Process for the production of thermoplastic moulding compounds

Patent metadata

Field	Value
Publication number	US-10843384-B2
Application number	US-201615735286-A
Country	US
Kind code	B2
Filing date	Jun 9, 2016
Priority date	Jun 12, 2015
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

The invention relates to a process for the production of thermoplastic moulding compounds, in particular for the production of acrylonitrile-butadiene-styrene (ABS), wherein at least a first reagent (11) and a second reagent (12) of the thermoplastic moulding compounds are fed to a loop conduit (29) which comprises a static mixer (36), wherein the reagents (11, 12) are pressed in loops through the loop conduit (29) and passing the static mixer (36), whereby the reagents (11, 12) are dispersed to form a dispersion (15) in the static mixer (36). The invention also relates to a thermoplastic moulding compound that is produced by the inventive process.

First claim

The invention claimed is:

1. A process for the production of acrylonitrile-butadiene-styrene (ABS), comprising the following steps:
a. adding at least one solvent to a first reagent ( 11 ) that contains or consists of styrene-acrylonitrile copolymer (SAN) and a second reagent ( 12 ) that contains or consists of rubber,
b. mixing the at least one solvent, the first reagent ( 11 ) and the second reagent ( 12 ) in a mixing vessel ( 50 ) to form a premix,
c. feeding the premix to a loop conduit ( 29 ) which comprises at least one static mixer ( 36 ),
d. pressing the reagents ( 11 , 12 ) in loops through the loop conduit ( 29 ), and
e. dispersing the reagents ( 11 , 12 ) to form a dispersion ( 15 ) in the static mixer ( 36 ),

and wherein the premix is pressed through the static mixer ( 36 ) back to a mixing vessel ( 50 ).

2. The process according to claim 1 , comprising a step of feeding the first reagent ( 11 ) styrene-acrylonitrile copolymer (SAN) to the loop conduit ( 29 ) in a molten state.

3. The process according to claim 1 , comprising a step of heating the first reagent ( 11 ), which contains or consists of styrene-acrylonitrile copolymer (SAN), above melting temperature.

4. The process according to claim 1 , comprising a step of feeding the second reagent ( 12 ), which contains or consists of rubber, to the loop conduit ( 29 ) as relatively fine powder.

5. The process according to claim 1 , comprising a step of feeding the second reagent ( 12 ) rubber to the loop conduit ( 29 ) in a molten state.

6. The process according to claim 1 , comprising a step of feeding the premix directly into the loop conduit ( 29 ).

7. The process according to claim 1 , comprising a step of storing the premix temporarily and later feeding the premix to the loop conduit ( 29 ).

8. The process according to claim 1 , comprising a step of pressing the reagents ( 11 , 12 ) in loops through the loop conduit ( 29 ) from 1 time to 100 times.

9. The process according to claim 1 , comprising a step of pressing the reagents ( 11 , 12 ) in loops through the loop conduit ( 29 ) by a first pump.

10. The process according to claim 1 , comprising a step of dispersing the reagents ( 11 , 12 ) at a temperature at a range of 160° C. to 250° C.

11. The process according to claim 1 , comprising a step of processing the dispersion ( 15 ) further to form acrylonitrile-butadiene-styrene (ABS).

12. The process according to claim 1 , further comprising the steps of:
a. feeding the premix to an inlet ( 42 ) of a first pump ( 10 ) while an outgoing valve ( 67 ) for taking the dispersion ( 15 ) out of the loop conduit ( 29 ) is closed,
b. forwarding the premix in loops through the loop conduit ( 29 ) toward the static mixer ( 36 ) by of the first pump ( 10 ),
c. opening the outgoing valve ( 67 ) after a certain number of loops within the loop conduit ( 29 ),
d. pressing out the dispersion ( 15 ) of the loop conduit ( 29 ) and delivering the dispersion ( 15 ) through the outgoing valve ( 67 ) by the first pump ( 10 ).

13. The process according to claim 12 , wherein
the outgoing valve ( 67 ) is arranged at a branch downstream of the mixing vessel ( 50 ) and upstream of the first pump ( 10 ).

Assignees

• Ineos Styrolution Group Gmbh

Inventors

• Ahn Sangjun
• Fischer Wolfgang
• Niessner Norbert
• Banaszak Brian J
• Walker Roland
• El-Jaby Ula
• Stammer Achim
• Hungenberg Klaus-Dieter
• Hisgen Bernd

Classifications

• C08F279/04

  Vinyl aromatic monomers and nitriles as the only monomers · CPC title

• B01J19/1881

  externally, i.e. the mixture leaving the vessel and subsequently re-entering it · CPC title

• C08L25/12

  with unsaturated nitriles · CPC title

• B29B7/7466

  Combinations of similar mixers · CPC title

• B01J8/10

  moved by stirrers or by rotary drums or rotary receptacles {or endless belts} · CPC title