Tire sidewalls including high molecular weight waxes

Patent metadata

Field	Value
Publication number	US-10836209-B2
Application number	US-201515536873-A
Country	US
Kind code	B2
Filing date	Dec 17, 2015
Priority date	Dec 17, 2014
Publication date	Nov 17, 2020
Grant date	Nov 17, 2020

Abstract

A tire sidewall comprising a vulcanized rubber and a high molecular weight wax.

First claim

What is claimed is:

1. A tire sidewall comprising:
a. a vulcanized rubber;
b. a high molecular weight wax, where the high molecular weight wax is characterized in that at least 90 weight % of the wax molecules have from 32 to about 70 carbon atoms and wherein the high molecular weight wax is characterized by a peak molecular weight of at least 500 g/mol;
c. a dynamic antioxidant, where the tire sidewall includes at least 2.0 parts by weight dynamic antioxidant per 100 parts by weight rubber, and where the dynamic antioxidant is at least one of substituted phenol, diphenyl amine-acetone reaction products, 2,2,2-trimethyl-1,2-dihydroquinoline polymer, and tri(nonophenyl)phosphite; and
d. a dynamic antiozonant, where the tire sidewall includes at least 2.0 parts by weight dynamic antiozonant per 100 parts by weight rubber, and where the dynamic antiozonant is one of N,N-dialkyl-p-phenylene diamine, N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylene diamine and N-isopropyl-N′-phenyl-p-phenylene diamine.

2. The tire sidewall of claim 1 , where the tire sidewall includes at least 2.0 parts by weight and at most 10 parts by weight high molecular weight wax per 100 parts by weight rubber.

3. The tire sidewall of claim 1 , where the tire sidewall includes at least 2.2 parts by weight and at most 8 parts by weight high molecular weight wax per 100 parts by weight rubber.

4. The tire sidewall of claim 1 , where the vulcanized rubber includes the vulcanized product of natural rubber and a synthetic polydiene.

5. The tire sidewall of claim 4 , where the weight ratio of natural rubber to synthetic polydiene is from 0.4:1 to 1.5:1.

6. The tire sidewall of claim 1 , where the vulcanized rubber includes the vulcanized product of ethylene-propylene-diene rubber.

7. The tire sidewall of claim 1 , where the high molecular weight wax is characterized in that at least 65 weight % of the wax molecules are linear.

8. The tire sidewall of claim 1 , where the high molecular weight wax is characterized by a Mettler drop point of at least 80° C.

9. The tire sidewall of claim 1 , where the high molecular weight wax is characterized by a congealing point of at least 80° C.

10. The tire sidewall of claim 1 , where the high molecular weight wax is characterized by a penetration at 25° C. of less than 10 1/10 mm.

11. The tire sidewall of claim 1 , where the high molecular weight wax is dispersed throughout said vulcanized rubber.

12. The tire sidewall of claim 1 , further comprising about 5 to about 200 parts by weight filler per 100 parts by weight rubber.

13. The tire sidewall of claim 12 , where the tire sidewall includes from about 2 to about 10 parts by weight of the dynamic antioxidant per 100 parts by weight rubber.

14. The tire sidewall of claim 13 , where the tire sidewall includes from about 2 to about 10 parts by weight of the dynamic antiozonant per 100 parts by weight rubber.

15. A tire comprising the tire sidewall of claim 14 .

16. A method for preparing the tire sidewall of claim 1 , the method including vulcanizing a green sidewall, where said green sidewall is fabricated from a vulcanizable composition of matter including a vulcanizable rubber, the high molecular wax, the dynamic antioxidant, and the dynamic antiozonant.

Assignees

• Bridgestone Americas Tire Operations Llc

Inventors

• Balnis Craig
• Welles Emily

Classifications

• B60C13/00 Primary

  Tyre sidewalls; Protecting, decorating, marking, or the like, thereof (B60C17/08 takes precedence; tyre shoulders B60C11/01; removable tyre sidewall trim rings B60B7/01) · CPC title

• B60C19/00

  Tyre parts or constructions not otherwise provided for · CPC title

• C08L21/00

  Compositions of unspecified rubbers · CPC title

• B60C1/00

  Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition · CPC title

• C08L9/00

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title