Method of heat transfer between a metallic or non-metallic item and a heat transfer fluid

Patent metadata

Field	Value
Publication number	US-10844261-B2
Application number	US-201616064720-A
Country	US
Kind code	B2
Filing date	Dec 20, 2016
Priority date	Dec 22, 2015
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

A method of heat transfer between a metallic or non-metallic item and a heat transfer fluid is provided. The method includes a fluid medium and nanoparticles. A thickness/lateral size ratio of the nanoparticles is below 0.00044. The nanoparticles do not include carbon nanotubes.

First claim

What is claimed is:

1. A method of heat transfer between a metallic or non-metallic item comprising the step of:
transferring heat between a metallic or non-metallic item and a heat transfer fluid including a fluid medium and nanoparticles, a lateral size of the nanoparticles being between 26 and 50 μm, a thickness/lateral size ratio of the nanoparticles being more than or equal to 0.00015 and less than 0.00044, wherein the nanoparticles do not include carbon nanotubes.

2. The method according to claim 1 , wherein the thickness/lateral size ratio is more than or equal to 0.00015 and less than 0.00043.

3. The method according to claim 2 , wherein the thickness/lateral size ratio is from 0.00015 to 0.00040.

4. The method according to claim 3 , wherein the thickness/lateral size ratio is from 0.00015 to 0.00035.

5. The method according to claim 4 , wherein the thickness/lateral size ratio is from 0.00020 to 0.00030.

6. The method according to claim 1 , wherein a thickness of the nanoparticles is from 1 to 99.99 nm.

7. The method according to claim 6 , wherein the thickness of the nanoparticles is from 5 to 50 nm.

8. The method according to claim 7 , wherein the thickness of the nanoparticles is from 5 to 15 nm.

9. The method according to claim 1 , wherein a lateral size of the nanoparticles is from 26 to 50 μm.

10. The method according to claim 9 , wherein the lateral size of the nanoparticles is from 35 to 45 μm.

11. The method according to claim 1 , wherein a nanoparticles concentration is from 0.01 to 12 wt. %.

12. The method according to claim 11 , wherein the nanoparticles concentration is from 2 to 8 wt. %.

13. The method according to claim 12 , wherein the nanoparticles concentration is from 4 to 7 wt. %.

14. The method according to claim 1 , wherein the nanoparticles are multilayered nanoplatelets.

15. The method according to claim 1 , wherein the nanoparticles are selected from a group consisting of: graphite nanoplatelets, graphene, few layers graphene, TiO 2 , ZnO 2 , ZnO, Boron-nitride, copper, silica, montmorillonite, zeolite clipnoptilolite, wollastonite, mica, zeolite 4A, Al 2 O 3 , silicate, pumice and calcium oxide.

16. The method according to claim 1 , wherein the heat transfer fluid includes a dispersing agent.

17. The method according to claim 16 , wherein the dispersing agent is a non-surface active polymer, a surfactant or a mixture thereof.

18. The method according to claim 17 , wherein the surfactant is cationic, anionic, amphoteric or non-ionic.

19. The method according to claim 18 , wherein the dispersing agent is selected from a group consisting of: polyvinnylpyrrolidone, polysaccharides, sulphated polysaccharides, linear alkylbenzene sulfonates, lignin sulfonates, di-alkyl sulfosuccinates, quaternary ammonium compounds and sodium stearate and a mixture thereof.

20. The method according to claim 16 , wherein a nanoparticles concentration/dispersing agent concentration ratio in weight is from 3 to 18.

21. The method according to claim 1 , wherein the fluid medium is selected from a group consisting of: water, ethylene glycol, ethanol, oil, methanol, silicone, propylene glycol, alkylated aromatics, liquid Ga, liquid In, liquid Sn, potassium formate and a mixture thereof.

22. The method according to claim 1 , wherein the heat transfer fluid is in laminar or turbulent regime flow.

23. The method according to claim 1 , wherein the item is metallic and is made of aluminum, steel, stainless steel, copper, iron, copper alloys, titanium, cobalt, metal composite or nickel.

24. The method according to claim 1 , wherein the metallic item is a heat exchanger and the heat transfer is realized with the fluid being inside the heat exchanger.

25. The method according to claim 1 , wherein the metallic item is a metallic substrate and the heat transfer is such that the heat transfer fluid is in direct contact with the metallic substrate.

26. The method according to claim 25 , wherein the contact between the metallic substrate and the heat transfer fluid is realized though jet impingement cooling, pool boiling, spray cooling or micro-channel cooling.

27. A method for the manufacture of a heat transfer fluid comprising:
providing nanoparticles, a lateral size of the nanoparticles being between 26 and 50 μm, a thickness/lateral size ratio of the nanoparticles being more than or equal to 0.00015 and less than 0.00044, wherein the nanoparticles do not include carbon nanotubess;
providing a fluid medium;
adjusting a nanoparticle concentration in order to achieve percolation; and
mixing the nanoparticles with the fluid medium.

28. A heat transfer fluid comprising:
the heat transfer fluid recited in claim 1 .

29. A heat transfer fluid manufactured by the process of claim 27 .

30. A heat transfer fluid comprising:
a fluid medium; and
nanoparticles;
a lateral size of the nanoparticles being between 26 and 50 μm,
a thickness/lateral size ratio of the nanoparticles being more than or equal to 0.00015 and less than 0.00044,
the nanoparticles not including carbon nanotubes.

31. A method of heat transfer between a metallic or non-metallic item comprising the step of:
transferring heat between a metallic or non-metallic item and a heat transfer fluid including a fluid medium and nanoparticles, a lateral size of the nanoparticles being between 26 and 50 μm, a thickness/lateral size ratio of the nanoparticles being more than or equal to 0.00015 and less than 0.00044, wherein the nanoparticles do not include carbon nanotubes and are selected from a group consisting of: graphite nanoplatelets, graphene, few layers graphene, TiO 2 , ZnO 2 , ZnO, copper, silica, montmorillonite, zeolite clipnoptilolite, wollastonite, mica, zeolite 4A, Al 2 O 3 , silicate, pumice and calcium oxide.

32. The method according to claim 1 , wherein the thickness/lateral size ratio is 0.00025.

Assignees

• Arcelormittal

Inventors

• NORIEGA PEREZ David

Classifications

• C09K5/10 Primary

  Liquid materials · CPC title

• C09K5/063 Primary

  Materials absorbing or liberating heat during crystallisation; Heat storage materials · CPC title

• C21D1/00

  General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering · CPC title

• C21D1/56

  characterised by the quenching agents · CPC title

• C21D1/667

  for spray quenching · CPC title