Apparatus, system and method for gas detection, and apparatus manufacturing method

Patent metadata

Field	Value
Publication number	US-10845303-B2
Application number	US-202016897930-A
Country	US
Kind code	B2
Filing date	Jun 10, 2020
Priority date	Apr 11, 2019
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

A sensing apparatus for detecting at least one target molecule in a gaseous medium is provided, comprising an optical fiber having a core with a tilted grating, and a coating assembly. The coating assembly has a composite film layer having an outer surface in direct contact with the gaseous medium, and contains at least two compositions mixed with one another therein, which include one or more surface plasmon resonance (SPR)-active compositions and one or more reacting compositions that are reversibly reactive to the at least one target molecule. Depending on different reacting compositions, the sensing apparatus can detect various target gas molecules such as hydrogen, ammonia, methane, and formaldehyde, etc. The sensing apparatus has relatively fast response time and high resistance to deactivation. A sensing system based on the sensing apparatus, a manufacturing method of the sensing apparatus, and a detection method using the sensing system, are further provided.

First claim

The invention claimed is:

1. A sensing apparatus for selectively detecting at least one target molecule in a gaseous medium, comprising an optical fiber and a coating assembly coating an outer surface of the optical fiber, wherein:
the optical fiber comprises a core and a cladding surrounding the core, wherein the core is provided with a tilted grating, configured to generate surface plasmon waves at an interface between the coating assembly and the gaseous medium upon a compatible electromagnetic radiation propagating in the optical fiber; and
the coating assembly comprises a composite film layer having an outer surface in direct contact with the gaseous medium, wherein:
the composite film layer comprises at least two compositions mixed with one another therein, wherein:
the at least two compositions comprise one or more active compositions, each configured to be active to surface plasmon resonance (SPR); and
the at least two compositions comprise one or more reacting compositions, each configured to be reversibly reactive to one or more of the at least one target molecule.

2. The sensing apparatus of claim 1 , wherein the one or more active compositions in the composite film layer comprise at least one of gold (Au), silver (Ag), platinum (Pt), aluminum (Al), or copper (Cu).

3. The sensing apparatus of claim 1 , wherein the one or more reacting compositions in the composite film layer comprise at least one of palladium (Pd), metallic La—Mg 2 —Ni, tungsten trioxide (WO 3 ), carbon nanotubes (CNT), Si nanowires, tin dioxide (SnO 2 ), a metal-polymer hybrid nanomaterial, a semiconductor oxide nanostructure, a core/shell plasmonic nanorod metamaterial, zinc oxide (ZnO), titanium oxide (TiO 2 ), iron oxide (Fe 2 O 3 /Fe 3 O 4 ), polyaniline, polypyrrole, metal phthalocyanine, graphite oxide, or copper (II) oxide (CuO).

4. The sensing apparatus of claim 3 , wherein the one or more reacting compositions in the composite film layer comprise at least one of palladium (Pd), metallic La—Mg 2 —Ni, Si nanowires, a metal-polymer hybrid nanomaterial, a semiconductor oxide nanostructure, a core/shell plasmonic nanorod metamaterial, and the at least one target molecule comprises hydrogen (H 2 ).

5. The sensing apparatus of claim 4 , wherein the one or more reacting compositions comprise palladium (Pd), having a weight concentration of approximately 20%-80% in the composite film layer.

6. The sensing apparatus of claim 5 , wherein the one or more active compositions in the composite film layer comprise gold (Au).

7. The sensing apparatus of claim 3 , wherein:
the one or more reacting compositions comprise WO 3 , and the at least one target molecule comprises at least one of hydrogen (H 2 ), H 2 S, or ammonia (NH 3 );
the one or more reacting compositions comprise SnO 2 , and the at least one target molecule comprises at least one of hydrogen (H 2 ), CH 4 , formaldehyde, benzene, or ammonia (NH 3 );
the one or more reacting compositions comprise CuO, and the at least one target molecule comprises NO 2 ;
the one or more reacting compositions comprise TiO 2 , and the at least one target molecule comprises at least one of CO or ammonia (NH 3 );
the one or more reacting compositions comprise ZnO, and the at least one target molecule comprises at least one of NO, formaldehyde, or ammonia (NH 3 );
the one or more reacting compositions comprise carbon nanotubes, and the at least one target molecule comprises hydrogen (H 2 ), benzene; or
the one or more reacting compositions comprise at least one of iron oxide (Fe 2 O 3 /Fe 3 O 4 ), polyaniline, polypyrrole, or metal phthalocyanines, and the at least one target molecule comprises ammonia (NH 3 ).

8. The sensing apparatus of claim 1 , wherein the composite film layer has a thickness in range of approximately 25-75 nm.

9. The sensing apparatus of claim 1 , wherein an internal tilt angle of the tilted grating is at least approximately 20 degrees.

10. The sensing apparatus of claim 1 , wherein the coating assembly further comprises a transition layer, sandwiched between the outer surface of the optical fiber and an inner surface of the composite film layer, wherein the transition layer is configured to improve adhesion of the composite film layer to the optical fiber, wherein the transition layer comprises at least one of titanium (Ti), molybdenum (Mo), or chromium (Cr).

11. The sensing apparatus of claim 1 , wherein the coating assembly further comprises a substrate layer, sandwiched between the outer surface of the optical fiber and an inner surface of the composite film layer, wherein the substrate layer is configured to be active to SPR and comprises at least one of gold (Au), silver (Ag), platinum (Pt), aluminum (Al), or copper (Cu).

12. The sensing apparatus of claim 11 , wherein the coating assembly further comprises a transition layer, sandwiched between the outer surface of the optical fiber and an inner surface of the substrate layer, wherein the transition layer is configured to improve adhesion of the substrate layer to the optical fiber, wherein the transition layer comprises at least one of titanium (Ti), molybdenum (Mo), or chromium (Cr).

13. A sensing system, comprising:
the sensing apparatus according to claim 1 ;
a light source apparatus, optically coupled to a first end of, and configured to provide an input light into, the sensing apparatus so as to allow the electromagnetic radiation to propagate in the core of the optical fiber of the sensing apparatus; and
a signal detection apparatus, coupled to the sensing apparatus and configured to obtain the signals of the surface plasmon waves therefrom so as to derive the information of the at least one target molecule in the gaseous medium.

14. The sensing system of claim 13 , wherein:
the light source apparatus comprises a broadband source (BBS), and the signal detection apparatus comprises an optical spectrum analyzer (OSA); or
the light source comprises a tunable laser source (TLS), and the signal detection apparatus comprises:
an optical detector, configured to detect, and to convert into analog electrical signals, the signals of the plasmon waves from the sensing apparatus; and
an analog-to-digital converter, configured to convert the analog electrical signals into digital electrical signals.

15. The sensing system of claim 13 , wherein the signal detection apparatus is coupled to the first end of the optical fiber, wherein:
a second end of the optical fiber is provided with a mirror having a reflection surface facing to, configured to reflect the electromagnetic radiation back towards, the first end of the optical fiber; and
the sensing system further comprises a coupler, wherein:
the coupler is arranged between the light source apparatus and the sensing apparatus along an input optical pathway and between the sensing apparatus and the signal detection apparatus along an output optical pathway; and
the coupler is configured to separate the input optical pathway and the output optical pathway to thereby allow the signal detection apparatus to obtain the signals of the surface plasmon waves from the sensing apparatus without being influenced by the input light.

16. A method for manufacturing a sensing apparatus capable of selectively detecting at least one target molecule in a gaseous medium, comprising:
providing an optical fiber, wherein the optical fiber comprises a core and a cladding surrounding the core, and the core is provided with a tilted grating, configured to generate surface plasmon waves at an interface between the coating assembly and the gaseous medium upon a compatib

Assignees

• Univ Jinan

Inventors

• Guo Tuan
• Caucheteur Christophe
• Liu Fu
• Zhang Xuejun
• Cai Shunshuo

Classifications

• Y02A50/20

  Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• G01N21/553

  and using surface plasmons (fluorescence excitation G01N21/648; enhanced Raman G01N21/658) · CPC title

• G01N33/004

  CO or CO2 · CPC title

• G01N33/0037

  NOx · CPC title