Silica molded bodies having low thermal conductivity

Patent metadata

Field	Value
Publication number	US-10843965-B2
Application number	US-201615754394-A
Country	US
Kind code	B2
Filing date	Aug 9, 2016
Priority date	Aug 28, 2015
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

Hydrophobic shaped silica bodies having low density and low thermal conductivity are produced by forming a dispersion of silica in a solution of binder and organic solvent, and removing the solvent and shaping to form a shaped body. The shaped bodies retain their hydrophobicity, are stable with regards to shape, and are useful in acoustic and thermal insulation.

First claim

The invention claimed is:

1. A process for producing silica granules having a C content of less than 8% by weight,
a density, determined by Hg porosimetry, of less than 0.30 g/cm 3 ,
a pore volume for pores smaller than 4 μm, determined by Hg porosimetry, of more than 2.0 cm 3 /g,
a proportion of the pores smaller than 4 μm, based on the total pore volume, of at least 60% and
a thermal conductivity, determined by a non-steady-state method, of less than 30 mW/K*m,
comprising:
i) producing a dispersion containing pyrogenic silica, at least one binder and an organic solvent, and
ii) evaporating the solvent from the dispersion, and shaping to form the shaped silica bodies.

2. The process of claim 1 , wherein the pyrogenic silica is selected from the group consisting of hydrophilic pyrogenic silica and mixtures of hydrophilic pyrogenic silica and partially hydrophobic pyrogenic silica.

3. The process of claim 1 , wherein at least one silane of the formula
Z 1+x —Si((CH 2 ) v Y)R 2−x

where Z is a methoxy or ethoxy group, R is a C 1 -C 3 alkyl group or C 2-3 alkenyl group, Y is hydrogen, a saturated or monounsaturated or polyunsaturated C 1 -C 20 -hydrocarbon radical, —OC(O)C(R′)═CH 2 , -vinyl, -hydroxyl, -halogen, phosphonato, —NCO, —NH—C(O)—OR″, -glycidoxy, —SH, or acid anhydride, x is 1 or 2 and v is 0, 1, or 3 is used as a binder.

4. The process of claim 1 , wherein the solvent is selected from the group consisting of alkanes, ethers, alcohols, and mixtures thereof.

5. Silica granules produced by the process of claim 1 .

6. Acoustic or thermal insulation comprising silica granules of claim 5 .

Assignees

• Wacker Chemie Ag

Inventors

• Jantke Dominik
• Weidner Richard
• Hindelang Konrad

Classifications

• C04B2201/30

  for heat transfer properties such as thermal insulation values, e.g. R-values · CPC title

• C04B2111/52

  Sound-insulating materials · CPC title

• C04B2111/40

  Porous or lightweight materials · CPC title

• C04B38/0093

  Other features · CPC title

• C04B38/009 Primary

  Porous or hollow ceramic granular materials, e.g. microballoons (C04B18/027, C04B20/002 take precedence) · CPC title