Prepreg, method for its production and fiber-reinforced molded product

Patent metadata

Field	Value
Publication number	US-10836877-B2
Application number	US-201815997004-A
Country	US
Kind code	B2
Filing date	Jun 4, 2018
Priority date	Jan 13, 2016
Publication date	Nov 17, 2020
Grant date	Nov 17, 2020

Abstract

To provide a prepreg excellent in storage stability and capable of obtaining a fiber-reinforced molded product excellent in impact resistance, chemical resistance and inter-member (interlayer) adhesion and a method for its production as well as a fiber-reinforced molded product excellent in impact resistance, chemical resistance and inter-member (interlayer) adhesion. The prepreg comprises reinforcing fibers and a matrix resin, wherein the matrix resin comprises, as a resin component, only a melt-moldable fluororesin having a melting point of from 100 to 325° C. and having functional groups of at least one type selected from the group consisting of carbonyl group-containing groups, hydroxy groups, epoxy groups and isocyanate groups, or the fluororesin and a thermoplastic resin (but excluding the fluororesin), and in 100 mass % of the total of the fluororesin and the thermoplastic resin, the proportion of the fluororesin is from 70 to 100 mass % and the proportion of the thermoplastic resin is from 0 to 30 mass %.

First claim

What is claimed is:

1. A prepreg, comprising reinforcing fibers and a matrix resin, wherein:
the matrix resin comprises, as a resin component, only a melt-moldable fluororesin having a melting point of at least 100° C. and at most 325° C. and having functional groups of at least one member selected from the group consisting of carbonyl group-comprising groups, hydroxy groups, epoxy groups and isocyanate groups, or the fluororesin and a thermoplastic resin other than the fluororesin, and in 100 mass % of the total of the fluororesin and the thermoplastic resin, a proportion of the fluororesin is from 70 to 100 mass % and a proportion of the thermoplastic resin is from 0 to 30 mass %; and
the prepreg is a reinforcing fiber sheet impregnated with the matrix resin.

2. The prepreg of claim 1 , wherein:
in 100 mass % of the total of the fluororesin and the thermoplastic resin, the proportion of the fluororesin is from 70 to less than 100 mass %, and the proportion of the thermoplastic resin is from more than 0 to 30 mass %; and
the matrix resin has a sea-island structure composed of a sea portion comprising the fluororesin and island portions comprising the thermoplastic resin, wherein an average diameter of the island portions is from 0.01 to 200 μm.

3. The prepreg of claim 1 , wherein the melting point of the fluororesin is from 100 to less than 260° C.

4. A fiber-reinforced molded product, comprising the prepreg of claim 1 .

5. A method for producing a prepreg, the method comprising melting a powder mixture obtained by mixing a powder (X) made of a resin material (α) and a powder (Y) made of a resin material (β), in the presence of a reinforcing fiber sheet, to impregnate the reinforcing fiber sheet with the resin material (α) and the resin material (β),
wherein the resin material (α) comprises a melt-moldable fluororesin having a melting point of from 100 to 325° C. and having functional groups of at least one member selected from the group consisting of carbonyl group-comprising groups, hydroxy groups, epoxy groups and isocyanate groups, and the resin material (0) comprises a thermoplastic resin other than the fluororesin, so that in 100 mass % of the total of the fluororesin and the thermoplastic resin, a proportion of the fluororesin becomes from 70 to less than 100 mass %, and a proportion of the thermoplastic resin becomes from more than 0 to 30 mass %.

6. The method of claim 5 , wherein an average particle diameter of the powder (X) is from 0.02 to 200 μm, and an average particle diameter of the powder (Y) is from 0.02 to 200 μm.

7. A method for producing a prepreg, the method comprising melting a powder (Z) made of a resin material (γ), in the presence of a reinforcing fiber sheet, to impregnate the reinforcing fiber sheet with the resin material (γ),
wherein the resin material (γ) comprises, as a resin component, only a melt-moldable fluororesin having a melting point of from 100 to 325° C. and having functional groups of at least one member selected from the group consisting of carbonyl group-comprising groups, hydroxy groups, epoxy groups and isocyanate groups, or the fluororesin and a thermoplastic resin other than the fluororesin, so that in 100 mass % of the total of the fluororesin and the thermoplastic resin, a proportion of the fluororesin is from 70 to 100 mass %, and a proportion of the thermoplastic resin is from 0 to 30 mass %.

8. The method of claim 7 , wherein:
an average particle diameter of the powder (Z) is from 0.02 to 200 μm;
in 100 mass % of the total of the fluororesin and the thermoplastic resin, the proportion of the fluororesin is from 70 to less than 100 mass %, and the proportion of the thermoplastic resin is from more than 0 to 30 mass %; and
an average diameter of island portions comprising the thermoplastic resin in the resin material (γ) prior to being impregnated into the reinforcing fiber sheet is from 0.01 to 8 μm and less than the average particle diameter of the powder (Z).

9. A method for producing a prepreg, the method comprising melting a resin film made of a resin material (γ), in the presence of a reinforcing fiber sheet, to impregnate the reinforcing fiber sheet with the resin material (γ),
wherein the resin material (γ) comprises, as a resin component, only a melt-moldable fluororesin having a melting point of from 100 to 325° C. and having functional groups of at least one member selected from the group consisting of carbonyl group-comprising groups, hydroxy groups, epoxy groups and isocyanate groups, or the fluororesin and a thermoplastic resin other than the fluororesin, so that in 100 mass % of the total of the fluororesin and the thermoplastic resin, a proportion of the fluororesin is from 70 to 100 mass %, and a proportion of the thermoplastic resin is from 0 to 30 mass %.

10. The method of claim 9 , wherein:
in 100 mass % of the total of the fluororesin and the thermoplastic resin, the proportion of the fluororesin is from 70 to less than 100 mass %, and the proportion of the thermoplastic resin is from more than 0 to 30 mass %; and
an average diameter of island portions comprising the thermoplastic resin in the resin material (γ) prior to being impregnated into the reinforcing fiber sheet is from 0.01 to 8 μm and less than a thickness of the resin film.

Assignees

• Agc Inc

Inventors

• Hosoda Tomoya
• Sato Takashi
• Abe Masatoshi

Classifications

• B29C70/506 Primary

  and impregnating by melting a solid material, e.g. sheet, powder, fibres (B29C70/508 takes precedence) · CPC title

• C08J5/243

  using carbon fibres · CPC title

• C08J2377/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08J2377/10 takes precedence) · CPC title

• C08J5/042

  with carbon fibres · CPC title

• C08J2327/18

  Homopolymers or copolymers of tetrafluoroethylene · CPC title