Conversion of crude oil to aromatic and olefinic petrochemicals

Patent metadata

Field	Value
Publication number	US-10844296-B2
Application number	US-201715845557-A
Country	US
Kind code	B2
Filing date	Dec 18, 2017
Priority date	Jan 4, 2017
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

A system includes a hydroprocessing zone configured to remove impurities from crude oil; a first separation unit configured to separate a liquid output from the hydroprocessing zone into a light fraction and a heavy fraction; an aromatic extraction subsystem configured to extract aromatic petrochemicals from the light fraction; and a pyrolysis section configured to crack the heavy fraction into multiple olefinic products.

First claim

What is claimed is:

1. A system comprising:
a crude separation unit configured to separate an input stream of crude oil into streams consisting of a light fraction, and a heavy fraction;
a hydroprocessing zone configured to remove impurities from the heavy fraction;
a first separation unit configured to separate a hydroprocessed effluent from the hydroprocessing zone into separator tops and separator bottoms;
an aromatic extraction subsystem configured to extract aromatic petrochemicals from the separator tops before feeding the separator tops to a reformer; and
a pyrolysis section configured to crack the separator bottoms into multiple olefinic products.

2. The system of claim 1 , in which the aromatic extraction subsystem comprises an aromatic extraction unit configured to separate aromatic petrochemicals of the separator tops from other components of the separator tops by one or more of solvent extraction and extractive distillation.

3. The system of claim 2 , in which the aromatic extraction subsystem comprises a reformer configured to convert the separator tops into a reformate, and in which the aromatic extraction unit is configured to receive the reformate.

4. The system of claim 3 , in which the reformate is rich in aromatic petrochemicals compared to the separator tops.

5. The system of claim 3 , in which the aromatic extraction subsystem comprises a second separation unit configured to separate an output from the reformer into the reformate and a byproduct fraction.

6. The system of claim 5 , comprising a gas separation unit configured to separate the byproduct fraction into hydrogen and light gases.

7. The system of claim 6 , in which the hydrogen is provided to the hydroprocessing zone.

8. The system of claim 6 , in which the light gases are provided to the pyrolysis section.

9. The system of claim 3 , in which the reformer is configured to convert the separator tops into the reformate by one or more of hydrocracking, isomerization, dehydrocyclization, and dehydrogenation.

10. The system of claim 3 , in which the reformer comprises a catalyst configured to catalyze production of aromatic petrochemicals.

11. The system of claim 2 , in which the other components of the separator tops are returned to the hydroprocessing zone.

12. The system of claim 5 , in which the aromatic extraction unit is configured to receive the reformate from the second separation unit and to generate an output stream that is rich in aromatics compared to the reformate.

13. The system of claim 12 , in which aromatic extraction subsystem comprises a reformer configured to convert the output stream into a reformate, and in which the aromatic extraction unit is configured to receive the reformate.

14. The system of claim 1 , in which the light fraction is provided to the pyrolysis section.

15. The system of claim 1 , comprising a fourth separation zone configured to separate an effluent from the hydroprocessing zone into a gas output from the hydroprocessing zone and the liquid output from the hydroprocessing zone.

16. The system of claim 1 , comprising a gas separation unit configured to separate a gas output from the hydroprocessing zone into hydrogen and light gases.

17. The system of claim 16 , in which the hydrogen is provided to the hydroprocessing zone.

18. The system of claim 16 , in which the light gases are provided to the pyrolysis section.

19. The system of claim 1 , comprising a fifth separation zone configured to remove fuel oil from the separator bottoms, the fifth separation zone positioned upstream of the pyrolysis section.

20. The system of claim 1 , in which the first separation unit comprises a flash separation device.

21. The system of claim 1 , in which the first separation unit comprises a separation device that physically or mechanically separates vapor from liquid.

22. The system of claim 1 , in which the pyrolysis section comprises a steam pyrolysis unit.

23. The system of claim 1 , in which the pyrolysis section is configured to crack the separator bottoms into one or more of methane, ethylene, propylene, butadiene, and butene.

24. The system of claim 1 , in which the hydroprocessing zone comprises one or more of (i) a hydrodemetallization catalyst and (ii) a catalyst having one or more of hydrodearomatization, hydrodenitrogenation, hydrodesulfurization, and hydrocracking functions.

25. The system of claim 1 , comprising a purification unit configured to separate the cracked separator bottoms into multiple streams, each stream corresponding to one of the multiple products.

Assignees

• Saudi Arabian Oil Co

Inventors

• Abudawoud Raed
• Mohammad Thamer
• Ballesteros Alberto Lozano
• Al Sayed Essam

Classifications

• C10G2400/30

  Aromatics · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C10G69/14 Primary

  plural parallel stages only · CPC title

• C10G69/06 Primary

  including at least one step of thermal cracking in the absence of hydrogen · CPC title

• C10G67/04

  including solvent extraction as the refining step in the absence of hydrogen · CPC title