cable positioned between the lens and the detector and having the inlet configured to receive the focused fluorescence emission and an outlet positioned to direct the focused fluorescence emission to the detector.

9. The fluorescence-measurement apparatus of claim 1 , wherein the sample comprises a hydrocarbon fluid.

Assignees

• Saudi Arabian Oil Co

Inventors

• Hegazi Ezzat
• Cunningham Vincent

Classifications

• G01N2201/129

  Using chemometrical methods · CPC title

• G01N2021/6484

  Optical fibres · CPC title

• G01N2021/6482

  Sample cells, cuvettes · CPC title

• G01N2021/392

  Measuring reradiation, e.g. fluorescence, backscatter · CPC title

• G01N2021/135

  Sample holder displaceable · CPC title