White anodic films with multiple layers
US-2017121836-A1 · May 4, 2017 · US
US10844506B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10844506-B2 |
| Application number | US-201816201969-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 27, 2018 |
| Priority date | Nov 28, 2017 |
| Publication date | Nov 24, 2020 |
| Grant date | Nov 24, 2020 |
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An aluminum member comprises a base material made of aluminum or art aluminum alloy, and an anodized coating provided on a surface of the base material and having a thickness of 100 μm or less. The anodized coating comprises a barrier layer formed on the surface of the base material and having a thickness of 10 to 150 nm, and a porous layer formed on the barrier layer and having a thickness of 6 μm or more. The porous layer comprises a first pore extending in a thickness direction of the porous layer from a boundary between the porous layer and the barrier layer, and a second pore connected to the first pore and extending so as to branch radially in the thickness direction of the porous layer toward a surface of the porous layer.
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What is claimed is: 1. An aluminum member comprising: a base material made of aluminum or an aluminum alloy; and an anodized coating provided on a surface of the base material and having a thickness of 100 μm or less, wherein the anodized coating comprises a barrier layer formed on the surface of the base material and having a thickness of 10 to 150 nm, wherein the barrier layer includes a first surface adjacent to the base material and a second surface opposite the first surface, and a porous layer formed on the second surface of the barrier layer and having a thickness of 6 μm or more, and the porous layer comprises a plurality of first pores extending in a thickness direction of the porous layer from the second surface of the barrier layer between the porous layer and the barrier layer toward a surface of the porous layer opposite the second surface of the barrier layer; and a plurality of second pores connected to the plurality of first pores and extending so as to branch radially in the thickness direction of the porous layer toward the surface of the porous layer, an angle of the plurality of second pores with the surface of the base material being 30 to 85 degrees, wherein the anodized coating is white and comprises an aluminum oxide, and wherein a brightness by Hunter of the aluminum member, as measured from a surface of the anodized coating, is 70 to 90. 2. The aluminum member according to claim 1 , wherein an average diameter of the plurality of first pores is 10 to 150 nm, and an average spacing between individual ones of the plurality of first pores adjacent to each other is 25 to 400 nm. 3. A method of manufacturing an aluminum member, wherein the aluminum member comprises a base material made of aluminum or an aluminum alloy, and an anodized coating provided on a surface of the base material and having a thickness of 100 μm or less, the anodized coating comprises a barrier layer formed on the surface of the base material and having a thickness of 10 to 150 nm, wherein the barrier layer includes a first surface adjacent to the base material and a second surface opposite the first surface, and a porous layer formed on the second surface of the barrier layer and having a thickness of 6 μm or more, and the porous layer comprises a plurality of first pores extending in a thickness direction of the porous layer from the second surface of the barrier layer between the porous layer and the barrier layer toward a surface of the porous layer opposite the second surface of the barrier layer; and a plurality of second pores connected to the plurality of first pores and extending so as to branch radially in the thickness direction of the porous layer toward the surface of the porous layer, an angle of the plurality of second pores with the surface of the base material being 30 to 85 degrees, wherein the anodized coating is white and comprises an aluminum oxide, and wherein a brightness by Hunter of the aluminum member, as measured from a surface of the anodized coating, is 70 to 90, the method comprising: preparing the base material made of aluminum or an aluminum alloy; and performing anodization on the base material in an electrolytic solution under conditions where a current density is 5 to 30 mA·cm −2 and a temperature of the electrolytic solution is 0 to 80° C., the electrolytic solution comprising: a first acid or a salt of the first acid at a concentration of 0.01 to 2.0 mol·dm −3 , the first acid being selected from a group consisting of an inorganic acid and an organic carboxylic acid; and a second acid at a concentration of 0.01 to 5.0 mol·dm −3 , the second acid being at least one acid anhydride selected from a group consisting of diphosphoric acid, triphosphoric acid, and polyphosphoric acid. 4. The aluminum member according to claim 1 , wherein the anodized coating is opaque.
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