Method for obtaining hydrocarbon solvents with boiling point above 300° C. and pour point lower than or equal to −25° C

Patent metadata

Field	Value
Publication number	US-10836968-B2
Application number	US-201816031783-A
Country	US
Kind code	B2
Filing date	Jul 10, 2018
Priority date	Dec 10, 2012
Publication date	Nov 17, 2020
Grant date	Nov 17, 2020

Abstract

A method for producing hydrocarbon solvents having a sulfur content of less than 10 ppm, aromatic hydrocarbon content of less than 500 ppm, an initial boiling point higher than or equal to 300° C. and final boiling point lower than or equal to 500° C., for a fraction interval of a maximum of 100° C., and pour point lower than −25° C. according to the standard ASTM D5950, comprising of the following steps of:
dewaxing of a hydrocarbon fraction having initial boiling point higher than 300° C. derived from the distillation of a gas oil fraction, hydrodearomatisation of all or part of the dewaxed effluent, in the presence of a catalyst comprising nickel on an alumina base, at a pressure ranging from 60 to 200 bar and a temperature ranging from 80° C. to 250° C., recovery of the dewaxed and dearomatised fraction, distillation in fractions of the dewaxed and dearomatised fraction, recovery of at least one 300° C.+ fraction having pour point lower than −25° C., this fraction having a distillation interval lower than 100° C.

First claim

What is claimed is:

1. A (300° C.+) hydrocarbon fraction having pour point lower than −25° C., initial boiling point higher than 300° C. and final boiling point lower than or equal to 500° C., with fraction interval lower than 100° C., having a sulfur content of less than 10 ppm and with content of aromatic hydrocarbons less than 500 ppm, obtained by a method comprising the following steps:
dewaxing of a hydrocarbon fraction having initial boiling point higher than 300° C. derived from the distillation of a gas oil fraction obtained by any crude oil refining process, and recovery of all or part of the dewaxed effluent, the step of dewaxing comprising at least one first section for mild cracking in the presence of a silicalite-based catalyst, having silica/alumina ratio greater than 130, comprising 0% to 10% by weight of at least one metal from group VIII, and possibly 0% to 10% by weight of a metal from Group VI;
hydrodearomatisation of all or part of the dewaxed effluent, in the presence of a catalyst comprising nickel on an alumina base, at a pressure ranging from 60 to 200 bar and a temperature ranging from 80° C. to 250° C., and said dewaxed effluent being possibly previously desulphurised in advance if its sulfur content is greater than 15 ppm,
recovery of the dewaxed fraction, possibly desulphurised, and dearomatised,
distillation (DA 1 ) in fractions of the said dewaxed and dearomatised fraction,
and finally recovery of at least one 300° C.+ fraction having pour point lower than −25° C. that is usable as solvent, this fraction having a distillation interval lower than 100° C., characterised in that said hydrocarbon fraction contains more than 40% by weight of naphthenic compounds, and less than 10% by weight of normal paraffins, and the mono naphthenic compounds represent more than 20% by weight of the naphthenic compounds.

2. A hydrocarbon fraction according to claim 1 , containing less than 5% by weight of normal paraffins.

3. A hydrocarbon fraction according to claim 1 , characterised in that it has a pour point that is lower than −30° C., a kinematic viscosity at 40° C. less than or equal to 15 mm 2 /s and an aniline point below 120° C.

4. A hydrocarbon fraction according to claim 1 , characterised in it comprises less than 35% by weight of hydrocarbons having a chain length of more than 22 carbon atoms, and more than 65% by weight of hydrocarbons having a chain length of less than 22 carbon atoms.

5. A hydrocarbon fraction according to claim 1 , as a solvent in applications related to phytosanitary products, inks and sealant putty.

6. A hydrocarbon fraction according to claim 3 , characterised in that it has a kinematic viscosity at 40° C. ranging from 5 mm 2 /s to 10 mm 2 /s.

7. A hydrocarbon fraction according to claim 5 , as a fluid for metal working.

8. A (300° C.+) hydrocarbon fraction having pour point lower than −25° C., initial boiling point higher than 300° C. and final boiling point lower than or equal to 500° C., with fraction interval lower than 100° C., having a sulfur content of less than 10 ppm and with content of aromatic hydrocarbons less than 500 ppm, obtained by a method comprising the following steps:
dewaxing of a hydrocarbon fraction having initial boiling point higher than 300° C. derived from the distillation of a gas oil fraction obtained by any crude oil refining process, and recovery of all or part of the dewaxed effluent, the step of dewaxing comprising at least one first section for mild cracking in the presence of a silicalite-based catalyst, having silica/alumina ratio greater than 130, comprising 0% to 10% by weight of at least one metal from group VIII, and possibly 0% to 10% by weight of a metal from Group VI;
hydrodearomatisation of all or part of the dewaxed effluent, in the presence of a catalyst comprising nickel on an alumina base, at a pressure ranging from 60 to 200 bar and a temperature ranging from 80° C. to 250° C., and said dewaxed effluent being possibly previously desulphurised in advance if its sulfur content is greater than 15 ppm,
recovery of the dewaxed fraction, possibly desulphurised, and dearomatised,
distillation (DA 1 ) in fractions of the said dewaxed and dearomatised fraction,
and finally recovery of at least one 300° C.+ fraction having pour point lower than −25° C. that is usable as solvent, this fraction having a distillation interval lower than 100° C.,
characterised in that said hydrocarbon fraction contains more than 40% by weight of naphthenic compounds, and less than 10% by weight of normal paraffins, and the mono naphthenic compounds represent more than 20% by weight of the naphthenic compounds.

Assignees

• Total Marketing Services

Inventors

• Aubry Christine
• Grasso Giacomo
• Dath Jean-Pierre

Classifications

• C10M2203/1006

  used as base material · CPC title

• C10G65/08

  at least one step being a hydrogenation of the aromatic hydrocarbons · CPC title

• C10G2300/301

  Boiling range · CPC title

• C10G2400/18

  Solvents · CPC title

• C10G47/18

  the catalyst containing platinum group metals or compounds thereof · CPC title