Organic zinc catalyst, preparation method thereof, and method for preparing polyalkylene carbonate resin using the catalyst

Patent metadata

Field	Value
Publication number	US-10836860-B2
Application number	US-202016823496-A
Country	US
Kind code	B2
Filing date	Mar 19, 2020
Priority date	Mar 9, 2016
Publication date	Nov 17, 2020
Grant date	Nov 17, 2020

Abstract

The method for preparing an organic zinc catalyst includes the step of reacting a zinc precursor with a dicarboxylic acid in the presence of a polyether derivative to form a zinc dicarboxylate-based catalyst.

First claim

What is claims:

1. An organic zinc catalyst which is a zinc dicarboxylate-based catalyst obtained by reacting a zinc precursor and a dicarboxylic acid having 3 to 20 carbon atoms with an aliphatic or aromatic polyether derivative having a functional group at a terminus thereof,
wherein the organic zinc catalyst includes a polyether physically or chemically bonded to the catalyst in an amount of 0.001 to 5% by weight relative to the weight of the catalyst,
wherein the polyether derivative includes an aliphatic or aromatic polyether derivative having a functional group at a terminus thereof which is substituted with an alkyl group having 1 to 18 carbon atoms, an aryl group having 6 to 18 carbon atoms, a vinyl group, an alkyl acrylate, a phosphate, or a sulfonyl group, and
wherein the polyether derivative is at least one compound selected from the group consisting of tetraethylene glycol dimethyl ether, diethylene glycol dibutyl ether, tetraethylene glycol dimethacrylate, benzyl-PEG (polyethylene glycol), a PEG aldehyde, and a PEG-phospholipid.

2. The organic zinc catalyst according to claim 1 , wherein the polyether derivative has a weight average molecular weight of 100 to 10,000.

3. The organic zinc catalyst according to claim 1 , wherein the polyether derivative is present in an amount of 0.1 to 10% by weight based on the zinc precursor.

4. The organic zinc catalyst according to claim 1 , wherein the zinc precursor is at least one zinc compound selected from the group consisting of zinc oxide (ZnO), zinc sulfate (ZnSO 4 ), zinc chlorate (Zn(ClO 3 ) 2 ), zinc nitrate (Zn(NO 3 )), and zinc hydroxide (Zn(OH) 2 ).

5. The organic zinc catalyst according to claim 1 , wherein the dicarboxylic acid is at least one selected from the group consisting of malonic acid, glutaric acid, succinic acid, adipic acid, terephthalic acid, isophthalic acid, homophthalic acid, and phenylglutaric acid.

6. The organic zinc catalyst according to claim 1 , wherein the reaction between the zinc precursor and the dicarboxylic acid is present in an amount of about 1 to 1.5 mol based on 1 mol of the zinc precursor.

7. The organic zinc catalyst according to claim 1 , wherein the reaction between the zinc precursor and the dicarboxylic acid is carried out under at least one liquid medium selected from the group consisting of toluene, hexane, dimethylformamide, ethanol, and water.

8. The organic zinc catalyst according to claim 1 , wherein the reaction between the zinc precursor and the dicarboxylic acid is carried out at a temperature of 50 to 130° C. for 1 to 10 hours.

9. The organic zinc catalyst according to claim 1 , wherein the reaction between the zinc precursor and the dicarboxylic acid is carried out without addition of monocarboxylic acid.

10. A method for preparing a polyalkylene carbonate resin, comprising polymerizing monomers including an epoxide and carbon dioxide in the presence of an organic zinc catalyst of claim 1 .

Assignees

• Lg Chemical Ltd

Inventors

• Kim Sung-Kyoung
• Park Seung Young

Classifications

• B01J2531/26

  Zinc · CPC title

• B01J2531/0216

  Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp · CPC title

• B01J31/2213

  At least two complexing oxygen atoms present in an at least bidentate or bridging ligand · CPC title

• C08G64/34 Primary

  and cyclic ethers · CPC title

• B01J37/04 Primary

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title