High flashpoint alcohol-based cleaning, sanitizing and disinfecting composition and method of use on food contact surfaces

Patent metadata

Field	Value
Publication number	US-10844322-B2
Application number	US-201213568724-A
Country	US
Kind code	B2
Filing date	Aug 7, 2012
Priority date	Aug 7, 2012
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

The invention is directed to a high flashpoint alcohol based cleaning, sanitizing and disinfecting composition and its method of use on food contact surfaces. More particularly, the present invention relates to a quick drying and ready to use cleaning and sanitizing formula with an isopropyl alcohol level low enough to permit a reduced flammability rating while maintaining microbiological sanitizing and disinfecting properties.

First claim

The following is claimed:

1. A ready to use cleaning, sanitizing and disinfecting composition comprising:
(a) about 1 to about 12.1 wt % alcohol;
(b) one or more anionic, nonionic, cationic, amphoteric or zwitterionic surfactants or mixtures thereof;
(c) an antimicrobial amount of quaternary ammonium alkyl or aryl salt or a combination thereof;
(d) about 0.001 to about 1 wt % hydrogen peroxide; and
(e) an effective amount of a peroxide stabilizing agent;
wherein the composition is an aqueous no-rinse use-solution having a pH of about pH 3 to about pH 12 and exhibits a closed cup flashpoint of greater than 100° F.; and
wherein the composition exhibits at least a 4 log reduction in Staphylococcus aureus ATCC 6538 or Escherichia coli ATCC 11229 in a 30 second food contact sanitizing test.

2. The composition of claim 1 further comprising a sequestering or scale removing agent.

3. The composition of claim 2 , the sequestering or scale removing agent comprising gluconic acid, acetic acid, citric acid, lactic acid, EDTA, NTA, HEDTA, acrylic acid polymers, methacrylic acid polymers, acrylic acid-methacrylic acid copolymers, water-soluble sodium, potassium or ammonium salts thereof, sodium, potassium, or ammonium phosphates thereof, or mixtures thereof.

4. The composition of claim 2 , wherein the sequestering or scale removing agent comprises citric acid or EDTA.

5. The composition of claim 1 further comprising a non-aqueous co-solvent.

6. The composition of claim 5 wherein the non-aqueous co-solvent comprises polypropylene glycol with a degree of polymerization from 10 to 200, benzyl alcohol, methyl benzyl alcohol, alpha phenyl ethanol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, ethylene glycol phenyl ether, propylene glycol phenyl ether, or a and combination thereof.

7. The composition of claim 5 wherein the non-aqueous co-solvent is less than 1 weight % of the composition.

8. The composition of claim 1 further comprising a pH buffering system.

9. The composition of claim 8 wherein the pH buffering system includes a pH adjusting agent comprises an organic acid, mineral acid, alkaline metal, alkaline earth salt, phosphoric acid, metal carbonate, or a mixture thereof.

10. The composition of claim 1 wherein the anionic surfactant comprises an alkali metal salt, alkanolamine salt of a C6-C24 saturated or unsaturated carboxylic acid, an alkylarylsulfonic acid or an alkyl sulfuric acid, sodium capryl sulfonate, sodium lauryl sulfate, linear alkyl benzene sulphonates/sodium dodecyl benzene sulfonate, decanoic acid, octanoic acid, n-pelargonic acid, or a mixture thereof.

11. The composition of claim 1 wherein the nonionic surfactant comprises an alkyl polyglucoside in which the alkyl group contains 8-18 carbon atoms, a glycerol fatty acid ester, a polyoxyethylene glycerol fatty acid ester, a polyoxyethylene sorbitan fatty acid ester, a polyethyleneglycol fatty acid ester, or & polyoxyethylene-polyoxypropylene block copolymer with terminal hydroxyl groups, or a combination thereof.

12. The composition of claim 1 , wherein the amphoteric and zwitterionic surfactants have a cationic amino group and an anionic carboxylate or sulfonate group.

13. The composition of claim 1 wherein the quaternary ammonium alkyl or aryl salt comprises a C6-C24 alkyl dimethyl benzyl ammonium chloride, octyl decyl dimethyl ammonium chloride, dioctyl dimethyl ammonium chloride, didecyl dimethyl ammonium chloride, or a mixture thereof.

14. The composition of claim 1 wherein the peroxide is between about 0.001 weight percent to about 0.2 weight percent of the composition.

15. The composition of claim 1 wherein the peroxide stabilizing agent further comprises hydroxyethylidene 1,1-diphosphonic acid (HEDP), 2-Aminoethylphosphonic acid (AEPn), Dimethyl methylphosphonate (DMMP), ATMP: Amino tris(methylene phosphonic acid) (ATMP), EDTMP: Ethylenediamine tetra(methylene phosphonic acid) (EDTMP), Tetramethylenediamine tetra(methylene phosphonic acid) (TDTMP), Hexamethylenediamine tetra(methylene phosphonic acid) (HDTMP), Diethylenetriamine penta(methylene phosphonic acid) (DTPMP), Phosphonobutane-tricarboxylic acid (PBTC), N-(phosphonomethyl)iminodiacetic acid (PMIDA), 2-carboxyethyl phosphonic acid (CEPA), 2-Hydroxyphosphonocarboxylic acid (HPAA), Amino-tris-(methylene-phosphonic acid) (AMP), or a mixture thereof.

16. A method of cleaning and sanitizing to remove oily soils on a food contact surface, the method comprising:
a. applying a ready to use, aqueous cleaning and sanitizing composition according to claim 1 onto the food contact surface; and
b. wiping the food contact surface with the composition to remove the oily soil on the food contact surface.

17. The composition of claim 1 , wherein the peroxide or peroxyacid stabilizing agent comprises dipicolinic acid.

18. The composition of claim 1 , wherein the surfactant comprises an alkyl alcohol alkoxylate.

19. The composition of claim 1 , wherein the pH is an alkaline pH.

20. The composition of claim 1 , wherein the pH is a neutral pH.

21. The composition of claim 1 , wherein the composition exhibits at least a 5 log reduction in Staphylococcus aureus ATCC 6538 or Escherichia coli ATCC 11229 in a 30 second food contact sanitizing test.

22. The composition of claim 1 , wherein the composition further exhibits at least a 1 log reduction in Enterobacter aerogenes ATCC 13048 in a 5 minute non-food contact sanitizing test.

23. The composition of claim 1 , wherein the composition further exhibits at least a 4 log reduction in Staphylococcus aureus ATCC 6538, Escherichia coli ATCC 11229, Pseudomonas aeruginosa ATCC 15442, Escherichia coli 0157:H7 ATCC 43895, Listeria monocytogenes ATCC 49594, Salmonella typhimurium ATCC 13311, Enterobacter sakazakii ATCC 12868, and Vibrio cholerae ATCC 25873.

24. A ready to use, aqueous cleaning, sanitizing and disinfecting composition comprising:
(e) about 1 to about 12.1 wt % isopropyl alcohol;
(f) a surfactant comprising an alkyl alcohol alkoxylate;
(g) an antimicrobial amount of quaternary ammonium alkyl or aryl salt or a combination thereof;
(h) about 0.001 to about 5 wt % hydrogen peroxide; and
(e) an effective amount of a peroxide stabilizing agent comprising dipicolinic acid;
wherein the composition has a pH of about pH 3 to about pH 12 and exhibits a closed cup flashpoint of greater than 100° F.; and
wherein the composition exhibits at least a 3 log reduction in Escherichia coli ATCC 11229 in a 5 minute non-food contact sanitizing test.

25. The composition of claim 24 , wherein the composition further exhibits at least a 5 log reduction in Staphylococcus aureus ATCC 6538 or Escherichia coli ATCC 11229 in a 30 second food contact sanitizing test.

26. The composition of claim 24 , wherein the pH is an alkaline pH.

27. The composition of claim 24 , wherein the pH is a neutral pH.

28. The composition of claim 24 , further comprising a sequestering or scale removing agent wherein the sequestering or scale removing agent comprises gluconic acid; acetic acid, citric acid, lactic acid, EDTA, NTA, HEDTA, acrylic acid polymers, methacrylic acid polymers, acrylic acid-methacrylic acid copolymers, water-soluble sodium, potassium or ammonium salts thereof, sodium, potassium or ammonium phosphates thereof, or a mixture thereof.

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Assignees

• Ryther Robert J
• Delaney Nicole M
• Hines Jesse D
• Grieme Linda E
• Ecolab Usa Inc

Inventors

• Ryther Robert J
• Delaney Nicole M
• Hines Jesse D
• Grieme Linda E

Classifications

• C11D3/2003

  Alcohols; Phenols · CPC title

• C11D1/62

  Quaternary ammonium compounds · CPC title

• C11D3/48

  Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions · CPC title

• C11D3/3947

  Liquid compositions · CPC title

• C11D3/2017 Primary

  branched · CPC title