Low-adhesion coatings with solid-state lubricants

Patent metadata

Field	Value
Publication number	US-10836974-B2
Application number	US-201715638340-A
Country	US
Kind code	B2
Filing date	Jun 29, 2017
Priority date	Mar 14, 2014
Publication date	Nov 17, 2020
Grant date	Nov 17, 2020

Abstract

Some variations provide a low-adhesion coating comprising a continuous matrix containing a first component, a plurality of inclusions containing a second component, and a solid-state lubricant distributed within the coating, wherein one of the first component or the second component is a low-surface-energy polymer, and the other of the first component or the second component is a hygroscopic material. The solid-state lubricant may be selected from graphite, graphene, molybdenum disulfide, tungsten disulfide, hexagonal boron nitride, or poly(tetrafluoroethylene) or other fluoropolymers. The solid-state lubricant particles may be coated with a metal selected from cadmium, lead, tin, zinc, copper, nickel, or alloys containing one or more of these metals. The solid-state lubricant is typically characterized by an average particle size from about 0.1 μm to about 500 μm. The solid-state lubricant is preferably distributed throughout the coating.

First claim

What is claimed is:

1. A low-adhesion composition containing a solventborne copolymer composition comprising:
(a) first soft segments comprising fluoropolymers that are present in the triblock structure:

wherein:
X, Y=CH 2 —(O—CH 2 —CH 2 ) p -T, and X and Y are independently selected;
p=1 to 50;
T is a hydroxyl or amine terminal group;
m=1 to 100; and
n=1 to 100;
(b) second soft segments comprising polyesters or polyethers, wherein said polyesters or polyethers are (α,ω)-hydroxyl-terminated and/or (α,ω)-amine-terminated;
(c) one or more isocyanate species possessing an average isocyanate functionality of about 2 or greater, or a reacted form thereof;
(d) one or more polyol or polyamine chain extenders or crosslinkers possessing an average functionality of about 2 or greater, or a reacted form thereof, wherein said polyol or polyamine chain extenders or crosslinkers contain hydroxyl-terminated or amine-terminated compounds that are reactive with said isocyanate species; and
(e) one or more solid-state lubricants distributed throughout said composition, wherein the molar ratio of said second soft segments to said first soft segments is 1.7 or less.

2. The low-adhesion composition of claim 1 , wherein said solid-state lubricants are selected from the group consisting of graphite, graphene, molybdenum disulfide, tungsten disulfide, hexagonal boron nitride, poly(tetrafluoroethylene), fluoropolymers, and combinations thereof.

3. The low-adhesion composition of claim 1 , wherein said solid-state lubricants are particles coated with a metal selected from the group consisting of cadmium, lead, tin, zinc, copper, nickel, and combinations or alloys thereof.

4. The low-adhesion composition of claim 1 , wherein said solid-state lubricants have an average particle size from about 0.1 μm to about 500 μm.

5. The low-adhesion composition of claim 1 , wherein said solid-state lubricants are distributed uniformly throughout said composition.

6. The low-adhesion composition of claim 1 , wherein said fluoropolymers have an average molecular weight from about 1,000 g/mol to about 10,000 g/mol.

7. The low-adhesion composition of claim 1 , wherein p is selected from 6 to 50 for each of X and Y.

8. The low-adhesion composition of claim 1 , wherein said isocyanate species are selected from the group consisting of 4,4′-methylenebis(cyclohexyl isocyanate), hexamethylene diisocyanate, cycloalkyl-based diisocyanates, tolylene-2,4-diisocyanate, 4,4′-methylenebis(phenyl isocyanate), isophorone diisocyanate, and combinations or derivatives thereof.

9. The low-adhesion composition of claim 1 , wherein said polyol or polyamine chain extenders or crosslinkers are selected from the group consisting of 1,3-butanediol, 1,4-butanediol, 1,3-propanediol, 1,2-ethanediol, di ethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, neopentyl glycol, 1,6-hexanediol, 1,4-cyclohexanedimethanol, ethanol amine, diethanol amine, methyldiethanolamine, phenyldiethanolamine, glycerol, trimethylolpropane, 1,2,6-hexanetriol, triethanolamine, pentaerythritol, ethylenediamine, 1,3-propanediamine, 1,4-butanediamine, diethyltoluenediamine, dimethylthiotoluenediamine, isophoronediamine, diaminocyclohexane, N,N,N′,N′-tetrakis(2-hydroxypropyl) ethylenediamine, and homologues, derivatives, or combinations thereof.

10. The low-adhesion composition of claim 1 , wherein said composition contains, in a hard segment, said reacted form of said one or more isocyanate species, combined with said reacted form of said one or more polyol or polyamine chain extenders or crosslinkers.

11. A low-adhesion coating containing a solventborne copolymer composition comprising:
(a) a substantially continuous matrix containing a first component;
(b) a plurality of inclusions containing a second component, wherein said inclusions are dispersed within said matrix; and
(c) a solid-state lubricant distributed within said matrix and within said inclusions, wherein said solid-state lubricant is distributed uniformly throughout said coating,
wherein one of said first component or said second component is a low-surface-energy polymer having a surface energy between about 5 mJ/m 2 to about 50 mJ/m 2 , and the other of said first component or said second component is a hygroscopic material;
wherein said low-surface-energy polymer is in the form of first soft segments comprising a fluoropolymer that is present in the triblock structure:

wherein:
X, Y=CH 2 —(O—CH 2 —CH 2 ) p -T, and X and Y are independently selected;
p=1 to 50;
T is a hydroxyl or amine terminal group;
m=1 to 100; and
n=1 to 100;
wherein said hygroscopic material is in the form of second soft segments comprising polyesters or polyethers, wherein said polyesters or polyethers are (α,ω)-hydroxyl-terminated and/or (α,ω)-amine-terminated;
wherein the molar ratio of said second soft segments to said first soft segments is 1.7 or less; and
wherein said hygroscopic material is covalently connected to said fluoropolymer in a copolymer.

12. The low-adhesion coating of claim 11 , wherein said solid-state lubricant is selected from the group consisting of graphite, graphene, molybdenum disulfide, tungsten disulfide, hexagonal boron nitride, poly(tetrafluoroethylene), fluoropolymers, and combinations thereof.

13. The low-adhesion coating of claim 11 , wherein said solid-state lubricant is a plurality of particles coated with a metal selected from the group consisting of cadmium, lead, tin, zinc, copper, nickel, and combinations or alloys thereof.

14. The low-adhesion coating of claim 11 , wherein said solid-state lubricant is characterized by an average particle size from about 0.1 μm to about 500 μm.

15. The low-adhesion coating of claim 11 , wherein said continuous matrix further contains (i) one or more isocyanate species possessing an average isocyanate functionality of about 2 or greater, or a reacted form thereof and (ii) one or more polyol or polyamine chain extenders or crosslinkers possessing an average functionality of about 2 or greater, or a reacted form thereof.

16. The low-adhesion material of claim 15 , wherein said isocyanate species are selected from the group consisting of 4,4′-methylenebis(cyclohexyl isocyanate), hexamethylene diisocyanate, cycloalkyl-based diisocyanates, tolylene-2,4-diisocyanate, 4,4′-methylenebis(phenyl isocyanate), isophorone diisocyanate, and combinations or derivatives thereof.

17. The low-adhesion coating of claim 15 , wherein said polyol or polyamine chain extenders or crosslinkers are selected from the group consisting of 1,3-butanediol, 1,4-butanediol, 1,3-propanediol, 1,2-ethanediol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, neopentyl glycol, 1,6-hexanediol, 1,4-cyclohexanedimethanol, ethanol amine, diethanol amine, methyldiethanolamine, phenyldiethanolamine, glycerol, trimethylolpropane, 1,2,6-hexanetriol, triethanolamine, pentaerythritol, ethylenediamine, 1,3-propanediamine, 1,4-butanediamine, diethyltoluenediamine, dimethylthiotoluenediamine, isophoronediamine, diaminocyclohexane, N,N,N′,N′-tetrakis(2-hydroxypropyl) ethylenediamine, and homologues, derivatives, or combinations thereof.

18. The low-adhesion coating

Assignees

• Hrl Lab Llc

Inventors

• Nowak Andrew P
• Sherman Elena
• Gross Adam F

Classifications

• C10N2010/16

  Groups 8, 9, or 10 · CPC title

• C10N2010/12

  Groups 6 or 16 · CPC title

• C10N2010/04

  Groups 2 or 12 · CPC title

• C10N2010/02

  Groups 1 or 11 · CPC title

• C10N2020/061

  Coated particles · CPC title